ALBERT

Description: In 2010, a wide-angle seismic reflection/refraction profile was acquired along the Hecataeus Rise, an area of shallow seabed immediately south of Cyprus in the eastern Mediterranean. The profile crossed from the Hecataeus Rise, through the Cyprus Arc to the Levantine Basin beyond. Due to the short length of the profile and the corresponding lack of deep ray coverage, velocity modelling was complemented by gravity modelling to gain constraints on deep crustal structure. The resultant model reveals velocities for the Hecataeus Rise that show no evidence of shallow ophiolites like those seen on mainland Cyprus, and the velocities are not diagnostic of a unique crustal affinity. Low-velocity sediments make up at least 7 km of the upper structure of Hecataeus Rise and these sediments overlie a two-layered crust. From the gravity modelling, the combined sediments and crust of Hecataeus Rise appear to be thinner than the Eratosthenes Seamount block to the southwest. A high-velocity lower crustal block is modelled under the seaward edge of Hecataeus Rise and, based on the gravity modelling, is inferred to extend landwards beneath the Rise. Similar high-velocity blocks were identified on the southwestern edge of Hecataeus Rise along nearby refraction lines and were interpreted as remnant Tethyan oceanic crust, foundered in the Cyprus Arc, along which subduction has ceased in this area. Given the thin two-layered crust beneath a thick accumulation of sediments modelled for Hecataeus Rise, we interpret that Hecataeus Rise represents a collage of oceanic fragments, accreted together within the failed subduction zone. Outboard of the crust of Hecataeus Rise, a 5-km deep low-velocity basin, possibly an accretionary wedge, is imaged that appears to correspond with the Cyprus Arc deformation zone imaged on both coincident and along-strike seismic reflection lines. A similar and wider feature is observed on seismic refraction lines to the west and combined, these may be revealing an eastward tapering zone of crustal deformation. To the south of the profile, the Levantine Basin appears undisturbed by the collision to the north and exhibits a uniform and homogeneous velocity structure.

Description: This study investigates pressure effects on the magnetic properties of non-interacting single-domain (SD) magnetite. Using a high-pressure cell specially designed for a Magnetic Property Measurement System, magnetic hysteresis measurements were conducted under high pressures of up to 1 GPa on natural plagioclase crystals containing much acicular SD magnetite. Coercivity and saturation magnetization were nearly constant with pressure, while saturation remanent magnetization and coercivity of remanence decreased with pressure at moderate rates of –8 per cent GPa –1 and –18 per cent GPa –1 , respectively. These results suggest that temperature effects govern the magnetic behaviour of acicular SD magnetite grains in the middle and lower crusts.

Description: We studied ionospheric responses to the 2012 April 11 M w 8.6 North Sumatra earthquake using total electron content (TEC) measurements with the regional Global Navigation Satellite System network. This earthquake ruptured the oceanic lithosphere off the Indian Ocean coast of North Sumatra, and is known as the largest strike-slip earthquake ever recorded. Coseismic ionospheric disturbances (CIDs) with rapid TEC enhancement of a few TEC units propagated northward with a speed of acoustic waves (~1 km s –1 ). Resonant atmospheric oscillation with a frequency ~4 mHz have been found as monochromatic oscillation of TEC lasting for an hour after the main shock and the largest aftershock. We compared CID amplitudes of 21 earthquakes world-wide with moment magnitudes ( M w ) 6.6–9.2. They roughly obeyed a law such that CID amplitude increases by two orders of magnitude for the M w increase of three. The 2012 North Sumatra earthquakes slightly deviated negatively from the trend possibly reflecting their strike-slip mechanisms, that is small vertical crustal movements for their magnitudes.

