ISSN:
1572-8862
Keywords:
A linear Rh-W-Cu-W-Rh sulfide cluster
;
FAB-MS
;
EXAFS
;
X-ray crystallography
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The positive ion FAB mass spectrum of a linear trinuclear sulfide cluster, [Cp*RhP(OEt)3(μ-WS4CuCl] (1; Cp* = η5-C5Me5), shows many ions heavier than the molecular ion. One of the envelopes corresponds to a pentanuclear cationic cluster of [{Cp*RhP(OEt)3(WS4)}2Cu]+. It has been synthesized by a reaction between [Cp*RhP(OEt)3WS4] and Cu+ in a 2:1 molar ratio as the PF6 salt [{Cp*RhP(OEt)3(μ-WS4)}2Cu][PF6] (2 · PF6), which is characterized by a single-crystal X-ray diffraction, EXAFS, and IR measurements.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01165471
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