ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound [5,5-(PMe2Ph)2-arachno-5,4,6-PdS2B6H8] contains a nine-vertex PdS2B6 cage with the Pd atom η4-bonded to two S and two B atoms. The Pd—S distances are notably asymmetric at 2.3588 (14) and 2.6759 (15) Å whereas the interatomic distances of symmetry-related pairs of Pd—B, S-B and B-B atoms indicate symmetric bonding. The two exo cage dimethylphenylphosphine ligands are attached to the Pd atom with Pd—P 2.2986 (15) and 2.2876 (13) Å. Bridging H atoms in the S2B6H8 moiety are asymmetrically bonded.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270195015952
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