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  • 1
    Publication Date: 2016-06-07
    Description: Unstrained Ge 1−x Sn x layers of various Sn concentration (1.5%, 3%, 6% Sn) and Ge 0.97 Sn 0.03 layers with built-in compressive (ε = −0.5%) and tensile (ε = 0.3%) strain are grown by molecular beam epitaxy and studied by electromodulation spectroscopy (i.e., contactless electroreflectance and photoreflectance (PR)). In order to obtain unstrained GeSn layers and layers with different built-in in-plane strains, virtual InGaAs substrates of different compositions are grown prior to the deposition of GeSn layers. For unstrained Ge 1−x Sn x layers, the pressure coefficient for the direct band gap transition is determined from PR measurements at various hydrostatic pressures to be 12.2 ± 0.2 meV/kbar, which is very close to the pressure coefficient for the direct band gap transition in Ge (12.9 meV/kbar). This suggests that the hydrostatic deformation potentials typical of Ge can be applied to describe the pressure-induced changes in the electronic band structure of Ge 1−x Sn x alloys with low Sn concentrations. The same conclusion is derived for the uniaxial deformation potential, which describes the splitting between heavy-hole (HH) and light-hole (LH) bands as well as the strain-related shift of the spin-orbit (SO) split-off band. It is observed that the HH, LH, and SO related transitions shift due to compressive and tensile strain according to the Bir-Pikus theory. The dispersions of HH, LH, and SO bands are calculated for compressive and tensile strained Ge 0.97 Sn 0.03 with the 8-band kp Hamiltonian including strain effects, and the mixing of HH and LH bands is discussed. In addition, the dispersion of the electronic band structure is calculated for unstrained Ge 1−x Sn x layers (3% and 6% Sn) at high hydrostatic pressure with the 8-band kp Hamiltonian, and the pressure-induced changes in the electronic band structure are discussed.
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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  • 2
    Publication Date: 2015-03-14
    Description: An integrated Ge photodetector of very low dark current density is demonstrated in an optoelectronic integrated circuit label-free biosensing system. The sensor system consists of a microring for optical sensing and a monolithically integrated Ge detector. For point-of-care applications, integration of Ge detector increases the reliability of measurement by eliminating mechanical-optical alignment of output signals. Optimizing Ge detector performance will further enhance system signal-noise ratio and reliability. For homogeneous sensing, the system has a sensitivity of ∼18.8 nm/RIU and a detection limit of 3.50 × 10 −5 .
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 3
    Publication Date: 2014-10-18
    Description: We present the catalyst-free growth of binary Bi 2 Te 3 topological insulator nanostructures on c -plane sapphire substrates by molecular beam epitaxy. Dense arrays of single-crystalline nanostructures, growing along the [110] direction, are obtained for substrate temperatures ranging from ∼180 °C to 260 °C. The growth rate and shape of the nanostructures are highly temperature-dependent. The microscopic study of the nanostructures and their relationship to the underlying Bi 2 Te 3 thin film gives an insight into the growth mechanism.
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 4
    Publication Date: 2014-09-25
    Description: Materials with layered van der Waals crystal structures are exciting research topics in condensed matter physics and materials science due to outstanding physical properties associated with their strong two dimensional nature. Prominent examples include bismuth tritelluride and triselenide topological insulators (TIs), which are characterized by a bulk bandgap and pairwise counter-propagating spin-polarized electronic surface states. Angle-resolved photoemission spectroscopy (ARPES) of ex-situ grown thin film samples has been limited by the lack of suitable surface preparation techniques. We demonstrate the shortcomings of previously successful conventional surface preparation techniques when applied to ternary TI systems which are susceptible to severe oxidation. We show that in-situ cleaving is a simple and effective technique for preparation of clean surfaces on ex-situ grown thin films for high quality ARPES measurements. The method presented here is universally applicable to other layered van der Waals systems as well.
