ALBERT

Description: In this paper, we summarize data on terrigenous sediment supply in the Kara Sea and its accumulation and spatial and temporal variability during Holocene times. Sedimentological, organic-geochemical, and micropaleontological proxies determined in surface sediments allow to characterize the modern (riverine) terrigenous sediment input. AMS-14C dated sediment cores from the Ob and Yenisei estuaries and the adjacent inner Kara Sea were investigated to determine the terrigenous sediment fluxes and their relationship to paleoenvironmental changes. The variability of sediment fluxes during Holocene times is related to the post-glacial sea-level rise and changes in river discharge and coastal erosion input. Whereas during the late/middle Holocene most of the terrigenous sediments were deposited in the estuaries and the areas directly off the estuaries, huge amounts of sediments accumulated on the Kara Sea shelf farther north during the early Holocene before about 9 Cal. kyr BP. The maximum accumulation at that time is related to the lowered sea level, increased coastal erosion, and increased river discharge. Based on sediment thickness charts, echograph profiles and sediment core data, we estimate an average Holocene (0–11 Cal. kyr BP) annual accumulation of 194×106 t yr−1 of total sediment for the whole Kara Sea. Based on late Holocene (modern) sediment accumulation in the estuaries, probably 12×106 t yr−1 of riverine suspended matter (i.e., about 30% of the input) may escape the marginal filter on a geological time scale and is transported onto the open Kara Sea shelf. The high-resolution magnetic susceptibility record of a Yenisei core suggests a short-term variability in Siberian climate and river discharge on a frequency of 300–700 yr. This variability may reflect natural cyclic climate variations to be seen in context with the interannual and interdecadal environmental changes recorded in the High Northern Latitudes over the last decades, such as the NAO/AO pattern. A major decrease in MS values starting near 2.5 Cal. kyr BP, being more pronounced during the last about 2 Cal. kyr BP, correlates with a cooling trend over Greenland as indicated in the GISP-2 Ice Core, extended sea-ice cover in the North Atlantic, and advances of glaciers in western Norway. Our still preliminary interpretation of the MS variability has to be proven by further MS records from additional cores as well as other high-resolution multi-proxy Arctic climate records.

Description: Late Quaternary sediments on the West African continental margin between 24°N and 15°N were studied with RV METEOR (1971) and VALDIVIA (1975). Cores on the shelf were taken with a 6-m-vibrocorer, in deeper water mainly with a 12 m Kastenlot corer. During Holocene, and up to the present time, more or less and climatic conditions north of the Senegal River area reduced terrigenous supply. Therefore, the biogenic-carbonate content exceeds about 50%. Wüstenquarz numbers (red + yellow quartz : white quartz x 100) are high (20 to mmore than 200), indicating eolian input. The Senegal River supplied fine grained, green colored, terrigenous material with some plant debris. During Würm, the Mediterranean climatic zone with winter rains was shifted more than 5° to the South and was reaching Banc d'Arguin (at about 20°N). Therefore, the terrigenous supply was increased in this northern part and consequently the carbonate content and the Wüstenquartz numbers dropped below 50% and 10, respectively. The arid zone was also shifted to the south; as a consequence, the Senegal River did not reach the sea, eolian supply diluted the biogenic carbonates, and increased Wüstenquartz numbers to more than 200. Eolian dunes covered parts of the shelf. Ratios of radiolarians/plankonic foraminifera and planktonic/benthonic organisms and sedimentation rates of organic carbon indicate stronger upwelling in the northern region. Turbidity currents were more frequent, eroding as much as a third of the material supplied ba pelagic sedimentation.

Description: A porcellanite layer, probably younger than 0.6-0.4 Ma, of a nearly monomineralic composition of opal-CT was sampled on the Southwest Indian Ridge during Polarstern cruise ANT-VI/3. The intense cementation of the rock, together with recent findings by the Ocean Drilling Program (Legs 113 and 120) and the occurrence of a unique older porcellanite from Eltanin Core 47-15, provides evidence of very early silica precipitation in pure diatom oozes of the Southern Ocean. Such porcellanites occur in shallowly buried young sediments and provide a contrast to the established concepts of porcellanite formation.

Description: Marine geological investigations were performed across the Laptev Sea continental shelf and slope. Thirty sampling sites were selected covering a depth range of ca 3500 m. Maximum core recovery was 9 m. PARASOUND sub-bottom profiling was used for site surveying and provided important information on the depositional environment of the continental margin together with sedimentological and stratigraphical investigations. Undisturbed horizontal layering of the sea-floor sediments is a common feature for the Laptev Sea shelf. There is no indication for glaciation of the broad shelf region during the Last Glacial, since moraine deposits are missing. However, a high number of plough marks in places points to recent to sub-recent ice-erosion which has led to an intensive sediment reworking on the shelf. Several broadly incised river channels recorded near the shelf edge are related to Pleistocene drainage systems of large Siberian rivers which cut into the dry shelves during the Last Glacial Maximum and were subsequently filled during the Holocene. During the Last Glacial we therefore suspect a significant freshwater contribution from the Eurasian continent to the Arctic Oceans. The composition of the normally consolidated core sediments indicates a strong flux of terrigenous material, which is mainly provided by the Siberian rivers. Currents distributing the suspension load and sea ice are supposedly major agents transporting sediments across the shelf to the central arctic deep sea basin. Sediment cores from the upper and middle continental slope exhibit only minor lithological changes. Bioturbated, fine-grained sediments with high organic carbon contents dominate. The presence of free hydrogen sulphide gas within the sediment column indicates that an intense decay of organic matter under reducing conditions is taking place. Sedimentation rates are estimated to be ca. 50 cm/1000 years at the upper slope of the western Laptev Sea, being approximately 10 times higher than at the continental rise. The suboxic to anoxic environment diminishes at deep sea sites of the western Laptev Sea, where sedimentation rates and influx of organic matter are reduced.

