ALBERT

Description: The Rio Grande Cone is a major fanlike depositional feature in the continental slope of the Pelotas Basin, Southern Brazil. Two representative sediment cores collected in the Cone area were retrieved using a piston core device. In this work, the organic matter (OM) in the sediments was characterized for a continental vs. marine origin using chemical proxies to help constrain the origin of gas in hydrates. The main contribution of OM was from marine organic carbon based on the stable carbon isotope (δ13C-org) and total organic carbon/total nitrogen ratio (TOC:TN) analyses. In addition, the 14C data showed important information about the origin of the OM and we suggest some factors that could modify the original organic matter and therefore mask the “real” 14C ages: (1) biological activity that could modify the carbon isotopic composition of bulk terrestrial organic matter values, (2) the existence of younger sediments from mass wasting deposits unconformably overlying older sediments, and (3) the deep-sediment-sourced methane contribution due to the input of “old” (〉50 ka) organic compounds from migrating fluids.

Description: An analysis is presented for electrophoretic motion of a charged non-conducting sphere in the proximity of rigid boundaries. An important assumption is that Ka → ∞, where a is the particle radius and K is the Debye screening parameter. Three boundary configurations are considered: single flat wall, two parallel walls (slit), and a long circular tube. The boundary is assumed a perfect electrical insulator except when the applied field is directed perpendicular to a single wall, in which case the wall is assumed to have a uniform potential (perfect conductor). There are three basic effects causing the particle velocity to deviate from the value given by Smoluchowski’s classic equation: first, a charge on the boundary causes electro-osmotic flow of the suspending fluid; secondly, the boundary alters the interaction between the particle and applied electric field; and, thirdly, the boundary enhances viscous retardation of the particle as it tries to move in response to the applied field. Using a method of reflections, we determine the particle velocity for a constant applied field in increasing powers of A up to O(λ6), where A is the ratio of particle radius to distance from the boundary. Ignoring the O(λ0) electro-osmotic effect, the first effect attributable to proximity of the boundary is O (λ3) for all boundary configurations, and in cases when the applied field is parallel to the boundaries the electrophoretic velocity is proportional to ξp— ξw, the difference in zeta potential between the particle and boundary. © 1985, Cambridge University Press. All rights reserved.

Description: Thrust-producing harmonically oscillating foils are studied through force and power measurements, as well as visualization data, to classify the principal characteristics of the flow around and in the wake of the foil. Visualization data are obtained using digital particle image velocimetry at Reynolds number 1100, and force and power data are measured at Reynolds number 40 000. The experimental results are compared with theoretical predictions of linear and nonlinear inviscid theory and it is found that agreement between theory and experiment is good over a certain parametric range, when the wake consists of an array of alternating vortices and either very weak or no leading-edge vortices form. High propulsive efficiency, as high as 87%, is measured experimentally under conditions of optimal wake formation. Visualization results elucidate the basic mechanisms involved and show that conditions of high efficiency are associated with the formation on alternating sides of the foil of a moderately strong leading-edge vortex per half-cycle, which is convected downstream and interacts with trailing-edge vorticity, resulting eventually in the formation of a reverse Kármán street. The phase angle between transverse oscillation and angular motion is the critical parameter affecting the interaction of leading-edge and trailingedge vorticity, as well as the efficiency of propulsion.

Description: Seasonal variation in the reproductive capacity of the bull was studied during a 27-month experimental period at the Experimental Station. There are a total of 1049 ejaculates for this period. Supplementary data for other periods on the Experimental Station and for two other large farms practising artificial insemination are also included.Highly significant individual and monthly differences were noted during the experimental period for the density and motility of the sperm, the pH of the semen and for the percentage of ejaculations performed. The seasonal variation in semen is marked, but there is considerable variation in different years between bulls and between farms in the periods of maximal and minimal types of semen and in seasonal trends.The relationship between such variation and climatic and nutritional conditions is discussed. There appears to be a basic seasonal rhythm in bull semen associated with climatic factors, warmer conditions causing stimulation and vice versa. Nutritional factors may, however, modify this rhythm. The relationship between seasonal variations in semen quality and fertility is discussed.

