ALBERT

Description: Submitted in partial fulfillment of the requirements for the degree of Master of Science at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2008

Description: Coupled ocean/atmosphere simulations exhibit systematicwarm biases over the SouthWest African (SWA) coastal region. Recent investigations indicate that coastal ocean dynamics may play an important role in determining the SST patterns, but none of them provide a detailed analysis. In this study, I analyze simulations produced both by coupled models and by idealized models. Then results are interpreted on the basis of a theoretical framework. Finally the conclusion is reached that the insufficient resolution of the ocean component in the coupled model is responsible for the warm biases over the SWA coastal region. The coarse resolution used in the ocean model has an artificially stretched coastal side-wall boundary layer, which induces a smaller upwelling velocity in the boundary layer. The vertical heat transport decreases even when the volume transport is unchanged because of its nonlinear relationship with the magnitude of the upwelling velocity. Based on the scaling of the idealized model simulations, a simplified calculation shows that the vertical heat transport is inversely proportional to the zonal resolution over the coastal region. Therefore, increasing the horizontal resolution can considerably improve the coastal SST simulation, and better resolve the coastal dynamics.

Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2011

Description: Eastern oceanic boundary currents are subject to hydrodynamic instability, generate small scale features that are visible in satellite images and may radiate westward into the interior, where they can be modified by the large-scale circulations. This thesis studies the stability of an eastern boundary current with and without the large-scale flow influence in an idealized framework represented by barotropic quasi-geostrophic dynamics. The linear stability analysis of a meridional current with a continuous velocity profile shows that meridional eastern and western boundary currents support a limited number of radiating modes with long meridional and zonal wavelengths and small growth rates. However, the linearly stable, long radiating modes of an eastern boundary current can become nonlinearly unstable by resonating with short trapped unstable modes. This phenomenon is clearly demonstrated in the weakly nonlinear simulations. Results suggest that linearly stable longwave modes deserve more attention when the radiating instability of a meridional boundary current is considered. A large-scale flow affects the short trapped unstable mode and long radiating mode through different mechanisms. The large-scale flow modifies the structure of the boundary current to stabilize or destabilize the unstable modes, leading to a meridionally localized maximum in the perturbation kinetic energy field. The shortwave mode is accelerated or decelerated by the meridional velocity adjustment of the large-scale flow to have an elongated or a squeezed meridional structure, which is confirmed both in a linear WKB analysis and in nonlinear simulations. The squeezed or elongated unstable mode detunes the nonlinear resonance with the longwave modes, which then become less energetic. These two modes show different meridional structures in kinetic energy field because of the different mechanisms. In spite of the model simplicity, these results can potentially explain the formation of the zonal jets observed in altimeter data, and indicate the influence of the large-scale wind-driven circulation on eastern boundary upwelling systems in the real ocean. Studies with more realistic configurations remain future challenges.

Description: A multistep dry fractionation method for modification of palm oil was adopted to achieve a high iodine value (IV) of the obtained palm olein, herein denoted as top olein. The effect of the composition of palm oil top olein on the IV and on the crystallization properties was analyzed in detail. Thermal properties of a series of olein and stearin fractions were evaluated by means of differential scanning calorimetry upon cooling. The composition of triacylglycerols in the products was investigated by high-performance liquid chromatography. IV analysis was carried out to measure the degree of unsaturation in these oil samples. Finally, an innovative and reliable method was developed to determine the IV of palm oils by relating the thermal properties with IV. The results agree well with those obtained by the traditional American Oil Chemists' Society method. In the palm oil industry, the iodine value is normally determined by a titration method that uses toxic solvents. An innovative method is proposed to quickly determine the iodine value of oil samples. This approach can provide statistically similar results to those given by traditional official procedures, with the advantages of being extremely rapid and environmentally friendly.

