ALBERT

Description: We present a conceptual model of fluid circulation in a ridge flank hydrothermal system, the Mariana Mounds. The model is based on chemical data from pore waters extracted from piston cores and from push cores collected by deep-sea research vessel Alvin in small, meter-sized mounds situated on a local topographic high. These mounds are located within a region of heat flow exceeding that calculated from a conductive model and are zones of strong pore water upflow. We have interpreted the chemical data with time-dependent transport-reaction models to estimate pore water velocities. In the mounds themselves pore water velocities reach several meters per year to kilometers per year. Within about 100 m from these zones of focused upflow velocities decrease to several centimeters per year up to tens of centimeters per year. A larger area of low heat flow surrounds these heat flow and topographic highs, with upwelling pore water velocities less than 2 cm/yr. In some nearby cores, downwelling of bottom seawater is evident but at speeds less than 2 cm/yr. Downwelling through the sediments appears to be a minor source of seawater recharge to the basaltic basement. We conclude that the principal source of seawater recharge to basement is where basement outcrops exist, most likely a scarp about 2–4 km to the east and southeast of the study area.

Description: Pore water has been analyzed from sediment cores taken from three areas on the eastern flank of the Juan de Fuca Ridge as part of FlankFlux 90, a study of hydrothermal circulation through mid-ocean ridge flanks. Seismic reflection and heat flow surveys (Davis et al., 1992a) indicate that the three areas differ in sediment thickness, basement topography, abundance of outcrops, basement temperature, and fraction of heat lost by advection versus conduction. Area 1 is on 0.6 Ma crust with nearly continuous basement outcrop, area 2 is on 1.3 Ma crust over the first buried ridge parallel to the present ridge axis, and area 3 is on 3.5–3.8 Ma crust over two axis-parallel buried ridges that penetrate the sediment cover in three locations. Each area includes a hydrothermal system in which seawater flows into basement, reacts with crustal basalt, and then exits basement either through the sediment or directly into the overlying water column. As constrained by concentrations of sulfate and lithium in the pore waters, at least some seawater enters basement in all three areas without reacting fully with the overlying sediment, even where no outcrops are known nearby. Speeds of up welling of pore water through the sediment have been estimated by fitting profiles of dissolved magnesium and chlorinity, which behave conservatively in these areas, to numerical time-dependent transport models. The estimated velocities range from 〈0.1 to 7.4 cm/yr; faster flows probably occur but were not sampled. Upwelling speed correlates positively with heat flow and basement highs and negatively with sediment thickness. The correlation with heat flow differs from area 2 to area 3 along with differences in physical properties of the turbidite sediment. We have documented pore water upwelling through sediment up to 100 m thick. We estimate that upwelling continues at decreasing speeds through sediment up to 160 m thick, corresponding to a heat flow of 0.44 W/m2 in area 2 and 0.3 W/m2 in area 3. Concentrations of magnesium and chlorinity in the altered seawater upwelling from basement are uniform within each area but differ from one area to the next. Both species remain at the bottom seawater concentration in area 1, where basement is cooled to 〈10°C at the base of the sediments mainly by advection. The concentration of magnesium decreases with increasing basement temperature in areas 2 and 3 to a minimum of 2.5 mmol/kg at about 90°C in area 3. The transition from largely advective to largely conductive heat loss occurs over only 20 km between areas 1 and 2 and corresponds to a dramatic change in the composition of fluid circulating through basement, as the uppermost basement is heated from 〈10° to 40–50°C. Chlorinity of the basement fluid increases above the present-day bottom seawater concentration in areas 2 and 3 and in nearly all other mid-ocean ridge flanks studied to date, as a result of rock hydration and the higher chlorinity of bottom seawater during the last glacial period. While chlorinity generally correlates positively with uppermost basement temperature in various ridge flank hydrothermal systems, it reaches a maximum in area 2 at only 40°C, probably because alteration there occurs at a lower water/rock ratio than elsewhere. For all mid-ocean ridge flanks studied to date, the temperature at the basement interface correlates better with the fraction of heat lost by advection versus conduction and with the average thickness of the sediment cover than with crustal age.