Description: Humic acid dissolved in artificial seawater influenced the morphology, internal structure, and composition of aragonite when precipitation was induced with dilute Na2CO3 solution. At sodium humate concentrations of around 20 mg/1, numerous brownish spherical aragonite bodies developed within one day at 25 °C. The spheres ranged in size from 10–100 microns and resembled natural marine ooids. They formed with gentle agitation of the solution as well as with no water movement at all. The typical structure of natural ooids consisting of concentric alternating aragonite and organic laminae was experimentally duplicated as layers of aragonite crystals alternating with humate membranes; however, in contrast to natural ooids, the individual aragonite crystals here were oriented radially with their c-axes. The aragonite of the spheres contained about 20 wt. % more strontium than the aragonite precipitated experimentally without the addition of sodium humate, and organic carbon content of the spherical aragonite was about 7% by weight.

Description: Sediments sampled in three lateral traverses from the outer continental shelf to the continental rise off the Sahara Desert were analysed for their grain size distribution and composition. The carbonate content of the shelf and upper slope sediments increases from about 10-15 % in the south to about 50-90 % in the north and changes to about 40-45 % in deeper water. The high carbonate content in the north generally reflects the high proportion of relict material in the sediments. The main change in the composition of the sediments - defined mostly as hemipelagic - from the outer shelf to the rise is in an increase of coccoliths and clays and a decrease of quartz. The cumulative grain size curves indicate that each of the samples is a mixture of different proportions of two approximately log normal populations. The size of the truncation point between the populations, the proportion between the coarse and fine populations and the mean, sorting, skewness and kurtosis decrease with increasing depth. Correlations between the parameters indicate that the moments express mainly the mixture proportions of the two populations. The two populations may, however, indicate an artificial effect of deflocculation during sample treatment rather than reflecting some hydraulic factor. The cumulative grain size distribution curves of eolian dust collected on ship's surface during cruises along the Saharan shelf and that of other published data is divided into a two-population and a onepopulation type. The two populations may be attributed to either gravitational settling of larger dust particles and normal dust fall or to disaggregation effect. The moment statistics of the dust differ mainly from those of the marine sediments in that they have a lower standard deviation. The composition and the textural parameters, combined with modal analysis of the dust and the separated soluble and insoluble components of the sediments indicate that the downslope transportation of the coarser sediment particles is a result of marine currents rather than of wind. The distribution pattern of the relict material in the northern outer shelf and upper slope is attributed to an extinct current regime which was stronger than the present one. The gravitational settling of coarse dust, mainly over the shelf, most probably accounts for the principal input of sediment that is transported further downslope by marine currents. Part of the fine, as well as a small portion of the coarse terrigenous material may be derived from direct settling of dust over the open sea. The recent sedimentation process results in a continental margin prograding off the Sahara Desert. In the south sedimentation occurs on the outer shelf, slope and rise, whereas in the north main sedimentation occurs on the lower slope and rise. The deflection of the Canary current away from the Cape Blanc coast is proposed as an explanation for the apparent reduced deposition rate over the outer shelf and upper slope in the northern area.

Description: Surface sediments from the continental slope and rise off North-West Africa between the Canary Islands and the Cape Verde Islands are mainly composed of silt-sized material (2-63 µm). A number of sampling profiles were run normal to the coast and the composition of the silt fraction was determined quantitatively by scanning electron microscope analysis. The carbonate portion of the sediment was found to be nearly exclusively of biogenic origin. The most important contributors are planktonic foraminifers and coccoliths with minor contributions derived from pteropods. Plankton-produced biogenic opal such as diatoms and radiolarians play a very minor role. The high production rates of opal-silica plankton which exists in the surface waters of the NW-African upwelling system does not give rise to corresponding increases of opal accumulation in the bottom sediment. Benthic producers consist mainly of foraminifers and molluscs but the entire input from benthic producers is extremely small. An exception to this occurs in the prodelta sediments of the Senegal river. Downslope particle transport is indicated by the occurrence of shallow-water coralline algae, ascidian sclerites and cliona boring chips and can be traced as far down as the continental rise. The non-carbonate silt fraction mostly consists of quartz which is derived as eolian dust from the Sahara desert by the Harmattan and the NE-Trade-wind system. The percentage of carbonate in the surface sediments directly indicates the relative proportions of autochthonous biogenic components and terrigenous allochthonous quartz particles.