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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 6881-6886 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The surface roughening of a silicon wafer during annealing in argon at an extremely low oxygen partial pressure, which restricts the conditions for the suppression of oxidation-induced stacking faults, was investigated. It was found that surface roughening occurs when the oxygen partial pressure is lower than 3×10−5 atm. The roughening is brought about by the generation of square pits and the anomalous growth of film. Fiber-like material is, sometimes, formed in the periphery of the wafer. It was found that grown film and the fiber-like material are SiO2 and that the pits have the shape of an inverted pyramid. The mechanism of this roughening is discussed with considering a boundary layer. As a result, the formation of the inverted-pyramidal pits is attributed to the occurrence of SiO evaporation in the boundary layer, where the gas flow is stagnant and the oxygen partial pressure is extremely low. The four exposed surfaces at the bottom of a pit have a {111} surface orientation. The anomalous growth of the oxide and the formation of the fiber-like material were interpreted to be due to the reoxidation of the evaporating SiO at the edge of the boundary layer and its redeposition in the form of SiO2 on the wafer. It was concluded that the inclusion of oxygen at a partial pressure higher than 4×10−5 atm is important to prevent surface roughening during annealing even in an inert gas like argon. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 1141-1148 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effect of the oxygen partial pressure during annealing under argon on the generation and growth of defects that adversely affect the yield and reliability of thermally grown oxide was investigated by precisely and widely controlling the oxygen partial pressure. Below the critical oxygen partial pressure of 6×10−3 atm, the generation of oxidation-induced stacking faults (OSFs) during a subsequent oxidation step was effectively suppressed from the density of about 103 cm−2 to less than 20 cm−2. Annealing for 10 min under an appropriate oxygen partial pressure was shown to be sufficient for annihilation of the origin of OSF and this effect continued even during a subsequent oxidation in dry oxygen. Mechanism by which the generation of OSFs is suppressed was discussed considering the oxidation mechanism under the reduced oxygen partial pressures. It is suggested that electric field that builds across the oxide layer when the oxygen partial pressure is below the critical value causes silicon interstitials and impurities such as metals to drift from the substrate to the outer surface of the oxide. During the annealing origins of OSFs such as Si–O clusters and metallic impurities are eliminated and mechanical damage is also annealed out before climbing to be the nuclei of OSFs. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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