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  • Column overloading  (1)
  • order-preserving map  (1)
  • Springer  (2)
  • American Chemical Society
  • Elsevier
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Publisher
  • Springer  (2)
  • American Chemical Society
  • Elsevier
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Order 12 (1995), S. 45-55 
    ISSN: 1572-9273
    Keywords: Primary: 06A06, 05C35 ; Secondary: 05B05, 03C13 ; Ordered set ; order-preserving map ; endomorphism ; retract ; reflexive graph ; rigid ; projective plane
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract Theendomorphism spectrum of an ordered setP, spec(P)={|f(P)|:f ∈ End(P)} andspectrum number, sp(P)=max(spec(P)\{|P|}) are introduced. It is shown that |P|〉(1/2)n(n − 1) n − 1 implies spec(P) = {1, 2, ...,n} and that if a projective plane of ordern exists, then there is an ordered setP of size 2n 2+2n+2 with spec(P)={1, 2, ..., 2n+2, 2n+4}. Lettingh(n)=max{|P|: sp(P)⩽n}, it follows thatc 1 n 2⩽h(n)⩽c 2 n n+1 for somec 1 andc 2. The lower bound disproves the conjecture thath(n)⩽2n. It is shown that if |P| − 1 ∈ spec(P) thenP has a retract of size |P| − 1 but that for all κ there is a bipartite ordered set with spec(P) = {|P| − 2, |P| − 4, ...} which has no proper retract of size⩾|P| − κ. The case of reflexive graphs is also treated.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 28 (1989), S. 293-299 
    ISSN: 1612-1112
    Keywords: Preparative liquid chromatography ; Column overloading ; Computer simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A theory of non-linear chromatography based on the mass balance equation is presented. The model is a system of partial differential equations and it includes axial dispersion in the mobile phase, flow in the mobile phase and mass transfer between phases. In the case of the injection of a mixture competition between components for places in the stationary or the mobile phase is taken into account. In the paper are discussed: numerical calculations of concentration and volume overloading and the effect of the mutual influence of the components of the injected mixture on the process of mass transfer between phases. Additionally, results of experiments for convex and concave adsorption isotherms are presented. In both cases the results obtained qualitatively confirm the theoretical analyses.
    Type of Medium: Electronic Resource
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