ALBERT

Description: ABSTRACT A primary concern for geologic carbon storage is the potential for leakage of stored carbon dioxide (CO 2 ) into the shallow subsurface where it could degrade the quality of groundwater and surface water. In order to predict and mitigate the potentially negative impacts of CO 2 leakage, it is important to understand the physical processes that CO 2 will undergo as it moves through naturally heterogeneous porous media formations. Previous studies have shown that heterogeneity can enhance the evolution of gas phase CO 2 in some cases, but the conditions under which this occurs have not yet been quantitatively defined, nor tested through laboratory experiments. This study quantitatively investigates the effects of geologic heterogeneity on the process of gas phase CO 2 evolution in shallow aquifers through an extensive set of experiments conducted in a column that was packed with layers of various test sands. Soil moisture sensors were utilized to observe the formation of gas phase near the porous media interfaces. Results indicate that the conditions under which heterogeneity controls gas phase evolution can be successfully predicted through analysis of simple parameters, including the dissolved CO 2 concentration in the flowing water, the distance between the heterogeneity and the leakage location, and some fundamental properties of the porous media. Results also show that interfaces where a less permeable material overlies a more permeable material affect gas phase evolution more significantly than interfaces with the opposite layering.

Description: We present a predictive, multiscale modeling framework for chemotaxis in porous media. This model results from volume averaging the governing equations for bacterial transport at the microscale and is expressed in terms of effective medium coefficients that are predicted from the solution of the associated closure problems. As a result, the averaged chemotactic velocity is an explicit function of the attractant concentration field and diffusivity, rather than an empirical effective chemotactic sensitivity coefficient. The model was validated by comparing the transverse bacterial concentration profiles with experimental measurements for Escherichia coli HCB1 in a T-sensor. The averaged chemotactic velocity predicted by the model was found to be within the range of values reported in the literature. Reasonable agreement (approximately 10% mean absolute error) between theory and experiments was found for several flow rates. In order to assess the potential for decreasing the computational demands of the model, the macroscale domain was divided into subdomains for the coupling of bacterial transport to that of the attractant. Sensitivity analysis was performed regarding the number of subdomains chosen, and the results indicate that bacterial transport (as measured by concentration profiles) was not highly affected by this choice. Overall, these results suggest that the predictive, multiscale modeling framework is reliable for modeling chemotaxis in porous media when chemotactic transport is significant compared to convective transport.

Description: Improvements in our ability to model runoff from glaciers remain an important scientific goal. This paper describes a new temperature-radiation-index glacier melt model specifically enhanced for use in High-Arctic environments, utilising high temporal and spatial resolution datasets while retaining relatively modest data requirements. The model employs several physically constrained parameters and was tuned using a lidar-derived surface elevation model of Midtre Lovénbreen, meteorological data from sites spanning ~70% of the glacier's area-altitude distribution, and periodic ablation surveys during the 2005 melt season. The model explained 80% of the variance in observed ablation across the glacier, an improvement of ~40% on a simplified energy balance model (EBM), yet equivalent to the performance of a full EBM employed at the same location. Model performance was assessed further by comparing potential and measured runoff from the catchment, and through application to an earlier (2004) melt season. The additive model form and consideration of a priori parameters for the Arctic locality were shown to be beneficial, with a planimetry correction eliminating systematic errors in potential runoff. Further parameterisations defining modelled incident radiation failed to yield significant improvements to model output. Our results suggest that such enhanced melt models may perform well for singular melt seasons, yet are highly sensitive to the choice of lapse rates and their transferability to different locations and seasons may be limited. While modelling ablation requires detailed consideration of the transition between snow- and ice-melt, our study suggests that description of the ratio between radiative and turbulent heat fluxes may provide a useful step towards dynamic parameterisation of melt factors in temperature-index models. Copyright © 2012 John Wiley & Sons, Ltd.

Description: To assess the risks of Geologic Carbon Sequestration (GCS), it is crucial to understand the fundamental physicochemical processes that may occur if and when stored CO 2 leaks upward from a deep storage reservoir into the shallow subsurface. Intermediate-scale experiments allow for improved understanding of the multiphase evolution processes that control CO 2 migration behaviour in the subsurface, because the boundary conditions, initial conditions, and porous media parameters can be better controlled and monitored in the laboratory than in field settings. For this study, a large experimental test bed was designed to mimic a cross-section of a shallow aquifer with layered geologic heterogeneity. As water with aqueous CO 2 was injected into the system to mimic a CO 2 -charged water leakage scenario, the spatiotemporal evolution of the multiphase CO 2 plume was monitored. Similar experiments were performed with two different sand combinations to assess the relative effects of different types of geologic facies transitions on the CO 2 evolution processes. Significant CO 2 attenuation was observed in both scenarios, but by fundamentally different mechanisms. When the porous media layers had very different permeabilities, attenuation was caused by local accumulation (structural trapping) and slow re-dissolution of gas phase CO 2 . When the permeability difference between the layers was relatively small, on the other hand, gas phase continually evolved over widespread areas near the leading edge of the aqueous plume, which also attenuated CO 2 migration. This improved process understanding will aid in the development of models that could be used for effective risk assessment and monitoring programs for GCS projects.

Description: The hydrology of near-surface glacier ice remains a neglected aspect of glacier hydrology despite its role in modulating meltwater delivery to downstream environments. To elucidate the hydrological characteristics of this near-surface glacial “weathering crust”, we describe the design and operation of a bespoke capacitance-based piezometer that enables rapid, economical deployment across multiple sites and provides an accurate, high-resolution record of near-surface water level fluctuations. Piezometers were employed at ten northern hemisphere glaciers, and through the application of standard bail-recharge techniques, we derive hydraulic conductivity ( K ) values from 0.003 to 3.519 m d -1 , with a mean of 0.185 ± 0.019 m d -1 . These results are comparable to those obtained in other discrete studies of glacier near-surface ice, and for firn, and indicate that the weathering crust represents a hydrologically inefficient aquifer. Hydraulic conductivity correlated positively with water table height but negatively with altitude and cumulative short-wave radiation since the last synoptic period of either negative air temperatures or turbulent energy flux dominance. The large range of K observed suggests complex interactions between meteorological influences and differences arising from variability in ice structure and crystallography. Our data demonstrate a greater complexity of near-surface ice hydrology than hitherto appreciated, and support the notion that the weathering crust can regulate the supraglacial discharge response to melt production. The conductivities reported here, coupled with typical supraglacial channel spacing, suggest that meltwater can be retained within the weathering crust for at least several days. This has implications not only for the accuracy of predictive meltwater runoff models, but we also argue for biogeochemical processes and transfers that are strongly conditioned by water residence time and the efficacy of the cascade of sediments, contaminants, microbes and nutrients to downstream ecosystems. Since continued atmospheric warming will incur rising snowline elevations and glacier thinning, the supraglacial hydrological system may assume greater importance in many mountainous regions and, consequently, detailing weathering crust hydraulics represents a research priority since the flow-path it represents remains poorly constrained.