ALBERT

Description: The quantification of heat and mass flow between deep reservoirs and the surface is important for understanding magmatic and hydrothermal systems. Here, we use high-resolution measurement of carbon dioxide flux (ϕCO 2 ) and heat flow at the surface to characterize the mass (CO 2 and steam) and heat released to the atmosphere from two magma-hydrothermal systems. Our soil gas and heat flow surveys at Rotokawa and White Island in the Taupō Volcanic Zone, New Zealand, include over 3,000 direct measurements of ϕCO 2 and soil temperature and 60 carbon isotopic values on soil gases. Carbon dioxide flux was separated into background and magmatic/hydrothermal populations based on the measured values and isotopic characterization. Total CO 2 emission rates (ΣCO 2 ) of 441 ± 84 t d -1 and 124 ± 18 t d -1 were calculated for Rotokawa (2.9 km 2 ) and for the crater floor at White Island (0.3 km 2 ), respectively. The total CO 2 emissions differ from previously published values by +386 t d -1 at Rotokawa and +25 t d -1 at White Island, demonstrating that earlier research underestimated emissions by 700% (Rotokawa) and 25% (White Island). These differences suggest that soil CO 2 emissions facilitate more robust estimates of the thermal energy and mass flux in geothermal systems than traditional approaches. Combining the magmatic/hydrothermal-sourced CO 2 emission (constrained using stable isotopes) with reservoir H 2 O:CO 2 mass ratios and the enthalpy of evaporation, the surface expression of thermal energy release for the Rotokawa hydrothermal system (226 MW t ) is 10 times greater than the White Island crater floor (22.5 MW t ).

Description: Rocks from the 23 Ma Lake City caldera show diverse chemical affinities attesting to a complex magmatic system beneath the caldera. Field and geochemical data from ignimbrites and intrusions constrain magma storage and magma interactions during the formation of the caldera. Two geochemically distinct magma batches erupted during caldera formation: batch A, consisting of rhyolites and trachytes, and batch B, consisting of dacites and trachyandesites. The ignimbrites of the Lower, Middle, and Upper Sunshine Peak Tuff represent the bulk of erupted batch A magma, with an increasing proportion of trachyte to rhyolite as the eruption progressed. Overall, the observed trends of major and trace elements are consistent with the sequential eruption of a magmatic system with a rhyolitic upper portion and trachytic lower portion. The Middle Sunshine Peak Tuff contains two distinct types of pumice clast, while the Upper Sunshine Peak Tuff contains four distinct pumice clast types, with one type chemically related to batch B magma. The link between the rhyolite and trachyte of batch A is supported by major- and trace-element geochemical modeling of an initially trachytic magma that fractionated and was subjected to crystal/melt segregation following 50%–60% crystallization. Compositional gaps and chemical heterogeneity in the bulk ignimbrite composition show that the proportions of these different magma types varied significantly during eruption. We propose that the fractionating batch A and B magmas formed distinct magma pods, some containing residual magma mush, that were tapped during different phases of caldera formation. After collapse, dacite lavas of batch B were erupted concurrent with resurgent uplift from shallow intrusion of both residual mingled batch A and batch B magma. In summary, our observations suggest (1) a complex magma chamber geometry from two fractionating magma batches, and (2) magma replenishment and accelerated periods of magma reorganization in the shallow magma plumbing system during a single caldera cycle at Lake City.

Description: A series of Cu-substituted goethites, single and co-substituted with Cr, Zn, Cd and/or Pb was prepared, having molar ratios equal to 2.00, 3.33 and 5.00 mol%. All the samples contained only goethite, except Cu-, (Cu,Zn)- and (Cu,Pb)-samples synthesized at 5.00 mol% where hematite was also formed. The presence of Cr/Cd suppressed the hematite-forming effects of Cu. The general sequence of metal entry into the single-metal-substituted goethites was Zn = Cr 〉 Cd 〉 Cu 〉 Pb and in di- (5.00 mol%) and tri- (3.33 mol%) metal-substituted goethites was Cu 〉 Zn 〉 Cd 〉 Cr 〉〉 Pb. Cu incorporation increased all the unit-cell parameters in single-metal-substituted goethite, and these parameters increased in combination with other metals as follows: Cd 〉 Zn 〉 Cr 〉 Pb in the multimetal-substituted goethites. The Cu-substituted goethite dissolved faster than pure goethite. Co substitutions of Cr/Pb reduced the dissolution rate (kFe), while substitutions of Cd/Zn increased kFe.