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  • Chemical Engineering  (56)
  • Wiley-Blackwell  (56)
  • Blackwell Publishing Ltd
  • Nature Publishing Group
  • Springer Nature
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 749-761 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Multi-cavity transfer molding is an important process step in several electronic and photonic technologies. In some applications, uniform filling of the cavities of the mold, or mold balancing, is required. A semi-empirical flow model to predict mold filling patterns was developed. The algorithm is a one-dimensional network flow simulation that uses experimental pressure drop data to determine the volumetric flow rate through the gates and runners. A comprehensive experimental program was undertaken to determine these hydraulic resistances for different flow rates and mold geometries. A theoretical treatment is also described to compute hydraulic resistance from gate geometry. Uniform gate resistances provide unbalanced filling and higher velocities in the cavities. Balanced filling can significantly reduce the molding compound velocity and the flow induced stresses, but imperfect balancing compromises the benefits. Experimental filling patterns were obtained for two sets of gates. The agreement between the model and the experiments was satisfactory, and the discrepancies were attributed to correctable phenomena.
    Additional Material: 12 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 1796-1796 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 1399-1404 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new capillary rheometer incorporated in an instrumented transfer molding press has been developed. This rheometer is effective for determining the viscosity characteristics of thermoset molding compounds under both isothermal and typical molding conditions. In examples of the rheometer's utility, the power law indices of two commercial epoxy molding compounds have been determined to be approximately 0.7. Additionally it has been shown that preconditioning typical epoxy compounds at 47 percent relative humidity causes a viscosity decrease of about 40 percent owing to plasticization of the epoxy resin.
    Additional Material: 11 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 3442-3457 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Of importance to geothermal energy development, oil, gas and mineral recovery, and waste storage is the characterization of the dissolution rate of host reservoir rock as a function of temperature, pressure and liquid-phase composition. As a major constitutive mineral in natural geologic systems, quartz was selected for study. Dissolution experiments were carried out in a continuous-flow, titanium autoclave reactor system at 100-200°C in various chemical environments. Acidification to pH 1.1 using nitric acid showed very little effect on the quartz dissolution rate. The effect of hydroxide ion concentration and ionic strength were evaluated in NaOH, NaOH/NaCl and NaOH/Na2SO4 solutions. The fractional-order dependency of the quartz dissolution rate on hydroxide ion and sodium ion (or ionic strength) concentration was determined in NaOH/NaCl solutions. The results that extend the available range of kinetic data for quartz generally agree with previous work. The observed fractional-order kinetics were qualitatively described using classical adsorption isotherms. No significant variation in the apparent reaction order of the hydroxide ion with increasing temperature could be determined due to the scatter in the data. Quartz dissolution rates were slower by about 40% in NaOH/Na2SO4 solutions than in NaOH/NaCl solutions at sodium concentrations higher than 0.01 molal. The apparent activation energy from 100 to 200°C in NaOH/NaCl solutions up to 0.01 molal hydroxide ion and 0.1 molal sodium ion was estimated to be 72 (±6) kJ/mol.
    Additional Material: 15 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 267-271 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gas-solids circulating fluidized beds have been successfully used in catalytic cracking of heavy oil, coal combustion, and some metallurgical and physical processes (Grace, 1990). Gas-liquid-solids fluidized beds are operated mainly in conventional fluidization regimes without solids circulation or in the transport regime with low solids holdups (less than 5%) (Fan, 1989). A circulating/fast fluidization regime, however, has not been studied. A three-phase circulating fluidized bed has several potential applications in biochemical and chemical processes. Three-phase fluidized-bed bioreactors generally use light and small particles (Berk et al., 1984). Circulating operation can promote solids mixing and increase product throughput per unit bed cross section, while high shear stress can promote biofilm renewal (Pirozzi et al., 1990). In three-phase hydrotreating reactors, solids catalysts lose their activity due to the deposit of metal and coke on the surface. Circulating operation not only regenerates deactivated catalyst continuously using accompanying downcomers but also transfers heat to and from the reactor. This article discusses the flow regimes of the three-phase circulating fluidized bed.
    Additional Material: 8 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1929-1939 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The breakup of droplets in an inhomogeneous flow is the key to emulsification. Frequently, the local flow experienced by the drops is a (quasi-) simple shear flow. The breakup of droplets in a steady, simple shear flow in the absence of emulsifiers has been studied extensively. In the presence of emulsifiers, the droplet interface may acquire viscoelastic properties, which are important in the prevention of coalescence, but their influence on droplet breakup has not been established solidly. This article reports on a phenomenological approach, which links the droplet breakup dynamics to the interfacial viscoelasticity, identifying the latter with the elasticity modulus of a deforming planar interface. Over a viscosity ratio range of three decades, the results have been found to agree with the model, which uses only independently known quantities derived from equilibrium interfacial tension properties.
    Additional Material: 12 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1436-1447 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Droplet breakup in laminar flows is important in emulsification processes and polymer blending. The influence of surfactants on droplet deformation and breakup in a plane hyperbolic flow was studied experimentally in an opposed-stream device. As in the case of simple shear flow, the inhomogeneity of the surfactant distribution along the droplet interface has a pronounced effect. Our results are qualitatively consistent with other numerical studies for droplet breakup in an axisymmetric elongational flow. Also a striking similarity is noted with other experimental observations for the deformation and breakup of polymeric drops in a quasi-steady-plane hyperbolic flow. The critical capillary number for droplet breakup in the experiments correlates with the interfacial viscoelasticity, and a reformulation of the numerical framework in terms of interfacial elasticity parameters is suggested for future numerical work including other linear flows.
    Additional Material: 10 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 174-175 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 631-640 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is described which may be used to simulate a packed column for countercurrent gas-phase controlled absorption with liquid-phase reaction. The model consists of a number of continuous stirred-tank reactors in parallel with equal volumes and mass transfer areas. A distribution is presented which uses one parameter to determine the fraction of total liquid throughput going to each reactor. The model successfully predicts all responses, including those of Kga versus time for no reaction, Kga versus inlet acid normality, and Kga versus inlet gas concentration for liquid-phase reaction for the systems ammonia-water and ammonia-sulfuric acid. It also explains the increase in mass transfer obtained by pulsing and controlled cycling.
    Additional Material: 16 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 705-710 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Preparative, multicomponent liquid chromatographic separations have been achieved by using a slowly rotating annular sorbent bed with fixed multiple feed points and fixed product withdrawal locations. The cation exchange separation of copper, nickel, and two cobalt complexes has been extensively used to study the effects of rotation rate, eluent rate, bed loading, and column size on separation performance. Experimental results have been compared with three theoretical models: plate theory, an analytical solution which incorporates multicomponent Langmuir isotherms, and an extension of the analytical solution to include dispersion effects.
    Additional Material: 7 Ill.
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