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  • American Institute of Physics (AIP)  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 7174-7179 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Determination of electric dipole moments on SO2 molecules in the region of the A˜ 1A2 and B˜ 1B1 states is reported. The Stark splittings and shifts of single rovibronic lines in several vibronic bands were measured by high-resolution laser spectroscopy in a supersonic molecular beam. Electric-field strengths of up to 12 kV/cm were applied. The dipole moment of the A˜ 1A2 state was determined to be 1.79(5) D, whereas an indication of a clearly smaller dipole moment was found for the B˜ 1B1 state.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 6391-6396 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: High resolution ultraviolet spectroscopy of SO2 in a cold supersonic beam is reported. The behavior of single rovibronic lines of the E band (305 nm) and the 322 nm band was investigated in an electric field of up to 12 kV/cm. The dipole moment of the 1 A1 state was determined to be 1.85 (0.03) D. Problems of the dipole determination in SO2 are discussed.
    Type of Medium: Electronic Resource
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