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  • Oxford University Press  (13)
  • Geological Society of London  (3)
  • Mineralogical Society of America  (3)
  • American Association for the Advancement of Science (AAAS)  (1)
  • 1
    Publication Date: 2016-08-01
    Description: The Kidnappers [~1200 km 3 dense rock equivalent (DRE)] and Rocky Hill (~200 km 3 DRE) caldera-forming events in the Taupo Volcanic Zone, New Zealand, were erupted in close succession from the Mangakino volcanic centre. They have identical radiometric ages at ~1 Ma, yet erosion along the contact between the two deposits suggests that some years to decades separated the two eruptions. Field constraints and the similarities of crystal textures and compositions and glass chemistries of both eruption deposits demonstrate that they came from one overall magmatic system with a common crystal mush source. However, second-order variations in these parameters confirm that the Kidnappers and Rocky Hill deposits represent distinct events and are not the products of a single zoned magma chamber. The systematically zoned Kidnappers fall deposits provide evidence for the tapping of three discrete magma bodies, whereas the succeeding Kidnappers ignimbrite is compositionally more diverse. The transition from fall to flow deposition marks a change in the style of caldera collapse and the simultaneous evacuation of discrete but compositionally diverse melts, each of which underwent a distinct evolution and was held at slightly different P–T conditions prior to eruption. Contrasting plagioclase and orthopyroxene zonation patterns are present in pumices originating from three discrete magma bodies. Less evolved mafic melts interacted with the system, which mobilized portions of the final erupted melt through heating and volatile or chemical exchange in the mush. The two largest Kidnappers melt-dominant bodies were re-tapped in modified form, or re-established from their common mush source, prior to the Rocky Hill event. Rocky Hill pumices contain common, fluid-affected antecrystic crystal clots derived from chamber wall material. Amphibole compositions from each eruption reflect melt evolution processes and, in particular, the contemporaneous crystallization of biotite and breakdown of orthopyroxene. Plagioclase and orthopyroxene from Rocky Hill pumices share common zonation patterns with those from the two largest magma bodies in the Kidnappers. The rapid production of new melt-dominant bodies and the triggering of the Rocky Hill eruption reflect the ability of the magmatic system to rejuvenate on a geologically short timescale. The Mangakino centre did not follow a typical cycle of decreased activity after the supervolcanic Kidnappers event, instead producing a second caldera-forming eruption, within years to decades from the same system.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 2
    Publication Date: 2015-04-25
    Description: New in situ major and trace element analytical data are presented for crystals (sanidine, plagioclase, biotite, orthopyroxene, clinopyroxene) and matrix glasses from juvenile materials representing the full Bishop Tuff sequence from the earliest fall unit (F1) to the latest ignimbrite package (Ig2Nc). These data are combined with published information to investigate the nature and zonation of the pre-eruptive Bishop magma chamber. Our data confirm that this magma chamber was a single unitary body that was thermally and compositionally zoned. The zonation was largely established prior to the growth of crystals, and also prior to mixing in the lower parts of the chamber induced by late-stage intrusion of a magma of contrasting composition and slightly higher temperature (the ‘bright-rim’ magma). Sparse mixed swirly and dacitic pumices show enrichments in Ba, Sr and Ti that identify these pumices as possible representatives of the ‘bright-rim’ magma. A model (revised from previously published work) for the pre-eruptive magma chamber comprises three main parts: (1) an upper, volumetrically dominant (~2/3), relatively unzoned region that was the source of the earlier, eastern-erupted ignimbrite units and their coeval fall units; (2) a volumetrically minor transition zone that shows evidence for minor degrees of mixing and was the dominant source for the latest, eastern-erupted part of Ig1Eb (Sherwin subunit) and the earlier part of the northern-erupted ignimbrite (Ig 2Na); (3) a lower, volumetrically subordinate (~1/3) region that was affected by mixing with the ‘bright-rim’ invasive magma in the lead-up to the eruption, and fed later northern-erupted units. Ingress of the ‘bright-rim’ magma introduced orthopyroxene and bright-rimmed zircon crystals, and induced partial resorption then overgrowth of rims enriched in Ti, Sr and Ba on sanidine and quartz, and development of zoning in clinopyroxene. Based on pumice proportions and associated crystal and glass chemistries through the eruptive sequence, we infer that the roof and floor of the magma chamber were stepped down to the north, such that the transition zone magma formed the floor of the southern part of the melt-dominant chamber and the roof of the northern part. Our data reinforce the previous concept of a single compositionally and thermally zoned Bishop magma chamber and additionally support a temporally constrained role for pre-eruptive magma mixing and the introduction of melts and minerals with contrasting compositions to the resident Bishop magma.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 3
