ALBERT

Description: By controlled experiments that simulate marine depositional environments, it is shown that accelerated weathering and clay mineral authigenesis occur during the combined process of ingestion, digestion and excretion of fine-grained sediment by two species of annelid worms. Previously characterized synthetic mud was created using finely ground, low-grade metamorphic slate (temperature approximately 300°C) containing highly crystalline chlorite and muscovite. This was added to experiment and control tanks along with clean, wind-blown sand. Faecal casts were collected at regular intervals from the experimental tanks and, less frequently, from the control tanks. Over a period of many months the synthetic mud (slate) proved to be unchanged in the control tanks, but was significantly different in faecal casts from the experimental tanks that contained the worms Arenicola marina and Lumbricus terrestris. Chlorite was preferentially destroyed during digestion in the gut of A. marina. Both chlorite and muscovite underwent XRD peak broadening with a skew developing towards higher lattice spacing, characteristic of smectite formation. A neoformed Fe-Mg-rich clay mineral (possibly berthierine) and as-yet undefined clay minerals with very high d-spacing were detected in both A. marina and L. terrestris cast samples. We postulate that a combination of the low pH and bacteria-rich microenvironment in the guts of annelid worms may radically accelerate mineral dissolution and clay mineral precipitation processes during digestion. These results show that macrobiotic activity significantly accelerates weathering and mineral degradation as well as mineral authigenesis. The combined processes of sediment ingestion and digestion thus lead to early diagenetic growth of clay minerals in clastic sediments.

Description: Compartmentalisation, the subdivision of an aquifer into discrete and relatively isolated units, may be of critical importance for the protection of groundwater although it has been largely ignored in the groundwater literature. The Lower Triassic Sherwood Sandstone, in north west of England, UK, may be a good example of an aquifer that has been compartmentalised by numerous high angle faults with displacements of up to 300 m. The study was initiated to assess the local groundwater flow, the extent of seawater invasion and the controls on recharge in the aquifer and to try to understand whether the aquifer is broken into discrete compartments. Maps and schematic cross-sections of groundwater heads for the years 1993, and 2002 were prepared to trace any structural controls on the groundwater heads across the area. Studying the contour maps and cross sections revealed that: 1) there are substantial differences in groundwater head across some of the NNW-SSE trending faults implying that groundwater flow is strongly limited by faults, 2) an anticline in the east of the area acts as a groundwater divide and 3) the groundwater head seems to follow the topography in some places, although steep changes in groundwater head occur across faults showing that they locally control the groundwater head. The aquifer was thus provisionally subdivided into several hydrogeological sub-basins based on groundwater head patterns and the occurrence of major structural features (faults and a fold). Using groundwater geochemistry data, contour maps of chloride and sulphate concentration largely support the structural sub-division of the area into hydrogeological sub-basins. Scrutiny of groundwater geochemical data, averaged for each sub-basin, confirmed the degree of compartmentalisation and the occurrence of sealed faults. The variation of the geochemical composition of the groundwater not only relates to the different, localised geochemical processes and seawater intrusion but also relates to compartmentalisation due to faulting. Faults have limited the degree of mixing between the groundwater types thus retaining the specific characteristics of each sub-basin. Highly localised seawater intrusion is mainly controlled by low permeability fault close to the Irish Sea and Mersey estuary. There is effectively no invasion of seawater beyond the faults that lie closest to the coastline. Freshwater recharge to the aquifer seems to be highly localised and mainly occurs by vertical percolation of rain and surface water rather than whole aquifer-scale groundwater flow. This study provides a detailed understanding of the groundwater flow processes in Liverpool as an example of methods can be applied to groundwater management elsewhere.