Description: Glacial recession from the Antarctic continental shelf is recorded by glacial-marine diamictons, sands, and overlying siliceous oozes. In order to clarify the chronology for this sequence, use was made of the University of Arizona tandem accelerator mass-spectrometer (TAMS) for 14C dating. Small samples of benthic and planktonic foraminifera were selectively removed from diamictons, graded sands, and surface sediments which were recovered from the Wilkes Land continental shelf and slope, East Antarctica. Organic carbon was also utilized as a source for TAMS dating of the siliceous oozes and muds. Uncorrected ages varied from 14,260 ± 140 to 3230 ± 200 yr B.P. Carbon fixed by phytoplankton and foraminifera is strongly influenced by old, glacial-derived CO2. Thus, reservoir corrections of up to 5500 yr are needed for the 14C dates. Iceberg turbation reworks foraminifera so that dates from resulting deposits (diamictons) are interpreted as maximum ages. The consistency of corrected ages from the shelf, along with the sedimentologic interpretation, suggests a rather recent recession, perhaps mid-Holocene for this portion of the East Antarctic ice sheet. Further application of the TAMS method should help clarify other problems concerning the late Quaternary glacial history of Antarctica.

Description: A two-dimensional configuration has been investigated in which air flows through a convergent nozzle and expands abruptly into a rectangular duct of larger cross-section which terminates in a plenum chamber. Three different types of oscillation have been observed in the downstream duct. At low plenumchamber pressures an oscillation occurs towards the exit of the duct as the boundary layer of the flow becomes alternately separated and attached. At increasing plenum pressure a shock-pattern oscillation takes place in which a change from a normal shock to oblique shocks occurs during a cycle. At still greater plenum pressures a base-pressure oscillation occurs which influences the entire duct flow downstream of the abrupt change in cross-section. The amplitudes of the oscillation can be as high as 10% of the rest state, and the frequency of the base-pressure oscillations can be predicted approximately from one-dimensional gasdynamic theory. The unsteady duct phenomena have been studied by synchronizing instantaneous pressures measured by quartz pressure transducers with interferograms obtained with a Mach–Zehnder interferometer. © 1977, Cambridge University Press. All rights reserved.

Description: When a particle is placed in a fluid in which there is a non-uniform concentration of solute, it will move toward higheror lower concentration depending on whether the solute is attracted to or repelled from the particle surface. A quantitative understanding of this phenomenon requires that the equations representing conservation of mass and momentum within the fluid in the vicinity of the particle are solved. This is accomplished using a method of matched asymptotic expansions in a small parameter L/a, where a is the particle radius and L is the length scale characteristic of the physical interaction between solute and particle surface. This analysis yields an expression for particle velocity, valid in the limit L/a→0, that agrees with the expression obtained by previous researchers. The result is cast into a more useful algebraic form by relating various integrals involving the solute/particle interaction energy to a measurable thermodynamic property, the Gibbs surface excess of solute. An important result is that the correction for finite L/a is actually O(/Ca), where C is the bulk concentration of solute, and could be 0(1) even when L/a is orders of magnitude smaller. © 1982, Cambridge University Press. All rights reserved.