Description: Data on the evolution of Earth's magnetic field intensity are important for understanding the geodynamo and planetary evolution. However, the paleomagnetic record in rocks may be adversely affected by many physical processes, which must be taken into account when analysing the palaeointensity database. This is especially important in the light of an ongoing debate regarding core thermal conductivity values, and how these relate to the Precambrian geodynamo. Here, we demonstrate that several data sets in the Precambrian palaeointensity database overestimate the true paleofield strength due to the presence of non-ideal carriers of palaeointensity signals and/or viscous re-magnetizations. When the palaeointensity overestimates are removed, the Precambrian database does not indicate a robust change in geomagnetic field intensity during the Mesoproterozoic. These findings call into question the recent claim that the solid inner core formed in the Mesoproterozoic, hence constraining the thermal conductivity in the core to ‘moderate’ values. Instead, our analyses indicate that the presently available palaeointensity data are insufficient in number and quality to constrain the timing of solid inner core formation, or the outstanding problem of core thermal conductivity. Very young or very old inner core ages (and attendant high or low core thermal conductivity values) are consistent with the presently known history of Earth's field strength. More promising available data sets that reflect long-term core structure are geomagnetic reversal rate and field morphology. The latter suggests changes that may reflect differences in Archean to Proterozoic core stratification, whereas the former suggest an interval of geodynamo hyperactivity at ca. 550 Ma.

Description: Was the Yukon-Tanana Terrane (YTT), a California-sized part of south-central Yukon, an autochthonous or para-autochthonous part of northern British Columbia in the Early Cretaceous or was it part of a proposed allochthonous ‘Baja B.C.’ continent offshore of southern California? To answer this fundamental question, a paleomagnetic study has been completed on 347 specimens from 24 sites in the 114.7 ± 1.1 Ma Quiet Lake batholith. This 1300 km 2 pluton is composed mostly of massive medium-to-coarse grained biotite quartz monzonite that exhibits no evidence of either deformation or metamorphism, and that intrudes metamorphosed pre-Cretaceous basement rocks of the YTT in southern Yukon. The paleomagnetic analysis utilized thermal and alternating field step demagnetization, and saturation isothermal remanence methods. A well-defined characteristic remanent magnetization (ChRM) direction was isolated throughout the 500–585 °C temperature range at Decl. = 340.6°, Incl. = 77.4° ( N = 14 sites, k = 51.2, A 95 = 5.6°). The ChRM resides in magnetite with a low titanium content and is interpreted to be a primary thermoremanent magnetization. After correction for 490 km of geologically demonstrable dextral displacement on the inboard Tintina fault zone, the Quiet Lake batholith's paleopole is not significantly different at 95 per cent confidence from the co-eval 115 Ma reference paleopole for North America, giving non-significant translation and rotation estimates of 1.4° ± 5.1° (1) northwestwards and 10° ± 13° (1) clockwise, respectively. Thus, this is the first Early Cretaceous paleopole to show clearly that the YTT in Yukon is a para-autochthon that was part of North America's continental margin at that time. Further, after correction for Tintina fault displacement, the eight available Mesozoic YTT paleopoles agree closely with the North American apparent polar wander path (APWP). In contrast, the 22 paleopoles from the Intermontane Belt show the expected behaviour of an allochthonous thin-skin of terranes (i.e. ‘Baja B.C.’ behaviour) and record ~8° of northward translation and ~50° of clockwise rotation relative to both the YTT and North American APWPs during the Mesozoic and Paleogene.

Description: Understanding the contribution of biogenic magnetic particles into sedimentary assemblages is a current challenge in palaeomagnetism. It has been demonstrated recently that magnetic particles produced through biologically controlled mineralization processes, such as magnetosomes from magnetotactic bacteria, contribute to the recording of natural remanent magnetization in marine and lacustrian sediments. Contributions from other, biologically induced, mineralization types, which are known from multiple laboratory experiments to include magnetic minerals, remain largely unknown. Here, we report magnetic properties of iron minerals formed by a community of iron- and manganese-reducing bacteria isolated from a natural groundwater deposit during a 2 yr long incubation experiment. The main iron phases of the biomineralized mass are lepidocrocite, goethite and magnetite, each of which has environmental significance. Unlike the majority of the previous studies that reported superparamagnetic grain size, and thus no remanence carrying capacity of biologically induced magnetite, hysteresis and first-order reversal curves measurements in our study have not detected significant superparamagnetic contribution. The biomineralized mass, instead, contains a mixture of single-domain to pseudo-single-domain and multidomain magnetite particles that are capable of carrying a stable chemical remanent magnetization. Isothermal remanent magnetization acquisition parameters and first-order reversal curves signatures of the biomineralized samples deviate from previously proposed criteria for the distinction of extracellular (biologically induced) magnetic particles in mixtures. Given its potential significance as a carrier of natural remanent magnetization, environmental requirements, distribution in nature and the efficiency in the geomagnetic field recording by biologically induced mineralization need comprehensive investigation.

