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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 5429-5435 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: High-pressure effects on vibrational modes have been investigated in crystals of squaric acid H2C4O4 (H2SQ) and its deuterated analog (D2SQ) which show two-dimensional networks of hydrogen bonds. Specific vibrational modes in Raman and infrared spectra were observed to anomalously disappear with the application of pressures above 30 kbar in H2SQ, but not in D2SQ, indicating that the H2SQ molecule in crystal shows the asymmetric (C1h)-to-centrosymmetric (C4h) structure change. This is possibly caused by pressure-induced deformation of the correlated proton potential essentially from the double-well to single-well type.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 8507-8513 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Infrared (IR) and visible absorbance spectra were measured as a function of hydrostatic pressure for five kinds of organic crystals composed of hydrogen-bonded molecular chains. An unconventional vibrational band is observed in the IR spectra around 1800 cm−1 commonly in these compounds and its intensity rapidly increases with pressure. We have ascribed the observed band to a proton vibration localized around kink-type defects or solitons in the hydrogen-bonded molecular chains. In accordance with the pressure-induced growth of the IR band, a new electronic absorption band appears in the visible region below the ordinary molecular excitation, suggesting a change in the electronic structures within the molecules around the soliton.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 2244-2251 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have investigated effects of random substitution of proton sites with deuterons on the temperature- and pressure-induced phase transitions in squaric acid crystal, which consists of ferroelectrically ordered molecular sheets of [C4O4]2−(SQ2−) skeletons and intervening protons or deuterons. In the isotopically mixed crystals (H1−xDx )2SQ, the critical temperature Tc for the dielectric phase transition was found to increase linearly with the deuterium concentration x, while the critical pressure Pc increases nonlinearly with x at 300 K. Around the pressure ∼20 kbar above Pc , the constituent SQ2− skeletons in the paraelectric phase show a symmetry change from the asymmetric (C1h ) to centrosymmetric (C4h ) form, which is likely caused by the deformation of the correlated proton (deuteron) potential.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 6857-6862 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The impurity (Cr3+)-doping effect on the stability of charge and orbital ordering has been systematically investigated for Nd1/2Ca1/2Mn1−yCryO3 crystals by measurements of magnetotransport and x-ray diffraction. The random field in terms of eg orbital deficiencies on the Cr sites drives the charge and orbital correlations to dynamical and short range, which is most relevant to the high-resistive state exhibiting colossal magnetoresistance. In the Cr-doped manganite, we can observe the coexistence of ferromagnetic–metallic and charge–orbital ordered phases, their spatial distributions, diffuse x-ray scattering, magnetic-field annealing, and the aging effect on the magnetic and electric properties, etc. These phenomena are reminiscent of those of relaxor ferroelectrics composed of ferroelectric clusters embedded in a paraelectric matrix. We propose that the mixed-valent manganite can be viewed as a "magneto- and electrorelaxor." © 2001 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 3362-3366 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Luminescence spectra and their variation with temperature have been investigated for solid films of poly(methylphenylsilane) and its branched analogs. Introduction of branching points to the polymers enhances the broad luminescence band in the visible region while suppressing the sharp UV luminescence band due to the resonant recombination of the exciton. The intensity of the visible luminescence is observed to keep on increasing with decreasing temperature in contrast with the nearly temperature-independent intensity of the resonant luminescence. The behavior is interpreted in terms of phonon-assisted tunneling between luminescence centers and nonradiative ones. © 1995 American Institute of Physics.
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  • 6
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Phenomena of colossal magnetoresistance (MR) or magnetic field induced insulator–metal (I–M) transitions have been investigated for single crystals of perovskite-type manganese oxides with controlled carrier density and one-electron bandwidth. In addition to the canonical MR behavior near the Curie temperature, the first-order phase transition accompanying several orders of magnitude change in resistivity has been observed under an external magnetic field for many of the composition-controlled crystals as an intrinsic bulk phenomenon. It was proved by the systematic experimental investigations that the field-induced destruction of the charge-ordered state accompanying the lattice structural as well as metamagnetic transition is a major origin of such a colossal MR. Versatile MR phenomena and I–M phase diagrams in the T–H plane are presented with their interpretation. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 58 (1991), S. 2018-2020 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: New GaAs quantum dot structures, called tetrahedral quantum dots (TQDs), are proposed to make a zero-dimensional electron-hole system. The TQDs are surrounded by crystallographic facets fabricated using selective area metalorganic chemical vapor deposition (MOCVD) on (111)B GaAs substrates. The calculated energy sublevel structures of zero-dimensional electrons in a GaAs TQD show large quantum size effects, because electrons are confined three dimensionally. GaAs and AlGaAs tetrahedral facet structures on (111)B GaAs substrates partially etched into a triangular shape were grown using MOCVD. Tetrahedral growth with {110} facets occurs in the triangular areas. The cathodoluminescence intensity map for GaAs tetrahedrons buried in AlGaAs shows the tetrahedral dot array.
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 57 (1990), S. 804-806 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The mobility modulation effect of AlAs/GaAs fractional layer superlattices in an AlGaAs/GaAs modulation-doped structure, which is used for quantum wire and electron wave interference transistors, is investigated by measuring their sheet electron concentration (ns). The ns obtained by the Shubnikov–de Haas oscillation is the number of high-mobility electrons. On the other hand, the ns calculated from structural parameters is the total number of the high- and low-mobility electrons. The relationship between the electron mobility and ns is found to be μ∝(ns − nc)γ, where γ=1 and nc=5.9×1011 cm−2. The mobility modulation part in the transconductance exceeds the electron concentration modulation part by a factor of 3.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 57 (1990), S. 2101-2103 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The AlAs/GaAs fractional superlattice in an AlGaAs/GaAs modulation-doped structure, which is used for quantum wire transistors and electron wave interference transistors, is investigated from the viewpoint of the electronic state. A threshold voltage (Vth) difference of 0.27 V between the quantum wire and electron wave interference transistor indicates a periodic potential amplitude of 10 meV. Vth of both these transistors and the flatband voltage (Vfb) calculated from the gate capacitance are obtained at various temperatures between 4.2 and 100 K. The density of states (DOS) is determined from the temperature dependence for Vth of both transistors and Vfb. A DOS below the bottom of the well in the periodic potential is one dimensional, but a DOS between the bottom of the well and the top of the barrier in the periodic potential is two dimensional.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 52 (1988), S. 1901-1903 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An orthorhombic-to-tetragonal phase transformation in YLaxBa2−xCu3O7 has been observed as a function of x, but with the same oxygen concentration, from x-ray powder diffraction data. Compounds with x≤0.37 have Tc in the 93–53 K range and are orthorhombic, while compounds with x≥0.45 have Tc≤42 K and are tetragonal. An analysis of the YLa0.6Ba1.4Cu3O6.99 diffraction pattern suggests that the tetragonal structure is closely related to those of the orthorhombic YBa2Cu3O7 and the tetragonal YBa2Cu3O6 with a partial substitution of La3+ ion on the Ba2+ site and a disorder of oxygen atoms at the midpoints of both a and b unit cell edges.
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