ISSN:
0009-2940
Keywords:
Titanocene complexes
;
Cyclopropane, methylene, complexes
;
Bis(titanocenyl)acetylene complex
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Synthesis and Structure of a New Bis[(trimethylphosphan)titanocene] Complex with a Bridging C2 Unit
Notes:
Bis(trimethylphosphane)titanocene (1) reacts with 2-methylene-1,1-diphenylcyclopropane (2) to give red crystalline (η2-2-methylene-1,1-diphenylcyclopropane)(trimethylphosphane)titanocene (3). In solution complex 3 degrades smoothly to form the new Cp2Ti(PMe3) - C2 - Ti(PMe3)Cp2 complex 4, the crystal structure of which has been elucidated by an X-ray analysis.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921251007
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