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  • Chemistry  (2)
  • 1960-1964  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Competing side reactions in the polymerization of α-olefins by ziegler-natta catalysts (1963)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 1 (1963), S. 2467-2476 
    Details
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The polymerization of 3-methylbutene-1 by TiCl3-Al(C2H5)3 catalysts in dilute solution above 80°C. yields a polymer which is contaminated with polyethylene. By using tagged aluminum alkyl, this polyethylene was shown to arise almost wholly by displacement of ethylene from the alkyl by the monomer. This side reaction was shown to be a general one in the polymerization of α-olefins other than propylene at elevated temperatures. Analysis of the gas phase above the reaction showed also that some decomposition of the monomer occurs under these conditions.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1963.100010722
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Linear polyglutaraldehyde (1963)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 1 (1963), S. 29-32 
    Details
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1963.110010108
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    Paper (German National Licenses)
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