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  • Chemical Engineering  (80)
  • Wiley-Blackwell  (80)
  • 1960-1964  (80)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 139-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The behavior of type-304 stainless steel in a forced-convection closed-loop lithium system was investigated over a wide range of temperatures and velocities. Fundamental information concerning the mechanism for mass transport has been obtained by examining solution and deposition effects along flat plates. The rate-determining process for solution is transport from the solid to the interface, whereas deposition rates are liquid-phase controlled.Liquid-phase mass transfer coefficients were correlated with a maximum deviation of approximately 15% by the use of von Kàrmàn's analysis of the turbulent boundary layer along a flat plate, combined with the Chilton-Colburn empirical modification of the Schmidt group. In contrast no adequate model is available for the prediction of solution rate constants which must be determined experimentally. Mean values of the solution rate constants ranged from 0.154 to 0.750 × 10-5 cm./sec. at temperatures from 510° to 612°C. These values are on the order of 103 smaller than corresponding liquid-phase mass transfer coefficients.
    Additional Material: 6 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 428-430 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 478-481 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rate studies were carried out for the ortho-para hydrogen conversion at liquid nitrogen temperature with a multiple-impregnation nickel on aluminum oxide catalyst. Data were obtained at pressures up to 400 lb./sq. in. gauge over a range of flow rates for three catalysts of different pellet sizes.For the largest particle, ⅛-in. cylinders, diffusion resistances were significant. Effectiveness factors were evaluated and found to be somewhat less that 0.5 for this relatively active catalyst. After the diffusion resistances were accounted for, the surface rate was correlated on the basis of a mechanism supposing molecular hyddrogen to be adsorbed on the surface. Separate evaluation of the catalyst for the hydrogen-deuterium exchange reaction suggested that dissociation was not significant at liquid nitrogen temperature.
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 367-370 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A finite-difference method is presented for solving three-dimensional transient heat conduction problems. The method is a modification of the method of Douglas and Rachford which achieves the higher-order accuracy of a Crank-Nicholson formulation while preserving the advantages of the Douglas-Rachford method: unconditional stability and simplicity of solving the equations at each time level. Although the method has not yet been applied, the analysis in this paper suggests that it will prove to be the most efficient method yet proposed for the numerical integration of three-dimensional transient heat conduction problems.
    Additional Material: 1 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 437-441 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study has been made of the effect of fixed packing on the properties of a gas-fluidized bed, including minimum fluidization velocity, pressure drop, and bed expansion. Experiments using a range of glass beads as fluidizing solid with smooth uniform spheres as packing indicate that both packing size and the ratio of particle to packing diameter are the main variables in correlating the results. Other solids of varying density and shape have also been used. In addition to smooth spherical packing, rough spheres and variously shaped packings such as Raschig rings, Berl saddles, and a cylindrical, open-ended screen packing have received preliminary study. With the screen packing, which occupies only 5% of the column volume, it has been possible to operate a fluidized bed at a much higher gas throughput without slugging than is possible with a conventional bed.A preliminary study has also been made of heat transfer rates, and the results indicate that the same factors are significant. With spherical packing, values of h of the order of 70% of that in a conventional bed have been obtained, while with screen packing values ranging up to 100% or greater have been observed.Possible applications of this technique and its limitations are also discussed.
    Additional Material: 8 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 10-12 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rates of diffusion of helium, nitrogen, and carbon dioxide through alumina pellets were measured at atmospheric pressure and room temperature. The cylindrical pellets, ¾ in. diameter and ⅜ in. in length, were prepared from α-alumina particles with a mean pore radius of 65 Å. Surface area and pore volume data indicated that the corresponding mean pore radius of the micro and macropores in the whole pellet was 96 Å.The results showed that Knudsen type of diffusion was the controlling transport process despite the large fraction of void volume in the macropores. Carbon dioxide diffused more rapidly than expected, suggesting the possibility of migration of physically adsorbed molecules along the pore walls.The diffusion rates were about 16% higher than predicted, with a mean pore radius (Wheeler model) based upon the void volume of both micro and macropores used. However there is no logical basis for using this mean pore radius for a pellet having widely separated, micro and macropore size distributions.
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 216-220 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Forced convection mass transfer between circular tubes and liquid lithium was experimentally investigated over a range of Schmidt numbers from 40 to 57 and Reynolds numbers from 5,550 to 22,500. Information concerning the mechanism for mass transfer was obtained by measuring local solution and deposition rates as a function of distance along the tubes. Observed entrance effects for the solution process suggest that it involves the parallel mechanisms of diffusion through a solid film and through occluded liquid in grain boundaries. It is indicated that the relative contributions of these processes changes with increasing temperature.A j-factor correlation of existing liquid metal mass transfer data for fully developed conditions in circular conduits is presented and indicates that an exponent of 0.112 for NRe best represents the data. This result agrees well with other studies (9).
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 231-239 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pressure drop and liquid saturation accompanying two-phase concurrent flow have been studied in a variety of packings and with gas-liquid systems having a wide range of fluid properties. Two basic flow patterns were observed with nonfoaming systems. Correlations of pressuredrop and liquid-saturation data were obtained in terms of the single-phase friction losses for the liquid and the gas when each flows alone in the bed. Deviations from the correlation with foaming systems are discussed and illustrated with sample data.
    Additional Material: 9 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 526-529 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 34-38 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study was made of the effects the surface tension of aqueous solutions of surface-active agents had on the bubble-formation characteristics of these solutions. Bubbles were formed by two processes: by passing air through a horizontal orifice submerged in the solution and by nucleate boiling at an electrically heated surface. The experimental measurements taken with the air-bubble system were used to determine the nature of the surface-tension effect on air-bubble formation. This knowledge was then applied to the interpretation of boiling measurements made with the same solutions. The boiling coefficients of the Tergitol-water solution were found to vary inversely with dynamic surface tension. Boiling coefficients for Aerosol-water solutions, however, varied in a manner which could not be related to surface-tension effects.
    Additional Material: 7 Ill.
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