Description: β-Yb 2 Si 2 O 7 is a promising environmental barrier coating (EBC) material and recently attracted attention for its damage tolerance. To investigate the mechanisms of its damage tolerance and possible plasticity, dense β-Yb 2 Si 2 O 7 sample was synthesized by in situ reaction/hot-pressing method, and its mechanical properties were measured from room to high temperatures. The low magnitudes of hardness to Young's modulus ratio H V /E , shear modulus to bulk modulus ratio G/B , and high fracture toughness to strength ratio K IC / σ provide evidences of damage tolerance of β-Yb 2 Si 2 O 7 . β-Yb 2 Si 2 O 7 exhibits extensive plastic deformation in Hertzian contact tests at both room and high temperatures. Transmission electron microscopy (TEM) observations show that the deformation mechanisms are different at low and high temperatures. Deformation twinning and parallel dislocation arrangement occur in plastic deformation at room temperature. Above the brittle-to-ductile transition temperature (between 1200°C and 1300°C), plastic deformation brings out extensive slip and climb of dislocations, while twinning is seldom observed. Measurement of temperature-dependent dynamic Young's modulus demonstrates excellent elastic stiffness retention up to 1300°C.

Description: Setting up an exclusive left-turn lane and corresponding signal phase for intersection traffic safety and efficiency will decrease the capacity of the intersection when there are less or no left-turn movements. This is especially true during rush hours because of the ineffective use of left-turn lane space and signal phase duration. With the advantages of vehicle-to-infrastructure (V2I) communication, a novel intersection signal control model is proposed which sets up variable lane direction arrow marking and turns the left-turn lane into a controllable shared lane for left-turn and through movements. The new intersection signal control model and its control strategy are presented and simulated using field data. After comparison with two other intersection control models and control strategies, the new model is validated to improve the intersection capacity in rush hours. Besides, variable lane lines and the corresponding control method are designed and combined with the left-turn waiting area to overcome the shortcomings of the proposed intersection signal control model and control strategy.

Description: The assembly consistency of a diesel engine will affect its nitrogen oxides (NOx) emission variation. In order to improve the NOx emissions of diesel engines, a study was carried out based on the assembly tolerance variation of the diesel engine’s combustion system. Firstly, a diesel engine which meets the Euro VI standards together with the experimental data is obtained. The mesh model and combustion model of the engine combustion system are built in the Converge software (version 2.4, Tecplot, Bellevue, DC, USA), and the experimental data is used to calibrate the combustion model obtained in the Converge software. Then, the four-factor and three-level orthogonal simulation experiments are carried out on the dimension parameters that include nozzle extension height, throat diameter, shrinkage diameter and combustion chamber depth. Through mathematical analysis on the experimental data, the results show that the variation of nozzle extension height and combustion chamber depth have a strong influence on NOx emission results, and the variation of combustion chamber diameter also has a weak influence on NOx production. According to the regression model obtained from the analysis, there is a quadratic function relating the nozzle extension height and NOx emissions and the amount of NOx increases with increasing nozzle extension height. The relationship between emission performance and size parameters is complex. In the selected size range, the influence of the variation of the chamber diameter on NOx is linear. The variation of the chamber depth also has an effect on NOx production, and the simulation results vary with the change of assembly tolerance variation. Thus, in the engine assembly process, it is necessary to strictly control the nozzle extension height and combustion chamber depth. The research results are useful to improve the NOx emission of diesel engine and provide a basis for the control strategy of selective catalytic reduction (SCR) devices.

Description: An earth-to-air heat exchanger (EAHE) system utilizes the low-grade thermal energy of underground soil to warm up and cool down the flowing air within an underground buried pipe. Integrating the EAHE system with building ventilation can reduce the energy demand for conditioning ventilation air. The main purposes of this paper are to estimate the year-round energy-saving potential of the EAHE-assisted building ventilation system and provide its design guidelines in a hot-summer and cold-winter climate. A steady-state heat transfer model was proposed to calculate the outlet air temperature of an EAHE and further identify its ability to preheat and precool ventilation air. Influences of depth, length, and diameter of a buried pipe on the year-round thermal performance of the EAHE system were evaluated. The results show that considering the compromise between thermal performance and construction costs of the EAHE system, a depth of 5 m and a length of 80 m are recommended. The EAHE system can provide a mean daily cooling and heating capacity of 19.6 kWh and 19.3 kWh, respectively. Moreover, the utilization of the EAHE system can reduce by 16.0% and 50.1% the energy demand for cooling and heating ventilation air throughout the whole year.