Description: Monthly means of the magnetic field measurements at ground observatories are a key data source for studying temporal changes of the core magnetic field. However, when they are calculated in the usual way, contributions of external (magnetospheric and ionospheric) origin may remain, which make them less favourable for studying the field generated by dynamo action in the core. We remove external field predictions, including a new way of characterizing the magnetospheric ring current, from the data and then calculate revised monthly means using robust methods. The geomagnetic secular variation (SV) is calculated as the first annual differences of these monthly means, which also removes the static crustal field. SV time-series based on revised monthly means are much less scattered than those calculated from ordinary monthly means, and their variances and correlations between components are smaller. On the annual to decadal timescale, the SV is generated primarily by advection in the fluid outer core. We demonstrate the utility of the revised monthly means by calculating models of the core surface advective flow between 1997 and 2013 directly from the SV data. One set of models assumes flow that is constant over three months; such models exhibit large and rapid temporal variations. For models of this type, less complex flows achieve the same fit to the SV derived from revised monthly means than those from ordinary monthly means. However, those obtained from ordinary monthly means are able to follow excursions in SV that are likely to be external field contamination rather than core signals. Having established that we can find models that fit the data adequately, we then assess how much temporal variability is required. Previous studies have suggested that the flow is consistent with torsional oscillations (TO), solid body-like oscillations of fluid on concentric cylinders with axes aligned along the Earth's rotation axis. TO have been proposed to explain decadal timescale changes in the length-of-day. We invert for flow models where the only temporal changes are consistent with TO, but such models have an unacceptably large data misfit. However, if we relax the TO constraint to allow a little more temporal variability, we can fit the data as well as with flows assumed constant over three months, demonstrating that rapid SV changes can be reproduced by rather small flow changes. Although the flow itself changes slowly, its time derivative can be locally (temporally and spatially) large, in particular when and where core surface secular acceleration peaks. Spherical harmonic expansion coefficients of the flows are not well resolved, and many of them are strongly correlated. Averaging functions, a measure of our ability to determine the flow at a given location from the data distribution available, are poor approximations to the ideal, even when centred on points of the core surface below areas of high observatory density. Both resolution and averaging functions are noticeably worse for the toroidal flow component, which dominates the flow, than the poloidal flow component, except around the magnetic equator where averaging functions for both components are poor.

