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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 403-408 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 15 Ill.
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  • 2
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dilute solution viscosity properties of fractions of two linear and one branched sample of polyvinyl acetate in benzene and of two linear and one branched fraction in several solvents were measured at 35°C. Values of total slope, b (from plots of ηsp/c vs. c), and intrinsic viscosities were obtained under the requirement that k′ + β = 0.500 ± 0.002. Empirical plots of log b vs. log [η] gave lines which were straight within the limits of accuracy of the data. For the linear fractions in benzene, Huggins' k′ was constant and the slope of the log b vs. log [η] line was 2; for the branched fractions in benzene, k′ increased with [η] and the slope of the log b vs. log [η] line was greater than 2. The log b vs. log [η] plots form the basis for a “one-point” method for determining [η]. Consideration of these data along with results reported in the literature indicates that k′ is measurably sensitive to branching only for fractions possessing a certain minimum combination of size and complexity. However, in some cases where the variations of k′ are inconclusive, use of the slope of the log b vs. log [η] line may provide a reliable indication of branching. It was found that a comparison between the branched and linear series could also be made at constant values of [η] or b. Two linear fractions in different solvents obeyed a type of Huggins relationship in which k′ did not vary with solvent and the slope of the log b vs. log [η] line was 2. For a higher molecular weight branched fraction, however, k′ varied from solvent to solvent and the slope of the log-log plot was about 1.7. These data do not support a reference point concept of “true” intrinsic viscosity based on a simple linear relationship between b and [η]. Preliminary results dealing with the effects of the shear rate indicated that the measured viscosity properties of branched fractions may be more seriously affected by changes in shear rate than those of linear fractions.
    Additional Material: 5 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 40 (1959), S. 457-468 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: New equations for evaluation of resonance (q) and electrical (∊) factors affecting copolymerization have been derived: \documentclass{article}\pagestyle{empty}\begin{document}$ \begin{array}{*{20}c} {r_1 } \hfill & { = \exp \left\{ { - {{\left( {q_1 - q_2 } \right)} \mathord{\left/ {\vphantom {{\left( {q_1 - q_2 } \right)} {RT}}} \right. \kern-\nulldelimiterspace} {RT}}} \right\}\exp \left\{ { - 7.23 \times 10^{20} \varepsilon _1 {{\left( {\varepsilon _1 - \varepsilon _2 } \right)} \mathord{\left/ {\vphantom {{\left( {\varepsilon _1 - \varepsilon _2 } \right)} {RT}}} \right. \kern-\nulldelimiterspace} {RT}}} \right\}} \hfill \\ {r_2 } \hfill & { = \exp \left\{ { - {{\left( {q_2 - q_1 } \right)} \mathord{\left/ {\vphantom {{\left( {q_2 - q_1 } \right)} {RT}}} \right. \kern-\nulldelimiterspace} {RT}}} \right\}\exp \left\{ { - 7.23 \times 10^{20} \varepsilon _2 {{\left( {\varepsilon _2 - \varepsilon _1 } \right)} \mathord{\left/ {\vphantom {{\left( {\varepsilon _2 - \varepsilon _1 } \right)} {RT}}} \right. \kern-\nulldelimiterspace} {RT}}} \right\}} \hfill \\ {r_1 r_2 } \hfill & { = \exp \left\{ { - 7.23 \times 10^{20} {{\left( {\varepsilon _1 - \varepsilon _2 } \right)^2 } \mathord{\left/ {\vphantom {{\left( {\varepsilon _1 - \varepsilon _2 } \right)^2 } {RT}}} \right. \kern-\nulldelimiterspace} {RT}}} \right\}} \hfill \\ \end{array} $\end{document} The new equations will apply over any temperature range, and will express ∊ in terms of e.s.u. and q in kcal./mole. These factors were determined for an extensive list of monomers and were tabulated. Agreement with Hammett σ values and other kinetic and theoretical considerations were found.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 18-25 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of estimating the true conditions of operation of a bubble-cap tray is presented. Intermediate between the Murphree and the Lewis methods, which represent the extremes of actual operation, this method involves the use of a correlation to determine the degree of liquid mixing on the tray and the use of new relations between the Murphree vapor efficiency, the Lewis case I efficiency, and the true local efficiency. For the last, partial liquid mixing is taken into account.Data were obtained on an 18-in. O.D. three-tray bubble-cap tower containing ten 3-in. bubble caps a tray. Partial liquid mixing was correlated for changes in vapor and liquid rates, pressure, temperature, and weir height for the system ethylene dichloride-toluene.Efficiency data on acetone-water, ethanol-water, and ethylene dichloride-toluene showed the following effects: (1) low concentration of lwo boiler usually, but not always, resulted in low true local efficiencies, always with high Murphree efficiencies; (2) vapor velocity effects are more intimately connected with slot velocity than superficial velocity (and hence entrainment); (3) raising the pressure gives higher efficiencies; (4) an increase in liquid depth increases the true local efficiency but may have no effect on the Murphree efficiency.
    Additional Material: 15 Ill.
