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  • Chemistry  (2)
  • Wiley-Blackwell  (2)
  • Blackwell Publishing Ltd
  • Inter Research
  • Public Library of Science
  • Springer
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Verlag/Herausgeber
  • Wiley-Blackwell  (2)
  • Blackwell Publishing Ltd
  • Inter Research
  • Public Library of Science
  • Springer
Erscheinungszeitraum
  • 1
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 13 (1980), S. 9-13 
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A study has been made of the 13C chemical shifts of a number of acyclic alkanes, alkenes, nitriles and ketones which contain quaternary carbon atoms. Similar data have also been obtained for the series of compounds involved in the synthesis of triisopropylacetic acid. Substituent effects and steric factors in these highly substituted compounds are discussed in relation to the chemical shifts.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    ISSN: 0730-6679
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Plastic bottles for carbonated beverages have many advantages over glass and metal containers. However, plastic bottles are also known to be imperfect barriers for gaseous fluids; i.e., they are semipermeable. This characteristic results in serious carbon dioxide transmission losses, particularly on the ½-L or smaller single-service bottles which have high area-to-volume ratios. Shelf life of these smaller beverage containers is therefore reduced. This article combines literature data and a simple diffusion model to predict shelf life for PET beverage bottles. As anticipated, the model shows that the smaller bottles have an unacceptable shelf life based on industrial standards. Moreover, while refrigerated temperatures increase shelf life to acceptable levels, temperatures for storage above 100°F can also reduce the 2-L bottle to less than acceptable levels. The shelf life predictions developed with the model are close to those observed in practice. Further manipulation with the model shows that a hypothetical multilayered barrier wall could be constructed which would give an acceptable shelf life at any reasonable temperature.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
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