ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The morphology of porous polysulfone hollow fibers which were spun by the dry-wet spinning process is discussed. It was demonstrated that a relatively moderate quenching medium should be employed in the bore of the nascent fiber in order to produce an isotropic fiber free of macrovoids and intrusion cells. A rather delicate quantitative balance between the internal precipitant and the spinning solution has to be maintained, especially when low-viscosity polymeric solutions are employed. Scanning electron micrographs of fiber cross sections display highly porous, spongestructured walls which in some instances exhibit a rather dense interface skin. However, control of the extrusion/coagulation procedure allows the formation of skinned, porous skinned, and nonskinned fibers.
Additional Material:
14 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1977.070210115
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