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  • Chemical Engineering  (13)
  • 1960-1964  (13)
Collection
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 139-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The behavior of type-304 stainless steel in a forced-convection closed-loop lithium system was investigated over a wide range of temperatures and velocities. Fundamental information concerning the mechanism for mass transport has been obtained by examining solution and deposition effects along flat plates. The rate-determining process for solution is transport from the solid to the interface, whereas deposition rates are liquid-phase controlled.Liquid-phase mass transfer coefficients were correlated with a maximum deviation of approximately 15% by the use of von Kàrmàn's analysis of the turbulent boundary layer along a flat plate, combined with the Chilton-Colburn empirical modification of the Schmidt group. In contrast no adequate model is available for the prediction of solution rate constants which must be determined experimentally. Mean values of the solution rate constants ranged from 0.154 to 0.750 × 10-5 cm./sec. at temperatures from 510° to 612°C. These values are on the order of 103 smaller than corresponding liquid-phase mass transfer coefficients.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 61-63 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A continuous velocity distribution is derived which is based on an arbitrary modification of Prandtl's mixing length expression. The resulting velocity distribution agrees well with experiments for transition and fully developed turbulent flow throughout the entire cross section of the conduit. Furthermore the mixing length expression applies to parallel flow in smooth circular tubes and between infinite parallel plates with the same set of constants.
    Additional Material: 2 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 137-138 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 284-287 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 216-220 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Forced convection mass transfer between circular tubes and liquid lithium was experimentally investigated over a range of Schmidt numbers from 40 to 57 and Reynolds numbers from 5,550 to 22,500. Information concerning the mechanism for mass transfer was obtained by measuring local solution and deposition rates as a function of distance along the tubes. Observed entrance effects for the solution process suggest that it involves the parallel mechanisms of diffusion through a solid film and through occluded liquid in grain boundaries. It is indicated that the relative contributions of these processes changes with increasing temperature.A j-factor correlation of existing liquid metal mass transfer data for fully developed conditions in circular conduits is presented and indicates that an exponent of 0.112 for NRe best represents the data. This result agrees well with other studies (9).
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 423-425 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 513-518 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is shown that viscosity variations and temperature differences between the upper and lower walls can significantly increase or decrease the tendency toward instability. It was found that low Prandtl number fluids are most sensitive to gravitational field effects because they are characterized by a thicker thermal boundary layer.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 469-474 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The absorption of carbon dioxide in pure diethanolamine was studied in a gas-liquid stirred reactor at 85°, 95°, and 105°F. Over forty runs were made but only nineteen were reported here since several were invalidated by difficulties with the stirring mechanism and reaction-temperature control. The absorption was followed by pressure-time measurements with the carbon dioxide pressure ranging between 30 and 4 cm. of mercury. Experimental data were consistent and reproducible.An equation describing the gas-liquid absorption system was derived and then simplified by considering only the kinetic region. The experimental data were correlated with the simplified equation by both integral and differential methods and indicate that the reaction follows a third-order rate equation: first order in carbon dioxide and second order in diethanolamine. A mechanism explaining the observed order is described.Justification for assuming kinetic control of the absorption was demonstrated by doubling and tripling the stirring speed which produced no significant change in the absorption rate. Also, the temperature dependence of the pseudo-rate constants was out of the range of ordinary mass transfer control. This agrees with the results of a theoretical model reported previously (6).
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 330-339 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Significant changes in heat and momentum transfer rates can be caused by finite interfacial velocities and external field forces. This study considers the nonlinear problem of combined free and forced convection in vertical and horizontal two-dimensional conduits with finite transverse velocity.Similarity transformations for the temperature function have been found which reduce the energy, momentum, continuity, and state equations for these configurations to nonlinear systems of two coupled ordianary differential euqations. These equations are solved by approximate methods to give Nusselt numbers and friction factors as well as velocity and temperature profiles.Stream to wall temperature differences increase with suction and decrease with injection. The effects of interfacial velocity on temperature profiles and heat transfer increase dramatically with Prandtl number. Because blowing and suction strongly affect temperature profiles they substantially modify natural convection effects in vertical flows. Suction creates steeper transverse temperature gradients and accentuates buoyancy effects in vertical flows. Conversely injection flattens temperature profiles and thus decreases the influence of buoyancy on the velocity field.
    Additional Material: 16 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 896-901 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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