Description: When immersed in a non-uniform electrolyte solution, a rigid charged sphere migrates toward higher or lower concentration of the electrolyte depending on the relative ionic mobilities and the charge borne by the sphere. This motion has a twofold origin: first, a macroscopic electrolyte gradient produces an electric field which acts on the charged sphere (electrophoresis); secondly, the electrolyte gradient polarizes the cloud of counterions surrounding the charged sphere by making the cloud thinner on the high-concentration side (chemiphoresis). In this paper, we compute the terminal velocity of a non-conductive sphere through a slightly non-uniform solution of a symmetrically charged binary electrolyte. The analysis proceeds through an expansion in the small parameter A (defined as the ratio of the counterion-cloud thickness to the particle radius). Results to 0(A) are presented. The only property of the sphere's surface that affects the velocity is its zeta potential ζ when the electrolyte gradient vanishes; no information concerning the dependence of ζ upon ionic strength is needed. While the chemiphoretic effect always directs the particle toward higher electrolyte concentration, the electrophoretic contribution can move the particle in either direction depending on the sign of βζ, where β is a normalized difference in mobilities between cation and anion of the elecytrolyte; thus particle movement could be directed toward either higher or lower electrolyte concentration depending on the physical properties of the system. With slight algebraic rearrangement, our results are also applicable to conventional electrophoresis (particle motion in an applied electric field) and show excellent agreement with the numerical calculations of O'Brien & White (1978). © 1984, Cambridge University Press. All rights reserved.

Description: An account is given of artificial insemination of 733 grade cows in Kenya from January 1936 to August 1939. 76·8% of the cows inseminated calved, with an average of 1·88 inseminations per conception. The different doses and dilution of sperm used gave very similar results, as did two inseminations, compared with one insemination, in a single heat period.

Description: :Most granitic batholiths contain plutons which are composed of low-variance mineral assemblages amenable to quantification of the P– conditions that characterise emplacement. Some mineral thermometers, such as those based on two feldspars or two Fe–Ti oxides, commonly undergo subsolidus re-equilibration. Others are more robust, including hornblende–plagioclase, hornblende–clinopyroxene, pyroxene–ilmenite, pyroxene–biotite, garnet–hornblende, muscovite-biotite and garnet–biotite. The quality of their calibration is variable and a major challenge resides in the large range of liquidus to solidus crystallisation temperatures that are incompletely preserved in mineral profiles. Further, the addition of components that affect Kd relations between non-ideal solutions remains inadequately understood. Estimation of solidus and near-solidus conditions derived from exchange thermometry often yield results 〉700°C and above that expected for crystallisation in the presence of an H2O-rich volatile phase. These results suggest that the assumption of crystallisation on an H2O-saturated solidus may not be an accurate characterisation of some granitic rocks.Vapour undersaturation and volatile phase composition dramatically affect solidus temperatures. Equilibria including hypersthene–biotite–sanidine–quartz, fayalite–sanidine–biotite, and annite–sanidine–magnetite (ASM) allow estimation of Estimates by the latter assemblage, however, are highly dependent on . Oxygen fugacity varies widely (from two or more log units below the QFM buffer to a few log units below the HM buffer) and can have a strong affect on mafic phase composition. Ilmenite–magnetite, quartz–ulvospinel–ilmenite–fayalite (QUILF), annite–sanidine–magnetite, biotite–almandine–muscovite–magnetite (BAMM), and titanite–magnetite–quartz (TMQ) are equilibria providing a basis for the calculation of .Granite barometry plays a critical part in constraining tectonic history. Metaluminous granites offer a range of barometers including ferrosilite–fayalite–quartz, garnet–plagioclase–hornblende–quartz and Al-in-hornblende. The latter barometer remains at the developmental stage, but has potential when the effects of temperature are considered. Likewise, peraluminous granites often contain mineral assemblages that enable pressure determinations, including garnet–biotite–muscovite–plagioclase and muscovite–biotite–alkali–feldspar–quartz. Limiting pressures can be obtained from the presence of magmatic epidote and, for low-Ca pegmatites or aplites, the presence of subsolvus versus hypersolvus alkali feldspars.As with all barometers, the influence of temperature, , and choice of activity model are critical factors. Foremost is the fact that batholiths are not static features. Mineral compositions imperfectly record conditions acquired during ascent and over a range of temperature and pressure and great care must be taken in properly quantifying intensive parameters.