    Publication Date: 2013-01-17
    Description: The geochemistry of pyroclasts sampled from four volcanoes along the Kermadec arc in the SW Pacific is used to investigate the genesis of silicic magmas in a young (〈2 Myr), archetypical intra-oceanic arc setting. Raoul, Macauley and Raoul SW volcanoes in the northern Kermadec arc, and Healy volcano in the southern Kermadec arc have all recently erupted dacitic to rhyolitic crystal-poor pumice. In addition to whole-rock analyses, we present a detailed study of mineral and glass chemistries to highlight the complex structure of the Kermadec magmatic systems. Major and trace element bulk-rock compositions mostly fall into relatively narrow compositional ranges, forming discrete groups by eruption for Raoul, and varying with relative crystal contents for Healy. In contrast, pumices from Macauley cover a wide range of compositions, between 66 and 72·5 wt % SiO 2 . At all four volcanoes the trace element patterns of pumice are subparallel to both those of previously erupted basalts and/or whole mafic blebs found both as discrete pyroclasts and as inclusions within pumices. Pb and Sr isotopic compositions have limited ranges within single volcanoes, but vary considerably along the arc, being more radiogenic in the southern volcanoes. Distinctive crystal populations and zonation patterns in pumices, mafic blebs and plutonic xenoliths indicate that many crystals did not grow in the evolved magmas, but are instead mixed from other sources including gabbros and hydrothermally altered tonalites. Such open-system mixing is ubiquitous at the four volcanoes. Oxygen isotope compositions of both phenocrysts (silicic origin) and xenocrysts or antecrysts (mafic origin) are typical for mantle-derived melts. Whole-rock, glass and mineral chemistries are consistent with evolved magmas being generated at each volcano through ~70–80% crystal fractionation of a basaltic parent. Our results are not consistent with silicic magma generation via crustal anatexis, as previously suggested for these Kermadec arc volcanoes. Although crystallization is the dominant process driving melt evolution in the Kermadec volcanoes, we show that the magmatic systems are open to contributions from both newly arriving melts and wholly crystalline plutonic bodies. Such processes occur in variable proportions between magma batches, and are largely reflected in small-scale chemical variations between eruption units.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 4
    Publication Date: 2014-07-01
    Description: The late Mesozoic Yanshanian volcanic arc affected an extensive region of SE China, but the conclusion of magmatism and later evolution are not fully understood. Widespread Yanshanian ignimbrites and their contemporaneous granites exposed in Hong Kong represent a microcosm of this magmatic arc. To constrain the post-magmatic thermal history of the region, we present zircon and apatite fission-track analyses from these rocks. Double dating using laser ablation inductively coupled plasma mass spectrometry U–Pb and fission-track techniques on detrital zircons from post-volcanic Cretaceous sediments is used to further constrain the tectonothermal evolution. The resulting dataset and thermal modelling suggest that the igneous rocks and Cretaceous sediments together experienced post-emplacement or post-depositional heating to 〉250 °C, subsequently cooling through 120–60 °C after c . 80 Ma. The heating reflects the combined effects of an enhanced geothermal gradient and burial. We interpret the enhanced gradient to represent continuing Yanshanian magmatic activity until c . 100–80 Ma, much later than previously considered. Our data also indicate a long-term, slow cooling ( c . 1 °C myr –1 ) since the early Cenozoic, linked to c . 2–3 km of erosion-driven exhumation. The thermotectonic history of Hong Kong reflects the mid-Cretaceous transition of SE China from an active to a passive margin bordered by marginal basins that formed in the early Cenozoic. Supplementary material: Descriptions of samples, operating conditions of the laser ablation inductively coupled plasma mass spectrometry system and the full dataset of U–Pb dating of detrital zircons are available at www.geolsoc.org.uk/SUP18750 .
