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  • Chemical Engineering
  • Inorganic Chemistry
  • 1965-1969  (386)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 411-414 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The profile of a growing droplet was determined with a pressure balance which was similar to that derived by Laplace for the static droplet. An additional term was added to the balance to account for the pressure on the interface due to the motion of the fluid within the droplet. The entire pressure balance was then combined with differential equations describing the geometry of the droplet. Computed profiles compared favorably with those obtained experimentally.An additional result was the definition of a parameter, f, indicating the importance of internal fluid motion on the shape of the profile. A method of estimating this parameter without solving the equations was developed.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 703-708 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis of oxygen absorption by blood flowing through a small oxygen-permeable fiber in steady state laminar flow is presented. The rigidity and geometry of the fibers eliminate unpredictable shunting and distention, permitting a more detailed analysis of blood-membrane factors than has previously been undertaken. The mathematical analysis treats the blood as a homogeneous, non-Newtonian fluid with a reversible nonlinear oxygen sink (erythrocytes). The differential equations are solved numerically and the results of the parametric analysis are presented. The parameters that have a major influence on residence time necessary to obtain a specified oxygen content are the Grashof number, the concentration of hemoglobin in the blood, and wall Nusselt number, γ: γ = DLαL/DMαM In [1 + tm/R] where D = diffusion coefficient, α = Bunsen solubility coefficient, subscript L = liquid in tube, subscript M = tube material, R = inner radius of tube, tm = tube wall thickness.Comparison of the experimental results to the model indicate that mixing due to the heterogeneous nature of blood is minimal and that the major limitation in oxygen absorption is the blood film. Means of reducing this resistance are discussed.
    Additional Material: 8 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1160-1166 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental investigation of heat transfer rates in which were used three spray towers varying from 4 to 6 in. in diameter and 7 to 10 ft. in height, and distributor elements with hole sizes varying from 1/8 to 1/64 in. in diameter was carried out. The immiscible liquid system consisted of water and kerosene (normal boiling point range 395° to 490°F.). Volumetric heat transfer coefficients ranged from 100 to 3,600 B.t.u./(hr.)(cu. ft.)(°F.) and the overall film heat transfer coefficients ranged from 4 to 23 B.t.u./(hr.)(sq. ft.)(°F.). Height equivalent to a theoretical stage varied from 1 to 8 ft. Scale-up correlations relating these rate data to operating variables were developed.
    Additional Material: 9 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 917-922 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study has been made of the expansion characteristics of beds of uniformly sized spherical particles of lead, nickel, sand, glass, and plastic that have been fluidized with air, carbon dioxide, and helium in columns packed with open-ended cylindrical screen packing. The addition of packing to a gas-fluidized bed limits the bubble size, prevents slugging and allows beds of high aspect ratio to expand smoothly in a manner similar to the behavior of liquid-fluidized beds. Moreover, much of the experimental data for gas-fluidized screen-packed beds have yielded straight lines on a Richardson-Zaki type of plot, again similar to the expansion of liquid-fluidized beds. The conditions necessary for this pseudoparticulate behavior in packed gas-fluidized beds are discussed. A correlation, based on the analysis given by Richardson and Zaki for liquid-fluidized beds, is proposed to relate bed porosity with gas velocity, density and viscosity, particle size and density, and bed diameter.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 472-477 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Axial mixing was measured in both phases for a countercurrently operated, mechanically agitated extractor of the Oldshue-Rushton design for water continuous and toluene and kerosene dispersed. Results in terms of an eddy axial diffusivity were correlated in terms of the variables studied. These correlations were then applied to column performance during extraction of n-butyl amine from kerosene into water, and the true mass transfer coefficients, corrected for axial mixing, were determined. These are shown to be predictable for droplets of dispersed phase considered to be rigid spheres.
    Additional Material: 7 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 504-507 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Numerical solutions of the equations of motion and energy are presented in the form of pressure-loss, flow-rate relationships for the laminar, nonisothermal flow of Newtonian and non-Newtonian fluids being heated and cooled in tubes at constant wall temperature. The flow properties are represented by a temperature-dependent form of the power law equation. The numerical results are shown to be in good agreement with experimental data for a wide range of fluid properties and flow conditions.
    Additional Material: 5 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 175-192 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 221-227 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mixing and a rapid, second-order irreversible chemical reaction were studied in a turbulent chemical flow reactor, with a point conductivity probe used to detect changes in concentration. From the mathematical theory of Toor, it is shown experimentally that data on the mixing of a passive scalar additive in a nonreactive system may be used accurately to predict the yield of a rapid, irreversible second-order reaction when the hydrodynamics and initial conditions on mixing for the reactive system are identical to those of the nonreactive system. Increasing the bulk average concentration of one reactant is shown to have a strong effect on the overall reaction yield.
    Additional Material: 9 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 995-999 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The results of rigorous numerical solutions of the general equations of motion are presented for isothermal, laminar, Newtonian flow in a tube entrance region for a uniform entrance velocity. Computed velocity profiles, entrance length, and pressure gradients are compared with previous theoretical and experimental results.
    Additional Material: 7 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 784-789 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analytical approach to mathematical expression of the mechanisms involved in typical slurry grinders is presented. Experimental equipment performance is correlated with developed formulas. Results are expressed in terms of fundamental machine and slurry parameters useful in predicting performance and scale-up.
    Additional Material: 7 Ill.
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