ISSN:
0749-1581
Keywords:
13C NMR
;
2-Methylene-d2-adamantane derivatives
;
Deuterium isotope shifts
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Deuterium isotope effects on 13C NMR chemical shifts, (2H/1H)nΔ(13C), of 2-methylene-d2-adamantane, 4-methylene-d2-2-adamantanone and 6-methylene-d2-2-adamantanone are presented. Long-range effects (4Δ, 5Δ and 6Δ) in a range from 5 to - 23 ppb were observed. The results for 5Δ and 6Δ are explained in terms of cross-ring field effects resulting from the change of dipole due to deuterium substitution.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260311005
Permalink