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Stimulated emission pumping spectroscopy of jet-cooled C3 (1989)

Rohlfing, Eric A. ; Goldsmith, J. E. M.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 90 (1989), S. 6804-6805

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: We report a dispersed fluorescence spectrum obtained for excitation of a ∑+u–∑+g vibronic band of C3 at 33 588 cm−1, part of a newly discovered electronic system. Rotationally resolved stimulated-emission-pumping spectra of jet-cooled C3 using this ∑+u intermediate state are presented for dumping to the 0v121 (1≤v2≤13) and 6v121 (1≤v2≤5) levels in the 1Σ+g ground state. Vibrational term energies, rotational constants, and l-type doubling parameters are determined for each level.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.456300

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