    Print ISSN: 0016-7649
    Topics: Geosciences
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  • 5
    Publication Date: 2014-07-17
    Description: New zircon U–Th model-age and trace element datasets are presented from Taupo volcano (New Zealand), which are used to investigate the timescales and broad-scale magmatic processes involving zircon crystallization after the caldera-forming 25·4 ka Oruanui supereruption. Detailed 14 C-based chronologies and controls on vent locations allow the timing and location of post-caldera eruptions to be spatially and temporally constrained to an extent not possible for any other supervolcano. After ~5 kyr of post-Oruanui quiescence, Taupo erupted three dacitic units, followed by another ~5 kyr break, and then a sequence of rhyolitic units in three subgroups (SG1–SG3) from 12 ka onwards. Despite overlapping vent sites and crustal source domains between the Oruanui and post-Oruanui eruptions, U–Th zircon model ages in Taupo SG1 rhyolites (erupted from 12 to 10 ka) indicate only minor inheritance of crystals from the Oruanui magma source. Post-Oruanui model-age spectra are instead typically centred close to eruption ages with subordinate older pre-300 ka equiline grains in some units. U–Pb dating of these older grains shows that both 300–450 ka plutonic-derived and pre-100 Ma greywacke basement-derived zircons are present. The former largely coincide in age with zircons from the 350 ka Whakamaru eruption products, and are dominant over greywacke in young units that were vented within the outline of the Whakamaru caldera. Despite multiple ages and vent sites, trace element compositions are broadly similar in zircons, regardless of their ages. However, a small subset of zircons analysed from SG1 rhyolite (Units B and C) have notably high concentrations of U, Th, P, Y + (REE) 3+ and Nb but with only minor variations in Hf and Ti. SG2 zircons typically have higher Sc contents, reflecting large-scale changes in melt chemistry and crystallizing mineral phases with time. The age spectra indicate that most Oruanui zircons were removed by thermally induced dissolution immediately following the supereruption. U–Th ages from single post-Oruanui eruptions show consistent inheritance of post-Oruanui grains with model ages that centre between the temporally separated but geographically overlapping eruption groups, generating model-age modes. Within the statistical limitations of the isotopic measurements, we interpret these repeated modes to be significant, resulting from incorporation of crystal populations from cyclic post-Oruanui periods of magmatic cooling and crystallization, acting within a crustal protolith chemically independent of that which was dominant in the Oruanui system. These periods of cooling and crystallization alternate with times of rejuvenation and eruption, sometimes demonstrably accompanying syn-eruptive regional rifting and mafic magma injection. Not only were the processes that developed the supersized Oruanui magma body rapid, but this huge magma system was effectively reset and rebuilt on a comparably short timescale.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 6
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    Mineralogical Society of America
    In: Elements
    Publication Date: 2016-03-26
    Description: Silicic volcanic systems provide timed snapshots at the Earth's surface of the magmatic processes that also build complementary plutons in the crust. Links between these two realms are considered here using three Quaternary (〈2.6 Ma) examples from New Zealand and the USA. In these systems, magmatic processes can be timed and the changes in magmatic conditions can be followed through the sequence of quenched volcanic eruption products. Before an eruption, magma accumulation processes can occur on timescales as short as decades, and whole magma systems can be rebuilt in millennia. Silicic volcanic processes, in general, act on timescales that are too rapid to be effectively measured in the exposed plutonic record.
    Print ISSN: 1811-5209
    Electronic ISSN: 1811-5217
    Topics: Geosciences
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  • 7
    Publication Date: 2017-11-02
    Description: The links between large-scale silicic volcanism and plutonism offer insights into the dynamics of crustal magmatic systems and growth of continental crust. In Hong Kong, voluminous silicic ignimbrites and linked plutons record a ~26 Myr period of magmatism from ~164 to 138 Ma. We present data from these linked volcanic-plutonic assemblages at the Lantau and High Island caldera complexes, with an emphasis on the ~143–138 Ma activity from the latter. To track the evolution of these magmatic systems, U-Pb dating and trace element analyses using secondary-ion mass spectrometry (SIMS) were carried out on zircons from 21 samples from both volcanic and plutonic samples. The SIMS age data sets divide into two groups across volcanic and plutonic origins: (1) seven samples with unimodal age spectra [five of which have the same mean value as the published Isotope Dilution Thermal Ionization Mass Spectrometry (ID-TIMS) age from the same sample]; and (2) 14 samples yielding multiple age components. Age patterns from both groups suggest that the previously separated ~143 Ma Repulse Bay (RBVG) and ~141–140 Ma Kau Sai Chau volcanic groups (KSCVG) instead represent activities over a single ~5 Myr period. Direct linkages previously proposed between some volcanic and plutonic units for this period (e.g., High Island Tuff, Kowloon Granite) are no longer supported, and magmatism represented by exposed plutons continued until 137.8 ± 0.8 Ma (Mount Butler Granite). Under CL imagery, a wide range of zircon textures identified in both volcanic and plutonic samples is indicative of complex processes, some of which are identified through trace element data coupled with textural characteristics. Overall, intra-grain (cores vs. rims; sector-zonation) and intra-sample variations in trace element abundances and ratios are larger than those between samples. Zircon chemistries in both volcanic and plutonic samples fall into two groups during the ~5 Myr history of the High Island caldera magmatic system. One group (RBVG and "cold" granites) includes inherited grains back to 164 Ma and wider ranges in Hf, Y, total trivalent elements, Th and U concentrations and Th/U, Yb/Gd, and U/Yb ratios than the other (KSCVG and "hot" granites). Two possible evolutionary models of the High Island caldera magmatic system are: (1) the system randomly tapped a single crustal domain that fluctuated in temperature as a result of varying interactions of hotter melts, or (2) the volcanic and plutonic records reflect the interplay of two crustal domains with contrasting "low-" and "high-temperature" characteristics. In Hong Kong, some plutonic bodies were comagmatic with large-scale volcanism, while others were emplaced at shallow crustal levels independently of volcanism, matching the current two end-member views of the volcanic-plutonic relationship.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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  • 8
    Publication Date: 2017-12-22
    Description: Rubin et al . (Reports, 16 June 2017, p. 1154) proposed that gradients in lithium abundance in zircons from a rhyolitic eruption in New Zealand reflected short-lived residence at magmatic temperatures interleaved with long-term "cold" (〈650°C) storage. Important issues arise with the interpretation of these lithium gradients and consequent crystal thermal histories that raise concerns about the validity of this conclusion.
