Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
107 (1997), S. 7397-7401
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The monomer–monomer surface reaction model with an adsorbate interaction term is studied. An epidemic analysis of the poisoning times (tp) for small square lattices as a function of lattice edge length L and interaction strength α at the point of equal adsorption rates yields a dynamic scaling relation which describes the crossover between log-power-law and exponential behavior in L, and is able to fit the entire dependence of tp upon α and L. The phase transition is further explored by varying adsorption rates and is found to follow second-order kinetics. A mean-field approximation is introduced as a comparison for the numerical results. © 1997 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.474977
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