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  • Artikel  (59)
  • Wiley  (43)
  • Wiley-Blackwell  (13)
  • American Institute of Physics (AIP)  (3)
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  • Artikel  (59)
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  • 1
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 27-33 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Electron excitation temperatures have been measured in a low-pressure (0.05-Torr Cs, 2-Torr total pressure) argon-cesium discharge that uses a heated cathode (900–1100 K). The excitation temperature determinations are based upon a model that allows calculation of cesium excited state densities for low electron density (〈1011 cm−3). The model assumes that the dominant creation processes for excited states are electron impact excitation from the ground state and radiative cascade from higher levels, while destruction is by spontaneous emission. Maxwellian electron energy distributions were used and the plasmas were considered to be optically thin. The model indicates that cascade contributions to the production of excited states can be as high as 50% for some cesium levels. Predicted emission spectra with cascade contributions to spontaneous emission intensities agree well with measured spectra except for radiation trapped transitions from low nP states to the ground state. Excitation temperatures are determined by fitting measured and calculated spectra.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 7319-7330 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The gas phase infrared spectra of the hydrated hydronium cluster ions H3O+⋅(H2O)n(n=1, 2, 3) have been observed from 3550 to 3800 cm−1. The new spectroscopic method developed for this study is a two color laser scheme consisting of a tunable cw infrared laser with 0.5 cm−1 resolution used to excite the O–H stretching vibrations and a cw CO2 laser that dissociates the vibrationally excited cluster ion through a multiphoton process. The apparatus is a tandem mass spectrometer with a radio frequency ion trap that utilizes the following scheme: the cluster ion to be studied is first mass selected; spectroscopic interrogation then occurs in the radio frequency ion trap; finally, a fragment ion is selected and detected using ion counting techniques. The vibrational spectra obtained in this manner are compared with that taken previously using a weakly bound H2 "messenger.'' A spectrum of H7 O+3 taken using a neon messenger is also presented. Ab initio structure and frequency predictions by Remington and Schaefer are compared with the experimental results.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 2328-2329 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: Infrared spectra of hydrated hydronium ions weakly bound to an H2 molecule, specifically H7O+3 ⋅H2 and H9O+4 ⋅H2, have been observed. Mass-selected parent ions, trapped in a radio frequency ion trap, are excited by a tunable infrared laser; following absorption, the complex predissociates with loss of the H2, and the resulting fragment ions are detected. Spectra have been taken from 3000 to 4000 cm−1, with a resolution of 1.2 cm−1. They are compared to recent theoretical and experimental spectra of the hydronium ion hydrates alone. Binding an H2 molecule to these clusters should only weakly perturb their vibrations; if so, our spectra should be similar to spectra of the hydrated hydronium ions H7O+3 and H9O+4.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 82 (1913), S. 278-282 
    ISSN: 0863-1778
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 80 (1913), S. 93-103 
    ISSN: 0863-1778
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Aus den Versuchen ergibt sich, daß Cuprohydrid bei der Reaktion zwischen Kupfersulfat und unterphosphoriger Säure entsteht, daß aber die Reinheit des Produktes von begrenzten Versuchsbedingungen, besonders von Temperatur und Zeit abhängt. Die Versuche bei gewöhnlicher Temperatur zeigen, daß nach mehrstündigem Stehen das Produkt Hydrid und Oxyd enthält, und auf die Koexistenz dieser beiden Stoffe ist die Explosionsfähigkeit der trockenen Substanz bei Berührung mit Luft zurückzuführen.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1441-1445 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An hypothesis is proposed to explain the origin of short-lived sites observed in nucleate pool boiling. Conditions are postulated under which microbubbles might circulate into the superheated liquid region and serve as the source of these nucleation sites. Consequences of this possible mechanism are examined for explanations of hysteresis effects and scatter of results in boiling research.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1229-1230 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1605-1613 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The behavior of active boiling site populations was monitored for pool boiling on an electrically heated 1-mil stainless steel sheet. The boiling sites were located using a high-speed infrared camera focused on the underside of the boiling surface. Experiments were conducted to determine factors affecting the origin, concentration, and lifetime of active sites.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 75-80 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Local boiling heat transfer coefficients were experimentally determined for nucleate boiling around the outer circumference of horizontal copper tubing. The tubes used were of 16 B.W.G. hard-temper copper with outside diameters of 1 1/4 and 2 in; the liquids boiled were methanol and n-hexane. The maximum peripheral variation occurred with the 1 1/4-in. tube in methanol where an over-all ΔT of 30.2°F. gave local outside coefficients varying between 249 and 548 B.t.u./(hr.)(sq. ft.)(°F.). The minimum variation was found to occur in the same system, in which an over-all ΔT of 72.3°F. gave coefficients varying between 856 and 910 B.t.u./(hr.)(sq. ft.)(F.°). The results, plotted in polar coordinates, showed a cardioid configuration for methanol with the maximum coefficients occurring at the bottom of the tube. The n-hexane results had the general shape of horizontal ellipses with maximum coefficients occurring at the sides of the tube.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 34-38 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A study was made of the effects the surface tension of aqueous solutions of surface-active agents had on the bubble-formation characteristics of these solutions. Bubbles were formed by two processes: by passing air through a horizontal orifice submerged in the solution and by nucleate boiling at an electrically heated surface. The experimental measurements taken with the air-bubble system were used to determine the nature of the surface-tension effect on air-bubble formation. This knowledge was then applied to the interpretation of boiling measurements made with the same solutions. The boiling coefficients of the Tergitol-water solution were found to vary inversely with dynamic surface tension. Boiling coefficients for Aerosol-water solutions, however, varied in a manner which could not be related to surface-tension effects.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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