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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 3361-3367 
    ISSN: 0887-624X
    Keywords: vinyl polyperoxides ; photoinitiators ; block copolymers ; unzipping of alkoxy radicals ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This article describes the first comprehensive study on the use of a vinyl polyperoxide, namely poly(styrene peroxide) (PSP), an equimolar alternating copolymer of oxygen and styrene, as a photoinitiator for free radical polymerization of vinyl monomers like styrene. The molecular weight, yield, structure and thermal stability of polystyrene (PS) thus obtained are compared with PS made using a simple peroxide like di-t-butyl peroxide. Interestingly, the PS prepared using PSP contained PSP segments attached to its backbone preferably at the chain ends. This PSP-PS-PSP was further used as a thermal macroinitiator for the preparation of another block copolymer PS-b-PMMA by reacting PSP-PS-PSP with methyl methacrylate (MMA). The mechanism of block copolymerization has been discussed. © 1996 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 2 (1981), S. 68-74 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Polypropylene is one of the important thermoplastics that has been reinforced with glass fibers to give a reasonably good engineering plastic. Because of its inert nature, it does not easily adhere to the glass surface and hence some improvement in mechanical properties. In the present study a vinyltriethoxysilane coupling agent in polymeric form has been tried and seen to improve the properties. Tests have been carried out at (a) constant strain rate (in the Instron testing machine), and (b)constant stress rate (water loading on a biaxial testing machine). Under constant strain rate only tensile properties have been studied while under constant stress rate, the tensile, torsional and combined tensile-torsional tests have been carried out. In each of the above cases, a considerable improvement in elastic modulus has been observed. The Tensile strength is improved to the extent of about 25 percent. There is only a slight improvement in torsional strength. Different fiber volume contents were used and their effect studied on modulus and strength. The mechanical data for reinforced-polypropylene samples have been discussed in terms of the fiber-length distribution in the composite. Detailed analysis of tensile data suggests that at low strains, when the critical length is relatively low, the fibers contribute to a high modulus. With increasing strain the critical length increases and the load carrying capacity of the fibers is reduced. Consequently the gain in strength is relatively less. The effect of fiber length distribution in torsion and combined tension-torsion tests would be expected to be similar and the results seem to confirm this.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 70 (1937), S. 2228-2232 
    ISSN: 0365-9631
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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