    Keywords: Geochemistry, Geophysics
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 9
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    Unknown
    Mineralogical Society of America
    In: Elements
    Publication Date: 2017-02-08
    Description: The geological record of volcanic eruptions suggests that scientists are some way from being able to forecast eruptions at many of the world's volcanoes. There are three reasons for this. First, continuing geological discoveries show that our knowledge is incomplete. Second, knowledge is limited about why, how, and when volcanic unrest turns into eruptions, and over what timescales. Third, there are imbalances between the studies of past eruptions, and the geophysical techniques and observations on modern events, versus the information needed or demanded by society. Scientists do not yet know whether there are other, presently unknown, factors that are important in controlling eruptions, or if there is an inherent unknowability about some volcanic systems.
    Print ISSN: 1811-5209
    Electronic ISSN: 1811-5217
    Topics: Geosciences
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  • 10
    Publication Date: 2014-01-09
    Description: We present zircon textural, trace element and U–Pb age data obtained by secondary ion mass spectrometry (SIMS) (SHRIMP-RG: sensitive high-resolution ion microprobe, reverse geometry) from 15 stratigraphically controlled Bishop Tuff samples and two Glass Mountain (GM) lava samples (domes OD and YA). Bishop zircon textures divide into four suites: (a) dominant sector-zoned grains, with (b) subordinate grains showing bright rims [lower U, Th, rare earth elements (REE)] in CL imaging, (c) sparse GM-type grains (texturally similar to zircons from GM dome YA) and (d) sparse Mesozoic xenocrysts from Sierran granitoid country rocks. All Bishop zircons from suites (a)–(c) combined have a weighted mean age of 777·9 ± 2·2 ka (95% confidence) and a tail back to ~845 ka. Our eruption age estimate using the weighted mean of 166 rim ages of 766·6 ± 3·1 ka (95% confidence) is identical within uncertainty to published estimates from isotope-dilution thermal ionization mass spectrometry (ID-TIMS) (767·1 ± 0·9 ka, 2) and 40 Ar/ 39 Ar (767·4 ± 2·2 ka, 2) techniques, the latter using the 28·172 Ma age for the Fish Canyon sanidine standard. We estimate also an eruption age for GM dome YA of 862 ± 23 ka (95% confidence), significantly older than the currently accepted 790 ± 20 ka K–Ar age. The oldest zircon cores from late-erupted Bishop material (including those with GM-type textures) have a weighted mean age of 838·5 ± 8·8 ka (95% confidence), implying that the Bishop Tuff system was active for only ~80 kyr, and had effectively no temporal overlap with the GM system. Trace element variations in Bishop zircons are influenced strongly for many elements by sector zoning, producing up to 3 x concentration differences between sides and tips within the same growth zone. Contrasting trends in molar (Sc + Y + REE 3+ )/P ratios between sides and tips indicate contrasting mechanisms of substitution in different sectors of the same crystal. Concentrations of Ti in tips are double those in the sides of crystals, hindering applicability of the Ti-in-zircon thermometer, in addition to variations inherent to the 0·15–0·67 range in values proposed for aTiO 2 . The bright-rim portions of grains are inferred to have crystallized from the same magma as that which generated the bright rims seen under cathodoluminescence or back-scattered electron imaging on quartz and feldspar, respectively. This less evolved, slightly hotter magma invaded the deeper parts of the chamber represented in the late-erupted northern units possibly up to ~10 kyr prior to eruption, but invaded shallower levels only very shortly before eruption, as shown by our textural information and previously proposed from the sharp delineation of quartz bright rims. By obtaining a large number of analyses from zircon separates that systematically cover the entire Bishop Tuff eruption sequence we can produce an eruption age estimate using SIMS to the same precision and accuracy as ID-TIMS and 40 Ar/ 39 Ar techniques.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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