Description: The electrical rock conductivity is a sensitive indicator for carbon dioxide (CO 2 ) injection and migration processes. For a reliable balancing of the free CO 2 in pore space with petrophysical models such as Archie's law or for the detection of migrating CO 2 , detailed knowledge of the pore water conductivity during interaction with CO 2 is essential but not available yet. Contrary to common assumptions, pore water conductivity cannot be assumed constant since CO 2 is a reactive gas that dissolves into the pore water in large amounts and provides additional charge carriers due to the dissociation of carbonic acid. We consequently carried out systematic laboratory experiments to quantify and analyse the changes in saline pore water conductivity caused by CO 2 at thermodynamic equilibrium. Electrical conductivity is measured on pore water samples for pressures up to 30 MPa and temperatures up to 80 °C. The parameter range covers the gaseous, liquid and supercritical state of the CO 2 involved. Pore water salinities from 0.006 up to 57.27 g L –1 sodium chloride were investigated as well as selective other ion species. At the same time, the CO 2 concentration in the salt solution was determined by a wet-chemical procedure. A two-regime behaviour appears: for small salinities, we observe an increase of up to more than factor 3 in the electrical pore water conductivity, which strongly depends on the solution salinity (low-salinity regime). This is an expected behaviour, since the additional ions originating from the dissociation of carbonic acid positively contribute to the solution conductivity. However, when increasing salinities are considered this effect is completely diminished. For highly saline solutions, the increased mutual impeding causes the mobility of all ions to decrease, which may result in a significant reduction of conductivity by up to 15 per cent despite the added CO 2 (high-salinity regime). We present the data set covering the pressure, temperature, salinity and ion species dependence of the CO 2 effect. Furthermore, the observations are analysed and predicted with a semi-analytical formulation for the electrical pore water conductivity taking into account the species’ interactions. For the applicability of our results in practice of exploration and monitoring, we additionally provide a purely empirical formulation to compute the impact of CO 2 on pore water conductivity at equilibrium which only requires the input of pressure, temperature and salinity information.

Description: We study rotating thermal convection in spherical shells as prototype for flow in the cores of terrestrial planets, gas planets or in stars. We base our analysis on a set of about 450 direct numerical simulations of the (magneto)hydrodynamic equations under the Boussinesq approximation. The Ekman number ranges from 10 –3 to 10 –5 . The supercriticality of the convection reaches about 1000 in some models. Four sets of simulations are considered: non-magnetic simulations and dynamo simulations with either free-slip or no-slip flow boundary conditions. The non-magnetic setup with free-slip boundaries generates the strongest zonal flows. Both non-magnetic simulations with no-slip flow boundary conditions and self-consistent dynamos with free-slip boundaries have drastically reduced zonal-flows. Suppression of shear leads to a substantial gain in heat-transfer efficiency, increasing by a factor of 3 in some cases. Such efficiency enhancement occurs as long as the convection is significantly influenced by rotation. At higher convective driving the heat-transfer efficiency tends towards that of the classical non-rotating Rayleigh–Bénard system. Analysis of the latitudinal distribution of heat flow at the outer boundary reveals that the shear is most effective at suppressing heat-transfer in the equatorial regions. Simulations with convection zones of different thickness show that the zonal flows become less energetic in thicker shells, and, therefore, their effect on heat-transfer efficiency decreases. Furthermore, we explore the influence of the magnetic field on the non-zonal flow components of the convection. For this we compare the heat-transfer efficiency of no-slip non-magnetic cases with that of the no-slip dynamo simulations. We find that at E = 10 –5 magnetic field significantly affects the convection and a maximum gain of about 30 per cent (as compared to the non-magnetic case) in heat-transfer efficiency is obtained for an Elsasser number of about 3. Our analysis motivates us to speculate that convection in the polar regions in dynamos at E = 10 –5 is probably in a ‘magnetostrophic’ regime.

Description: A spatially averaged mean-field model for fully or partially ordered members of the ilmenite–hematite solid solution series is rigorously derived from the Heisenberg Hamiltonian by first assuming no temporal correlation of atomic spins, and then by spatially averaging over spins at equivalent atomic positions. The model is based on the geometry of exchange interactions between nearest and next-nearest neighbours and predicts magnetization curves in homogenous solid solutions with variable degree of order. While the general framework presented can also be applied to atomic scale models, and to other solid solution series, here the symmetries of the ilmenite–hematite lattice are exploited to show that four different sublattice magnetizations and six independent combinations of exchange constants determine the temperature variation of the magnetization curves. Comparing measured Curie temperatures T C and M s ( T ) curves to model predictions results in accurate constraints for these combinations. It is also possible to calculate predictions for high-field magnetization slopes HF , which not only improve accurate experimental determination of the Curie temperature but also provide a new magnetic method to estimate the order parameter for ilmenite–hematite solid solution samples.