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  • Chemistry  (523)
  • 550 - Earth sciences
  • Condensed Matter: Electronic Properties, etc.
  • 1965-1969  (523)
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Publisher
Years
Year
  • 1
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The dependence of the cleavage of some cis/trans-isomers in the terpenoid and steroid series on the energy of the ionizing electrons have been studied.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 19 (1968), S. 796-804 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Electronmicroscope study of carbide precipitation in stainless steelsExtraktion replicas and thin metal foils can be used for the preparation of specimes for electron microscope investigation. Extraktion replicas enable the size of precipitated carbide particles and their distribution in the metal structure to be established. With the thin metal foils the precipitation mechanism and orientation relations between precipitate and base material can be studied. The experimental techniques are explained for two applications. In this connection the relation has been confirmed between chromium carbide precipitation at grain boundary and intercristalline corrosion of austenitic CrNi steel. It has been found that it is not carbide morphology but the continuity of the carbide network which plays the predominate role. In addition, direct evidence has been obtained of the fact that the knife-line corrosion found in the vicinity of weldseams is mainly due to Ti carbides occuring in Ti-stabilised steels.
    Notes: Zur herstellung elektromikroskopischer Präparate eignen sich Extraktionsabdrücke und dünne Metallfolien. Die Extraktionsabdrücke ermöglichen die Feststellung der Größe von ausgeschiedenen Carbidteilchen sowie der Verteilung dieser Teilchen im Gefüge. Die dünnen Metallfolien gestatten die Untersuchung des Ausscheidungsmechanismus und der Orientierungsbeziehungen zwischen Ausscheidung und Grundphase. Die Untersuchungstechniken werden anhand von zwei Anwendungen erläutert. Dabei wurde der Zusammenhang zwischen der Ausscheidung von Chromcarbiden an den Korngrenzen und der interkristallinen Korrosion austenitischer CrNi-Stähle bestätigt. In diesem Zusammenhang wurde gefunden, daß nicht die Carbidmorpholgie entscheidend ist, sondern die Kontinuität des Carbidnetzes. Außerdem wurde direkt nachgewiesen, daß die in Titan stabilisierten Stählen auftretenden Titancarbide die hauptursache für die Messerlinienkorrosion von Schweißverbindungen sind.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 483-489 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study concerns rates of evaporation and mass transfer of water vapor from a heated salt solution through a water repellent porous membrane to a cooled water condensate. This transfer is a result of temperature differences and corresponding vapor pressure differences across the membrane. Three groups of experiments were carried out which indicate that the major factor influencing the rates of transfer is diffusion through a stagnant gas in the membrane pores. However, an equation considering film heat transfer coefficients, membrane thermal conductivity, and an empiricial correction based on temperature driving force appears to be necessary for representing all the data. The empirical correction appears to be related to internal condensation and possibly diffusion along surfaces.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 78 (1966), S. 612-613 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 5 (1967), S. 465-472 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The rotatory dispersion of the β-form of polypeptides is considered. The parameter b0 of the Moffit-Yang equation is calculated quantum mechanically. The results obtained b0 = -30, agrees with experiment which gives b0 near zero for the β-form.
    Additional Material: 4 Ill.
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  • 6
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In this paper, the preferred conformations of the bases with respect to the sugar in various base-sugar units are worked out using criteria of potential energy. The van der Waals type of intercations between nonbonded atoms is represented by a 6-12 function and the electrostatic interactions have been calculated in the monopole approximation using Coulomb's law. The torsional contributions to the total energy have been neglected. It is found that in general the pyrimidines have preferred anti contributions (as described by Donohue and Trueblood) and purines have both syn and anti and conformations. Certain differences between differently puckered riboses in regard to the above general tendency are discussed. The conclusions, in general, conform with the results obtained by us earlier with the use of hard-sphere potential and are also supported by observations on conformations of nucleotides and nucleotides in crystal structure.
    Additional Material: 6 Ill.
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  • 7
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The potential energy calculations on the sugar-phosphate unit for different puckerings of the sugar are reported in this paper. The results obtained here essentially confirm our earlier predictions made by using criteria of contact distances (hard-sphere potential) and are also supported by observed conformation in crystal structures. The minimum energy conformations of the sugar phosphate unit, along with the preferred orientations of the base with respect to the sugar given in the previous paper, determine the probable conformations of the monomer unit of a polynucleotide (or nucleic acid) chain.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: As part of a study on the conformation of polynucleotides and nucleic acids the preferred conformations of the model conpound dimethyl phosphate are worked out using potential energy functions. In calculating the total potential energy associated with the conformation, nonbonded, torsional, and electrostatic terms have been considered. The variation of the total conformational energy is represented as a function of two torsion angles φ and ψ which are the rotations about the two phosphoester bonds. The most stable conformations are found to be the gauche-gauche conformations about these bonds. The conformations observed for phosphodiesters in the solid state and in the proposed structures of polynucleotides and nucleic acids cluster around the minimum. Also, regions of minimum energy correspond well with the typical allowed regions of a representative dinucleotide.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 12 (1968), S. 1-8 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Anhydrous gelatin-glycerol compositions exhibit rubbery behavior in the temperature region -40 to +40°C. and in the gelatin weight fraction range 0.1-0.4. These rubbers are capable of sustaining considerable stress over several decades of time at room temperature or below but flow rapidly in the region 45-60°C. Stress relaxation moduli at 25°C. appear to be insensitive to the substitution of glycerol with water but shear viscosity data indicate that gelatin-glycerol rubbers flow at temperatures about 15°C. higher than their aqueous counterparts.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Some esters of γ, δ-unsaturated or β-arylsubstituted acids undergo a peculiar transformation under electron-impact including an elimination of the alcohol residue as a radical R. with the following loss of the ketene molecule. One of the oxygen atoms of the carbonyl group enters an ion which is formed from an unsaturated part of the molecule. The possible mechanism of this reaction and the influence of structural modifications on the course of this process are discussed.
    Additional Material: 2 Ill.
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