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  • BioMed Central  (97)
  • Wiley-Blackwell  (76)
  • American Chemical Society (ACS)
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 17 (1980), S. 821-831 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Relationships are formulated to explain the variation in dihydrofolate reductase inhibitory potency for a series of 25 substituted quinazolines, with an antineoplastic potential. Highly significant correlations are obtained using CNDO/2-3R calculated indices and/or the empirically estimated molecular polarizability as independent variables. The MO calculated indices employed are the atomic polarizability, as defined herein, and bond energy. The molecular polarizability is represented by a simple sum of environment independent partial atomic polarizabilities. The partial polarizabilities, reported here for H, C, N, O, F, S, Cl, and Br, are obtained from a multiple regression forced through the origin.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 190 (1989), S. 2279-2286 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Chitosan films were prepared by casting from solutions in dilute acetic acid containing methanol, acetone, or dimethyl sulfoxide. Induced changes in the structural orientation of the molecules within the film were studied by wide angle X-ray diffraction, and it was shown that the presence of a high concentration of organic solvent in solution altered the crystal structure of the resultant films, rendering them insoluble in water. Benzoylated and butyrylated derivatives of chitin and chitosan were prepared and characterised by infrared spectroscopy. Films of these derivatives were prepared by casting from a number of organic solvents and water, and the structures examined in more detail by wide angle X-ray diffraction. The introduction of the aliphatic and aromatic groups to the polysaccharide backbone was thus shown to disrupt the natural orientation of the polymer chains; the solubility of the acylated derivatives is discussed with respect to these structural changes.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal of Morphology 109 (1961), S. 19-36 
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 16 (1972), S. 3063-3071 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The ultraviolet absorption spectra of Cadoxen solutions of hydrocellulose and hydrocellulose phenylosazones are described. With solutions of hydrocellulose no simple relationship between D.P. and absorbance was found. Solutions of hydrocellulose phenylosazone in Cadoxen show well-defined maxima at 277 nm and 390 nm and do not change over 1 hr when oxygen is excluded. The absorbance of the phenylosazone at 390 nm may be used to determine the D.P. of the hydrocellulose samples.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 2955-2961 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The surface areas of dyed and undyed secondary cellulose acetate fibers have been determined using low-temperature nitrogen gas adsorption by the method of Brunauer, Emmett, and Teller. The results confirmed earlier work using p-nitrophenol, in which it was shown that there is a marked change of surface area of dyed fiber in the region corresponding to a theoretical monolayer adsorption of the dye.
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 4251-4261 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of several variables on the adsorption rate of four dyestuffs onto chitin was studied. A model is proposed enabling the film mass transfer coefficients to be determined. The coefficients were independent of initial dye concentration, chitin mass, chitin particle size, and temperature; a slight dependence with agitation was obtained. The film mass transfer coefficients at 400 rpm were 2.8×10-3, 2.9×10-3, 3.9×10-3, and 0.9×10-3 cm/s for Acid Blue 25, Acid Blue 158, Mordant Yellow 5, and Direct Red 85, respectively.
    Additional Material: 9 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 1499-1514 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Chitin has the ability to adsorb substantial quantities of dyestuffs from aqueous solutions. Consequently, it may be a useful adsorbent for effluent treatment from textile mills. The design procedures for batch and continuous fixed bed adsorption columns have been investigated for four dyestuffs, namely, CI Acid Blue 25 (Telon Blue Anl, Bayer), CI Acid Blue 158 (Neolan Blue 29, Ciba Geigy) CI Mordant Yellow 5 (Eriochrome Flavine A, Ciba Geigy), and CI Dirert Red 84 (Solophenyl Brown 3RL, Ciba Geigy). The main fixed bed system variables studied are bed height, dye flow rate, and chitin particle size, and these effects have been incorporated into a simplified design model.
    Additional Material: 14 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 641-656 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Chitosan has been prepared from prawn shell and crab shell chitin. The molecular weight of the material derived from prawn shells is higher than that obtained from crab shell. The molecular weight, tensile strength, elongation at the break, and hydrophilic properties of chitosan are extremely dependent on the degree of deacetylation achieved when chitin is hydrolyzed to chitosan. Graft copolymers have been prepared with chitosan and a series of vinyl monomers using both heterogeneous and homogeneous reaction conditions. The hydrophilic properties of chitosan can be modified by blending with poly(vinyl alcohol).
    Additional Material: 9 Ill.
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  • 9
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Treatment of peptides containing methionine and/or tryptophan with dimethylsulfoxide/hydrochloric acid/acetic acid resulted in oxidation of these amino acids respectively to methionine sulfoxide and oxyindolalanine. This reaction was monitored by fast atom bombardment mass spectrometry using a dithiothreitol/dithioerythritol liquid matrix. Under these conditions, only methionine and tryptophan were oxidized. Comparison of mass spectra of a sample before and after oxidation should provide a rapid screening procedure for determination of these residues in peptides.
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 258-264 
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Platelet activating factor (PAF) bioactivity has been demonstrated in saliva from normal volunteers. We sought structural confirmation and evidence of heterogeneity in the 1-O-alkyl chain of the acetyl glyceryl ether phosphoryl choline (AGEPC) extracted from saliva by employing stable isotope dilution techniques in conjunction with gas chromatography/mass spectrometry. The method described involves removal of the polar phosphocholine moiety, accounts for acetyl group migration, and allows for acylation of the resultant free hydroxyl with pentafluorobenzoyl chloride. Thin-layer chromatography (TLC) purification is undertaken after phospholipase C cleavage and again after pentafluorobenzoyl chloride derivatization. The majority of the ion current is represented in the molecular anion, allowing measurement of 50 pg in biological fluid with a signal-to-noise ratio of ≥9. In one subject with markedly increased salivary PAF levels, we found evidence for molecular heterogeneity of AGEPC with production of not only C16:0 but also C18:0 and C18:1 in the alkyl chain. This technique, by using TLC in lieu of high-performance liquid chromatography, avoids potentially confounding trace contamination effects, produces spectra with few interfering signals and increases sample throughput.
    Additional Material: 5 Ill.
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