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  • 1
    Publication Date: 2015-08-21
    Description: Solid-state dewetting is used to fabricate supersaturated, submicron-sized Au-Ni solid solution particles out of thin Au/Ni bilayers by means of a rapid thermal annealing technique. Phase separation in such particles is studied with respect to their equilibrium crystal (or Wulff) shape by subsequent annealing at elevated temperature. It is found that {100} faceting planes of the equilibrated particles are enriched with Ni and {111} faces with Au. Both phases are considered by quantum-mechanical calculations in combination with an error-reduction scheme that was developed to compensate for a missing exchange-correlation potential that would reliably describe both Au and Ni. The observed phase configuration is then related to the minimization of strongly anisotropic elastic energies of Au- and Ni-rich phases and results in a rather unique nanoparticle composite state that is characterized by nearly uniform value of elastic response to epitaxial strains all over the faceted surface. The same conclusion is yielded also by evaluating bi-axial elastic moduli when employing interpolated experimental elastic constants. This work demonstrates a useful route for studying features of physical metallurgy at the mesoscale.
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 2
    Publication Date: 2015-09-26
    Description: In this work, we present the terrace etching technique to obtain excessive thickness series of atomic layer deposition (ALD) grown Al 2 O 3 and HfO 2 on GaN-cap/AlGaN/GaN heterostructures allowing for the detailed study of oxide charge distribution and its impact of the metal-insulator-semiconductor high electron mobility transistor (MISHEMT) threshold voltage. By modeling the experimental plot of threshold voltage versus oxide thickness on the basis of experimentally determined two-dimensional electron gas charge density in AlGaN/GaN MISHEMTs, we separated the interface and bulk charge components and determined the oxide-metal barrier height for the investigated gate dielectrics. In both Al 2 O 3 and HfO 2 gate dielectrics, the oxide charges are mainly located at the oxide/GaN interface. Determining the interface trap charges from comparison of the pulsed capacitance-voltage (CV) technique with very fast voltage sweep to the modulation type CV method with slow DC voltage ramp, we extracted positive fixed charges of N Ox = 2.7 × 10 12  cm −2 for Al 2 O 3 and N Ox = 7.8 × 10 12  cm −2 for HfO 2 . We found a strong V th shift of opposite direction for both high-k materials, corresponding to negatively charged up trap states at the HfO 2 /GaN interface and positively charged up trap states at the Al 2 O 3 /GaN interface. The evaluation of the metal-oxide barrier height in dependence of the metal work function followed the trend of the Schottky model, whereas HfO 2 showed less Fermi level pinning compared to Al 2 O 3 indicating the presence of an increased number of interface states in Al 2 O 3 on GaN.
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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