Description: We report total dissolved inorganic carbon (DIC) abundances and isotope ratios, as well as helium isotope ratios (3He/4He), of cold seep fluids sampled at the Costa Rica fore arc in order to evaluate the extent of carbon loss from the submarine segment of the Central America convergent margin. Seep fluids were collected over a 12 month period at Mound 11, Mound 12, and Jaco Scar using copper tubing attached to submarine flux meters operating in continuous pumping mode. The fluids show minimum 3He/4He ratios of 1.3 RA (where RA is air 3He/4He), consistent with a small but discernable contribution of mantle-derived helium. At Mound 11, δ13C∑CO2 values between −23.9‰ and −11.6‰ indicate that DIC is predominantly derived from deep methanogenesis and is carried to the surface by fluids derived from sediments of the subducting slab. In contrast, at Mound 12, most of the ascending dissolved methane is oxidized due to lower flow rates, giving extremely low δ13C∑CO2 values ranging from −68.2‰ to −60.3‰. We estimate that the carbon flux (CO2 plus methane) through submarine fluid venting at the outer fore arc is 8.0 × 105 g C km−1 yr−1, which is virtually negligible compared to the total sedimentary carbon input to the margin and the output at the volcanic front. Unless there is a significant but hitherto unidentified carbon flux at the inner fore arc, the implication is that most of the carbon being subducted in Costa Rica must be transferred to the (deeper) mantle, i.e., beyond the depth of arc magma generation.

Description: We present a conceptual model of fluid circulation in a ridge flank hydrothermal system, the Mariana Mounds. The model is based on chemical data from pore waters extracted from piston cores and from push cores collected by deep‐sea research vessel Alvin in small, meter‐sized mounds situated on a local topographic high. These mounds are located within a region of heat flow exceeding that calculated from a conductive model and are zones of strong pore water upflow. We have interpreted the chemical data with time‐dependent transport‐reaction models to estimate pore water velocities. In the mounds themselves pore water velocities reach several meters per year to kilometers per year. Within about 100 m from these zones of focused upflow velocities decrease to several centimeters per year up to tens of centimeters per year. A larger area of low heat flow surrounds these heat flow and topographic highs, with upwelling pore water velocities less than 2 cm/yr. In some nearby cores, downwelling of bottom seawater is evident but at speeds less than 2 cm/yr. Downwelling through the sediments appears to be a minor source of seawater recharge to the basaltic basement. We conclude that the principal source of seawater recharge to basement is where basement outcrops exist, most likely a scarp about 2–4 km to the east and southeast of the study area.

Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Progress in Earth and Planetary Science 5 (2018): 74, doi:10.1186/s40645-018-0232-3.

Description: South Chamorro Seamount (SCS) is a blueschist-bearing serpentinite mud volcano in the Mariana forearc. Previous scientific drilling conducted at SCS revealed highly alkaline, sulfate-rich formation fluids resulting from slab-derived fluid upwelling combined with serpentinization both beneath and within the seamount. In the present study, a time-series of ROV dives spanning 1000 days was conducted to collect discharging alkaline fluids from the cased Ocean Drilling Program (ODP) Hole 1200C (hereafter the CORK fluid). The CORK fluids were analyzed for chemical compositions (including dissolved gas) and microbial community composition/function. Compared to the ODP porewater, the CORK fluids were generally identical in concentration of major ions, with the exception of significant sulfate depletion and enrichment in sulfide, alkalinity, and methane. Microbiological analyses of the CORK fluids revealed little biomass and functional activity, despite habitable temperature conditions. The post-drilling sulfate depletion is likely attributable to sulfate reduction coupled with oxidation of methane (and hydrogen), probably triggered by the drilling and casing operations. Multiple lines of evidence suggest that abiotic organic synthesis associated with serpentinization is the most plausible source of the abundant methane in the CORK fluid. The SCS formation fluid regime presented here may represent the first example on Earth where abiotic syntheses are conspicuous with little biotic processes, despite a condition with sufficient bioavailable energy potentials and temperatures within the habitable range.

Description: This work was partly supported by JSPS KAKENHI Grant Number 25701004 (SK).