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 5
    Publication Date: 2016-02-12
    Description: The development of a precise micromachining process for Ge 1– x Sn x has the potential to enable both the fabrication and optimization of Ge 1− x Sn x -based devices in photonics and microelectromechanical systems. We demonstrate a digital etching scheme for Ge 0.922 Sn 0.078 based on a two-stage, highly selective CF 4 plasma dry etch and HCl wet etch. Using X-Ray Reflectivity, we show consistent etch control as low as 1.5 nm per cycle, which is defined as one dry etch step followed by one wet etch step. The etch rate increases to 3.2 nm per cycle for a longer dry etch time due to physical sputtering contributions, accompanied by an increase in RMS surface roughness. By operating within a regime with minimal sputtering, we demonstrate that good digital etch depth control and surface quality can be achieved using this technique.
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 6
    Publication Date: 2015-11-04
    Description: Breaking time-reversal symmetry through magnetic doping of topological insulators has been identified as a key strategy for unlocking exotic physical states. Here, we report the growth of Bi 2 Te 3 thin films doped with the highest magnetic moment element Ho. Diffraction studies demonstrate high quality films for up to 21% Ho incorporation. Superconducting quantum interference device magnetometry reveals paramagnetism down to 2 K with an effective magnetic moment of ∼5  μ B /Ho. Angle-resolved photoemission spectroscopy shows that the topological surface state remains intact with Ho doping, consistent with the material's paramagnetic state. The large saturation moment achieved makes these films useful for incorporation into heterostructures, whereby magnetic order can be introduced via interfacial coupling.
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 9031-9032 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We consider the problem of mass redistribution in a two-phase system. Solutions are obtained for the interface motion utilizing both a model and the exact microscopic Fokker–Planck equation. In each case an initial linear growth is followed by a distinctive transition to the long time t1/2 diffusive growth.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 82 (1997), S. 6357-6358 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We formulate a kinetic description of the vertical exchange reaction in which Ga replaces In during migration enhanced epitaxy of GaAs on InAs. Considering the Ga deposition rate R to be finite rather than infinite, as was done previously, leads to a reinterpretation of experimental results. The kinetic coefficient k as found by comparison with the In concentration profile determined by secondary ion mass spectroscopy is found to be 25% greater at 500 °C, cycle time of 5 s and R=〈fraction SHAPE="CASE"〉12 s−1 than that found earlier. The probability of an In atom being replaced by a newly deposited Ga atom, which depends on the details of the Ga deposition schedule, is determined and found to be identical, 98%, for these conditions to that found earlier. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 63 (1993), S. 3333-3334 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We consider the evolution of terrace widths for the case, at step-flow conditions, where the adatom-step exchange kinetics include the possibility of step crossing as well as sticking. We find that the stability criteria are determined by the crossing probabilities, with stability resulting when crossing the lower step is favored. This result is based on a description that takes into account adatom diffusion on the terraces; the result is in direct conflict with that previously obtained which is based on computer simulations of a probabilistic model that does not include an adatom migration mechanism and fails to take into account the correlation effect due to the preferential return of adatoms to a crossed step.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 102 (1995), S. 8235-8248 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Time-dependent quantum wave packets have been used in a model calculation to investigate the substrate-mediated photodesorption of a molecule from a metal surface. A "hot'' electron, generated in the substrate by an absorbed photon, temporarily resonates in an unoccupied molecular orbital. This results in a new set of forces, and if the electron spends sufficient time in the resonance, then on returning to the electronic ground state the molecule will have acquired sufficient energy to desorb. Rather than modeling the excitation and relaxation steps independently, we treat the motion of the molecule and the hot electron on an equal footing. We have studied the dynamics on potential energy surfaces (PESs) explicitly including both the electronic and nuclear coordinates. PES parameters were chosen to model NO desorption from Pt where it has been suggested that the excited state is attractive. The desorption probability has been calculated as a function of hot electron energy and photon energy for different potential topologies. We show that observable desorption is possible for short resonance lifetimes (∼1 fs) and moderate excited state potential gradients. Also presented are the translational energy distributions of the desorbing molecules. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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