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  • Articles  (67)
  • Springer  (39)
  • American Association for the Advancement of Science  (22)
  • American Institute of Physics (AIP)  (6)
  • Mineralogical Society of America
  • Physics  (59)
  • Chemistry and Pharmacology  (37)
Collection
  • Articles  (67)
Journal
  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 64 (1994), S. 2970-2972 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Heteroepitaxial growth of 2% lattice-mismatched EuTe on PbTe (111) by molecular beam epitaxy is investigated in the two-dimensional layer-by-layer growth regime combining in situ reflection high-energy electron diffraction and scanning tunneling microscopy (STM). At the critical layer thickness a distinct surface roughening is observed. The quantitative analysis of STM images yields an increase of the root mean square roughness by a factor of 4 at this roughening transition. Strong evidence is presented that for the used growth conditions this roughening is not caused by strain induced coherent islanding but by misfit dislocations at the onset of strain relaxation.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 69 (1996), S. 2822-2824 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Molecular beam epitaxy of PbTe on BaF2 (111) is studied using UHV–scanning tunneling microscopy and atomic force microscopy. It is shown that PbTe growth is totally dominated by growth spirals formed around threading dislocations (TD) that originate from the growth on the 4.2% lattice-mismatched substrate. Due to dislocation annihilation, the TD density rapidly decreases with layer thickness, which results in a dramatic increase of the electron mobilities in the layers. © 1996 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 111 (1999), S. 7801-7806 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Vibration–rotation–tunneling (VRT) spectroscopy has been extended to the 4 THz spectral region through the observation of a second intermolecular vibration of (D2O)4. Analysis of the precisely measured perpendicular transition confirms the previously reported cyclic homodromic structure and reveals a dramatically increased (30×) hydrogen bond rearrangement rate in the excited state. © 1999 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 4005-4015 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report the first high resolution spectrum of a librational vibration for a water cluster. Four parallel bands of (H2O)3 were measured between 510 and 525 cm−1 using diode laser vibration–rotation–tunneling (VRT) spectroscopy. The bands lie in the "librational band" region of liquid water and are assigned to the nondegenerate out of plane librational vibration. The observation of at least three distinct bands within 8 cm−1 originating in the vibrational ground state is explained by a dramatically increased splitting of the rovibrational levels relative to the ground state by bifurcation tunneling and is indicative of a greatly reduced barrier height in the excited state. This tunneling motion is of special significance, as it is the lowest energy pathway for breaking and reforming of hydrogen bonds, a salient aspect of liquid water dynamics. © 2001 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 3994-4004 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report the first direct observation of the hydrogen-bond stretching vibration for a water cluster. A perpendicular band of (D2O)3 was measured by terahertz laser vibration–rotation–tunneling spectroscopy at 142.8 cm−1 in the "translational band" region of the liquid corresponding to the hindered translational motions of water molecules. We have tentatively assigned the spectrum to transitions from the vibrational ground state to the degenerate hydrogen-bond stretch or a combination or mixed state of the degenerate stretch and a torsional vibration. Comparison with theoretical results shows that calculated frequencies are much too high, presumably because they do not include coupling between the torsional and stretching vibrations. © 2001 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 3988-3993 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report the observation of a new c-type band of (D2O)3 at 583.215 92(37) GHz, which we assign to the k=±20←±10 torsional hot-band. The new data includes the first observation of K=0 states for the k=+10 and k=−20 levels and effects a correct assignment of these states. A new perturbation was observed for the K=2 states of the k=+20←−10 subband splitting each transition into two equally spaced equal intensity doublets. Analysis of the band and inclusion into a global fit of all torsional bands produces negligible differences with previous analyses, and confirms the validity of the Hamiltonian developed to treat the coupling between torsional motion and overall rotation. The 583.2 GHz band completes the precise characterization of all (D2O)3 vibrational levels below 100 cm−1. © 2001 American Institute of Physics.
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  • 7
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Nanosize poly(methyl methacrylate) (PMMA) microlatexes with high PMMA/surfactant ratio have been successfully prepared by a modified microemulsion polymerization, i.e., continuous and slow addition of monomer (MMA) to the polymerizing MMA microemulsion with mild stirring. Number-average diameters of 33–46 nm with narrow polydispersity (Dv/Dn= 1.1) and polymer content of 6–24 wt% were achieved using low levels of surfactant (dodecyltrimethylammonium bromide, DTAB) — less than 1 wt% of the reaction mixture. Particle diameter depended on polymerization temperature, MMA content, and concentrations of initiator and surfactant. Larger particles wereformed when temperature was too high, initiator concentration was too high, or surfactant concentration was too low.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 63 (1930), S. 596-609 
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Zusammenfassung Es werden die vier transversalen galvanomagnetischen und thermomagnetischen Effekte bei adiabatischer Anordnung nach der Sommerfeldschen Theorie berechnet und die Beziehungen unter diesen Effekten theoretisch untersucht. Die verschiedenen thermoelektrischen Effekte in homogenen Kreisen werden diskutiert.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Solar physics 1 (1967), S. 5-15 
    ISSN: 1573-093X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Amplitude distributions, which are nearly Gaussian, have been calculated for radial velocity, continuum brightness, spectral line equivalent width and spectral line central residual intensity fluctuations measured from high-dispersion high-resolution spectrograms taken at the center of the solar disk. The RMS and skewness S for each distribution have been calculated in a manner which allows testing of the homogeneity of the granulation pattern (i.e. variations in its statistics across the solar disk and with time). Pattern inhomogeneity across the disk is strongly indicated, and further evidence suggesting appreciable pattern persistence over time intervals ≳ 15 minutes is presented. The possibilities for investigations of S and its associated bi-spectrum are discussed. The qualitative values of S obtained are shown not to be due to unusually bright, rising granules (though a statistical tendency towards such granules is possible). An attempt to explain S for continuum brightness fluctuations in terms of the nonlinear effects of Planckian emission and opacity fluctuations in a stratified photosphere, leads to contradiction with the measured amplitude distributions, a contradiction which is probably due to an oversimplified treatment of radiative transfer in an inhomogeneous photosphere.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Solar physics 22 (1972), S. 276-296 
    ISSN: 1573-093X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The application of the fast-Fourier-transform (FFT) algorithm to calculating one-dimensional and bi-dimensional (temporal and spatial), power and cross-power (coherence and phase) spectra is examined for solar photospheric fluctuations. Alternative methods for smoothing raw spectra, direct averaging (employing various weights) and indirect truncation of the correlation function, are compared, and indirect smoothing is compared with spectra calculated by mean-lagged-product (MLP) methods. Besides providing the raw spectrum, FFT techniques easily allow computing a series of spectra with varying amounts of smoothing. From these spectra a range of satisfactory compromise between resolution and stability can be determined which helps in the interpretation of spectral trends, and in identifying more clearly the existence and significance of spectral features. For bi-dimensional spectra presented as contour plots, this range of satisfactory smoothing can be restricted, particularly when spectral trends must be represented by small-scale contours. Equivalent spectra (i.e. comparable equivalent degrees of freedom) computed or smoothed by different methods have minor, but not negligible, differences. Examination of these differences favors computing of FFT spectra smoothed by averaging for photospheric fluctuations.
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