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  • Inorganic Chemistry  (2)
  • Wiley-Blackwell  (2)
  • American Association for the Advancement of Science
  • American Geophysical Union
  • Institute of Physics
Collection
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  • Wiley-Blackwell  (2)
  • American Association for the Advancement of Science
  • American Geophysical Union
  • Institute of Physics
Years
  • 1
    Electronic Resource
    Electronic Resource
    Silane. VIII. Alkalische Solvolyse von meta-substituierten Aryl-silanen (1967)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 351 (1967), S. 37-41 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The alkaline solvolysis of some meta-substituted aryl silanes in ethanol/water was investigated by kinetic methods. The specific rate constants demonstrate a great influence of substituents which can be interpreted by means of TAFTS σº constants.
    Notes: Die alkalische Solvolyse einiger meta-substituierter Aryl-silane in Äthanol/Wasser wurde kinetisch untersucht. Die spezifischen Geschwindigkeitskonstanten zeigen einen starken Substituenteneinfluß, der mit Hilfe der TAFTschen σº-Werte gedeutet werden kann.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19673510106
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  • 2
    Electronic Resource
    Electronic Resource
    Silane. XIIVorbericht: Z. anorg. allg. Chem. 370: 317 (1969).. Alkalische Solvolyse von substituierten Benzylsilanen (1970)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 374 (1970), S. 94-100 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Alcaline solvolysis of substituted phenyl and benzyl silanes listed in “Inhaltsübersicht” is compared. The inductive transfer coefficient of the CH2 group is fixed.
    Notes: Die alkalische Solvolyse von substituierten Phenyl- und Benzyl- silanen der Formeln \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{*{20}c} {\left({{\rm X} - {\rm C}_{\rm 6} {\rm H}_{\rm 4} } \right)_{\rm n} \left({{\rm CH}_{\rm 3} } \right)_{3 - {\rm n}} {\rm SiH}} \hfill \\ {\left({{\rm X} - {\rm C}_{\rm 6} {\rm H}_{\rm 4} - {\rm CH}_{\rm 2} } \right)_{\rm n} \left({{\rm CH}_{\rm 3} } \right)_{3 - {\rm n}} {\rm SiH}} \hfill \\\end{array} $$\end{document} wird verglichen. Hieraus wird der induktive Übertragungs-Koeffizient der CH2-Gruppe ermittelt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19703740113
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    Paper (German National Licenses)
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