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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 10 (1992), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The solid-solid reaction magnesiocarpholite = sudoite + quartz has been bracketed between 350 and 500°C, 6.3 and 7.8 kbar. Because it is impossible to synthesize end-member sudoite, all experiments were carried out using natural minerals as starting materials. Although mineral compositions were very close to those of the end-members, the effect of the fluorine content in carpholite was significant. Particularly in those experiments where sudoite grows at the expense of carpholite, electron microprobe analysis of the run products shows that a more stable F-rich carpholite crystallizes too, and consumes the fluorine released in solution by the breakdown of the original carpholite.Our experimental results are combined, through a thermodynamic analysis, with a previous data set and with previous experimental data concerning the relative stability of chlorite, talc and magnesiocarpholite with excess of quartz and water as a function of P–T and AlAl(SiMg)-1 substitutions in phyllosilicates. This allows us to constrain the feasible thermodynamic parameters (H°f, sud; S° sud) and (H°f,car; S°car) for the Mg end-members. Using the partition coefficients calculated from natural parageneses, we have computed a petrogenetic grid for the system FeO–MgO–Al2O3–SiO2–H2O. It demonstrates that parageneses involving sudoite and carpholite can be used as indicators of P–T conditions, up to 600° C, 8 kbar for sudoite, and at higher pressure for carpholite.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2012-02-24
    Description: Low-grade metabasites and hydrothermally altered ultramafic rocks form most of the Paleoarchean Barberton Greenstone Belt (BGB) of South Africa. However, P – T constraints are sparse and the nature of the greenschist-facies metamorphism is poorly characterized. This study provides new P – T estimates and descriptions of the petrological characteristics of altered mafic–ultramafic rocks across the Kromberg type-section, Onverwacht Group, BGB, from both surface samples and fresh drill core. Application of a chlorite thermodynamic multi-equilibrium calculation and pseudosection modelling, in conjunction with petrographic observations, indicates a wide range in metamorphic conditions from sub-greenschist to the uppermost greenschist facies across the type-section. A central fuchsite-bearing zone containing strong mylonitic fabrics, referred to as the Kromberg Section Mylonites (KSM), records at least two metamorphic events: a high- T , low- P (420 ± 30°C, 〈3 kbar) metamorphism, and a lower-T event ( T = 240–350°C, P = 2·9 ± 0·15 kbar) related to retrograde metamorphism associated with extensional quartz–carbonate veins. Pillow lava metabasalts directly beneath the KSM record the same HT–LP-type metamorphic conditions, whereas metabasalts 90 m and 125 m above the KSM record temperatures of 250–340°C. Lower in the Kromberg section, metamorphic conditions vary from 215–321°C (at 2·9 kbar, mid to lower parts) to very low-grade conditions of 140–209°C in the lowermost Kromberg. Thus, an inverted metamorphic field gradient is documented beneath the KSM. Petrological analysis of the fuchsite-bearing rocks of the KSM indicates that they contain listvenite, a hydrothermal alteration product typically found in mafic–ultramafic tectonic mélange zones of ophiolite terranes. Together with the new metamorphic P – T constraints this means that these rocks are not a product of Archean atmospheric weathering. Rather, the inverted metamorphic field gradient in the Kromberg type-section suggests that the KSM represents a Paleoarchean thrust zone. Cr-spinel compositions in the ultramafic protolith to the KSM listvenites suggest a supra-subduction zone setting. A new geodynamic model is therefore proposed in which the mafic–ultramafic oceanic rocks of the Kromberg type-section were obducted as a thrust nappe pile in a regional transpressional tectonic regime between 3227 and 3230 Ma.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 3
    Publication Date: 2012-01-23
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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