ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions The addition of thioacetic acid to theΔ 5 bonds of 16β- and 16α-mercapto-3β-hydroxypregn-5-en-20-one 3,16-diacetates (II) and (III) under radical conditions gives not only trans-diaxial addition products-6β,16β- and 6β,16α-dimercapto-3β-hydroxy-5o;-pregnan-20-one 3,6,16-triacetates (IV) and (V) -but also cis-addition products-6α,16β- and 6α,16α-dimercapto-3β-hydroxy-5α-pregnan-20-one 3,6,16-triacetates (VI) and (VII).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00905550
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