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  • Polymer and Materials Science  (4)
  • Wiley-Blackwell  (4)
  • American Physical Society
  • Geological Society of America (GSA)
  • Oxford University Press
Collection
Publisher
  • Wiley-Blackwell  (4)
  • American Physical Society
  • Geological Society of America (GSA)
  • Oxford University Press
Years
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 289-303 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dynamic shear experiments in the linear range of deformation and extensional tests at constant strain rate have been carried out on a linear low-density polyethylene (LLDPE) melt and on two branched low-density polyethylene (LDPE) melts with different amounts of long-chain branching. Both the dynamic shear moduli and the tensile stress obey the time-temperature superposition principle. A simple model based on a nonaffine generalized Maxwell model with two relaxation times is proposed to describe the rheological behavior in elongation of these melts. Close agreement between the model and the experimental data can be obtained by adjusting the two relaxation times and the “slip parameter” of entanglements. The variations of these parameters with strain rate and their relationship with molecular structure are discussed.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 29 (1991), S. 933-943 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Viscoelastic properties of styrene-co-methyl methacrylate random copolymers have been determined over a temperature range covering the glass transition, the rubbery plateau, and the terminal zone and compared with polystyrene and polymethyl methacrylate homopolymers. Nonlinear behavior was observed in the variations of most of the physical and rheological characteristics with the methyl methacrylate content in the copolymer. Results are interpreted in terms of the rupture of polar-polar intermolecular interactions between ester groups due to the presence of styrene units.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 25 (1987), S. 295-310 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Extensional tests at constant strain rate \documentclass{article}\pagestyle{empty}\begin{document}$ \dot \varepsilon $\end{document} have been carried out on polystyrene melts with different molecular weight distributions at various temperatures and strain rates. The true tensile stress is found to be well approximated by the sum of two contributions: (1) a neo-Hookean expression involving the recoverable strain and (2) a contribution rapidly reaching a steady-state value. Two experimental parameters can be defined: an elasticity modulus \documentclass{article}\pagestyle{empty}\begin{document}$ G(\dot \varepsilon ) $\end{document} from (1) and a viscosity \documentclass{article}\pagestyle{empty}\begin{document}$ \eta _{\rm v} (\dot \varepsilon ) $\end{document} from (2). It is further shown that time-temperature equivalence applies not only to the stress but also to the recoverable strain and to G and ηv. The dependence of G and ηv on strain rate is then discussed. For high strain rates, G is close to the linear viscoelastic plateau modulus of PS melts and decreases with decreasing strain rate. The value of ηv is found to a good approximation to be equal to three times the shear viscosity taken at a shear rate equivalent to the elongational strain rate.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 6 (1995), S. 301-308 
    ISSN: 1042-7147
    Keywords: polymer blends ; melt rheology ; crosslinked rubber ; structured latex ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The linear viscoelastic behavior of model rubbertoughened polymer melts has been studied. The most significant influence of the dispersed crosslinked rubber phase on the melt rheology of the blends is the existence of a secondary plateau for the storage modulus G′ at low frequencies. This behavior was ascribed to a percolation phenomenon, leading to the formation of a threedimensional network of inclusions, and contributing to the elasticity at low frequencies of the blend. Two different systems were investigated: (a) a polystyrene matrix with crosslinked and structured latex particles and (b) silicon oil matrices with homogeneous crosslinked PMMA particles. An initial shearing history was found to influence the dynamic mechanical properties of the molten blends and in particular to lower the lowfrequency plateau value for G′. During a subsequent annealing, the plateau modulus increases again. These results are in agreement with the assumption of a particle network.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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