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  • 5
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Previous publications have shown that for solid spheres fluidized in water a unique relationship exists between the slip velocity and the system holdup. With this work as a model a method is now presented for estimating the behavior of the liquid-in-liquid spray column in which droplets of one phase move through a second quiescent phase.Combining the solids fluidization results with information on the single droplet terminal velocity one can obtain a design estimate of the holdup or interphase contact area for the liquid-liquid spray column. This design estimate includes the particular nature of the liquid droplet of being susceptible to internal circulation, oscillation, and distortion.
    Additional Material: 14 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 184-189 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rate of mass transfer was measured for solid metal shapes dissolving into mercury at room temperature. Sherwood numbers for horizontal tin, cadmium, zinc, and lead cylinders dissolving by natural convection agreed with Nusselt numbers for heat transfer in nonmetallic liquids at the same Rayleigh (Grashof × Prandtl) numbers. Dissolving of zinc tubes by mercury flowing turbulently within them agreed with heat transfer to nonmetals in tubes. Dissolving of random beds of lead spheres by mercury flowing through the bed agreed with similar nonmetal systems. It is concluded that mass transfer processes in liquid metals follow substantially the correlations for other fluids in heat or mass transfer, which with moderate safey factors may thus be used for at least preliminary design purposes.
    Additional Material: 8 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 465-471 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental plate efficiency and pressure drop data were obtained on the n-octane-toluene system in a 5 plate, 6 in. diam. column at atmospheric pressure. Hole sizes of 1/16, 1/8, and 3/16 in.; 5.68 and 12.5% free areas; weir heights of 1, 2, and 3 in.; and plate spacings of 6, 12, 18, and 24 in. were studied. Reflux ratios of one, two, four, five, ten, and total were utilized to determine the effect on efficiency.It was found that hole diameter, free area, plate spacing, and a wide range of reflux ratio had relatively small effect on efficiency and pressure drop; however weir height and lower reflux showed relatively larger effects on both variables.Efficiencies and pressure drops were lower than those predicted from published correlations particularly at low flow rates.
    Additional Material: 12 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 245-248 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Photoggraphic methods have been used to study the behavior of water flowing freely down vertical surfaces under the influence of gravity at Reynolds numbers between 200 and 30,000. The physical appearances of the liquid layers in transitional and fully turbulent flow have been noted. Layer thicknesses have been obtained from high-speed photographs and correlated with liquid Reynolds numbers, the range of experimental data thus being extended into the fully turbulent region. A simple basis of comparison with flow between parallel plates has been developed.
    Additional Material: 3 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 136-142 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The pressure-drop characteristics associated with one liquid and one gaseous phase flowing concurrently in a pipe or tube have yet to be understood. The operation of evaporators, boilers, and condensers has long stimulated interest in the pressure drop of steamwater mixtures, and more recently this specialized case of one-component, two-phase flow has received even greater attention from the applications in cooling nuclear reactors. The two-phase-flow problems have not been amenable to through theoretical analyses, and therefore empirical and semiempirical correlations have attained unusual prominence in practical applications. The present investigation employs a new research tool for the study of two-phase-flow structure.A variety of geometric flow patterns is possible. Bergelin, Alves, and others have classified these patterns according to visual appearance; whereas the Martinelli classifications were based upon whether the flow in each phase was termed viscous or turbulent. The distinction between viscous and turbulent flow in either phase is rather arbitrary, and if the Reynolds number for one phase, calculated on the basis of the total tube diameter, is greater than 2,000, the flow in the phase is called turbulent. This investigation is confined to the study of annular flow, in which most of the liquid is found in an annular ring surrounding the central vapor core and the flow in each phase is turbulent.Boiling or flashing occurs when superheated water rises in an insulated vertical tube at atmospheric pressure. For a separated two-phase flow geometry, the mean linear steam velocity may exceed that of the water. The fraction of the tube occupied by the steam (void fraction) at a given cross section cannot be obtained directly from a determination of the thermodynamic quality. Void fractions, however, must be known for the estimation of the pressure drops due to head and momentum changes.Void fractions and pressure drops for steam-water flows were measured in an 0.872-in. I.D. vertical tube at atmospheric pressure over a quality range of 0 to 4%. The test section was the hot leg of a natural-circulation loop, and the inlet liquid flow rate ranged from 1 to 3 ft./sec. A new technique for measuring void fractions was used, and the method utilizes the difference between the gamma-ray absorption coefficients of water and steam.
    Additional Material: 12 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 462-466 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A kinetic study of the catalytic vapor-phase hydrogenation of three aldehydes (acetaldehyde, propionaldehyde, and n-butyraldehyde) was made at low conversions with a commercial supported nickel catalyst. A simple initial rate equation was determined and found to agree with a mechanism suggested by the ideal kinetics of Hougen and known experimental evidence. By means of this equation the relative reactivities of the aldehydes were compared and found to agree with the predictions of organic theory. An improved reactor designed to ensure isothermal operation is described.
    Additional Material: 2 Ill.
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