Description: Groundwater in the Triassic Sherwood Sandstone aquifer, Liverpool, UK, has locally elevated chloride concentrations (~4000 mg/l) in parts of the coastal region although there is freshwater right up to the coast line in other areas. The aquifer is cut my numerous faults with vertical displacements of as much 300 m. SPOT satellite data have been used for the Merseyside area of Liverpool. The satellite data revealed and confirmed the location of some of the main faults since the fault zones of the aquifer have low permeability (due to grain crushing, cataclasis, and clay smearing). Where fault zones outcrop at the surface, below the well-developed regolith, there is locally elevated soil water and thus anomalous vegetation patterns in comparison to unfaulted and highly porous aquifer. The ability to identify fault zones by this satellite-based method strongly suggests that they are at least partially sealing, sub-vertical features in the aquifer. Digitally enhanced and processed satellite data were used to define the relative proportions of sand and clay in the near-coastal (inter-tidal) part of the Mersey estuary. Sand-dominated sediment has higher pixel values in comparison with clay deposits in the near infrared spectral region (NIR). Where open and weathered fault rocks crop out at the surface near the intertidal zone, water movement in these potential surface water conduits is limited where the intertidal zone is clay-dominated since clay will plug the conduit. Where these weathered and open fault-rocks crop out against sand-dominated parts of the coastline, fresh water outflux into the seawater has been imaged using the satellite data. Furthermore, the high and low chloride concentration parts of the aquifer are separated by major, sub-vertical fault zones and have allowed a very steep water table gradient to remain in the aquifer.

Description: The study was initiated to assess the local groundwater flow, the extent of seawater invasion and the controls on recharge in the aquifer and to try to understand whether the aquifer is broken into discrete compartments. The study area is located in the northwest of England and encompasses the urban area of Liverpool and surrounding countryside and extends east-west from Liverpool to Widnes and as far north as Formby. The Irish Sea marks the western margin of the area while the Mersey estuary defines the southern margin. The Triassic sandstone in this area has been, and remains, an important aquifer although industrialisation and groundwater exploitation have led to significant water quality problems. Maps of water table for the years 1993, 1997, 2000 and 2002 and schematic cross-sections of the water table height along the faults were prepared to trace any effect of these faults on water table height across. Studying the water table maps and cross sections revealed that: 1) there are substantial differences in water table height across some of the NNW-SSE trending faults implying that groundwater flow is strongly limited by fault, 2) an anticline in the east of the area acts as a groundwater divide and 3) the water table seems to follow the topography in some places, although steep changes in water table occur across faults showings that they locally control the water table elevation. The aquifer was thus provisionally subdivided into several hydrogeological sub-basins based on water table height patterns and the occurrence of major structural features (faults and a fold). Using groundwater geochemistry data, contour maps of chloride and sulphate concentration largely support the structural sub-division of the area into hydrogeological sub-basins. Scrutiny of groundwater geochemical data, averaged for each sub-basin, confirmed the degree of compartmentalisation and the occurrence of sealed faults. The variation of the geochemical composition of the groundwater not only relates to the different, localised geochemical processes and seawater intrusion but also relate to compartmentalisation due to faulting. Faults have limited the degree of mixing between the groundwater types thus retaining the specific characteristics of each sub-basin. Highly localised seawater intrusion is mainly controlled by low permeability fault close to the Irish Sea and Mersey estuary. There is no effectively no invasion of seawater beyond the faults that lie closest to the coastline. Freshwater recharge to the aquifer must be highly localised and will mainly occur by vertical percolation of rain and surface water rather than whole aquifer-scale groundwater flow.

Description: By controlled experiments that simulate marine depositional environments, it is shown that accelerated weathering and clay mineral authigenesis occur during the combined process of ingestion, digestion and excretion of fine-grained sediment by two species of annelid worms. Previously characterized synthetic mud was created using finely ground, low-grade metamorphic slate (temperature approximately 300°C) containing highly crystalline chlorite and muscovite. This was added to experiment and control tanks along with clean, wind-blown sand. Faecal casts were collected at regular intervals from the experimental tanks and, less frequently, from the control tanks. Over a period of many months the synthetic mud (slate) proved to be unchanged in the control tanks, but was significantly different in faecal casts from the experimental tanks that contained the worms Arenicola marina and Lumbricus terrestris. Chlorite was preferentially destroyed during digestion in the gut of A. marina. Both chlorite and muscovite underwent XRD peak broadening with a skew developing towards higher lattice spacing, characteristic of smectite formation. A neoformed Fe-Mg-rich clay mineral (possibly berthierine) and as-yet undefined clay minerals with very high d-spacing were detected in both A. marina and L. terrestris cast samples. We postulate that a combination of the low pH and bacteria-rich microenvironment in the guts of annelid worms may radically accelerate mineral dissolution and clay mineral precipitation processes during digestion. These results show that macrobiotic activity significantly accelerates weathering and mineral degradation as well as mineral authigenesis. The combined processes of sediment ingestion and digestion thus lead to early diagenetic growth of clay minerals in clastic sediments.