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  • Chemistry  (523)
  • Physics  (67)
  • Industrial Chemistry  (18)
  • Wiley-Blackwell  (590)
  • American Geophysical Union
  • PANGAEA
  • 1965-1969  (590)
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  • Wiley-Blackwell  (590)
  • American Geophysical Union
  • PANGAEA
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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 7 (1969), S. 157-172 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Self-protective polyesters were synthesized in two ways: by polymer analog transformations on polymers obtained and by introduction of inhibiting groups into the polymer during synthesis. It is shown that the Fries rearrangement takes place in the aromatic polyesters in the presence of the Friedel-Crafts catalysts and on ultraviolet irradiation as well. Thermogravimetric analysis of the rearranged polymers and investigations of the influence of the ultraviolet irradiation on their properties show that the rearrangement markedly increases the photochemical and thermal stability of the polymers. Photostabilization may also be accomplished by the introduction of inhibiting groups, such as hydroxyl, sulfur, or phosphorus into the polymer molecule.
    Additional Material: 9 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 6 (1968), S. 1351-1365 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The thermal stability of the isomeric poly-1,2,4-oxadiazole (PO-2) and poly-1,3,4-oxadiazole (PO-3) was investigated. The isomerism of the ring substantially influenced polymer thermostability. The weight losses in PO-2 occur above 220-230°C. in vacuo, but PO-3 degrades only at 280-300°C. The weight changes in isomeric polyoxadiazole at lower temperatures are connected with the completion of the cyclization process. At higher temperatures degradation of the oxadiazole ring takes place, and as a result carbon and nitrogen oxides, 4,4′-dicarboxy (diphenyl ether) dinitrile and other products are evolved. The mechanism of polymer thermal degradation is examined; it is shown that the weakest bonds are C—O and N—O. These data are in a good agreement with the results of calculation of the π-electron systems of unsubstituted oxadiazole cycles in the framework of the molecular orbital treatment in the Hückel approximation. It is shown that the oxygen in the oxadiazole ring oxidizes the products of thermal degradation of polymers and a cell effect takes place. The thermal oxidation of isomeric polyoxadiazoles does not differ essentially from the degradation in vacuo. It was found that the formation of intermediate products such as peroxides and hydroperoxides does not take place, and oxygen does not act as an initiator of polymer degradation.
    Additional Material: 8 Ill.
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  • 3
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The dependence of the cleavage of some cis/trans-isomers in the terpenoid and steroid series on the energy of the ionizing electrons have been studied.
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 6 (1968), S. 2715-2727 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Repeatedly grafted copolymers (pemosors) were obtained by grafting one and the same or different vinyl monomers onto heterochain polymers in a radical reaction. As starting polymers films of polyethylene terephthalate and poly-ε-caproamide were used. Styrene and methyl methacrylate were the grafted vinyl monomers. It has been shown that pemosors could be formed in yields of 500-1000% (of the starting sample weight) by multiple grafting on vinyl polymer. Pemosors differ in appearance both from the starting polymers and the single-graft copolymers. Investigations of pemosor samples by electron microscope showed that the morphological structure of the surface was appreciably affected, the changes being more significant with increasing content of the grafted polymer. X-Ray studies and NMR data on pemosors showed that multiple grafting of vinyl monomers does not change the crystal structure of the starting polymers, affecting only the supermolecular structure of the outer layer. Pemosors are polymers of a new type, differing in their properties from the starting polymers and the single-graft copolymers. The grafting character and penetration depth of the grafted monomer depend on the packing compactness of the supermolecular structure of the polymeric base as well as on the chemical nature of the starting polymers and monomers. Pemosors possess considerable chemical resistance and withstand prolonged boiling in 40% alkali solution.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 5 (1967), S. 771-780 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The activity coefficient γNa+, of sodium ion, in aqueous solutions of both isotactic and conventional poly(methacrylic acid) (PMA) has been studies throughout the whole range of degree of neutralization α with a Beckman Na electrode and membrane electrodes. The results show that the fraction of sodium ions bound to isotactic PMA is higher than that bound to conventional (or syndiotactic) PMA over the entire range of α. The binding of divalent counterions (Mg+2, Cu+2, Co+2, and Ni+2) by the two forms of PMA (at α = 0.95) has been evaluated from the release of Na+ ions with the Beckman Na electrode. Turbidimetric determinations of the critical amount of various divalent cation chlorides necessary to bring about precipitation of both isotactic and conventional PMA (at α = 0.95) have also been carried out.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 19 (1968), S. 796-804 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Electronmicroscope study of carbide precipitation in stainless steelsExtraktion replicas and thin metal foils can be used for the preparation of specimes for electron microscope investigation. Extraktion replicas enable the size of precipitated carbide particles and their distribution in the metal structure to be established. With the thin metal foils the precipitation mechanism and orientation relations between precipitate and base material can be studied. The experimental techniques are explained for two applications. In this connection the relation has been confirmed between chromium carbide precipitation at grain boundary and intercristalline corrosion of austenitic CrNi steel. It has been found that it is not carbide morphology but the continuity of the carbide network which plays the predominate role. In addition, direct evidence has been obtained of the fact that the knife-line corrosion found in the vicinity of weldseams is mainly due to Ti carbides occuring in Ti-stabilised steels.
    Notes: Zur herstellung elektromikroskopischer Präparate eignen sich Extraktionsabdrücke und dünne Metallfolien. Die Extraktionsabdrücke ermöglichen die Feststellung der Größe von ausgeschiedenen Carbidteilchen sowie der Verteilung dieser Teilchen im Gefüge. Die dünnen Metallfolien gestatten die Untersuchung des Ausscheidungsmechanismus und der Orientierungsbeziehungen zwischen Ausscheidung und Grundphase. Die Untersuchungstechniken werden anhand von zwei Anwendungen erläutert. Dabei wurde der Zusammenhang zwischen der Ausscheidung von Chromcarbiden an den Korngrenzen und der interkristallinen Korrosion austenitischer CrNi-Stähle bestätigt. In diesem Zusammenhang wurde gefunden, daß nicht die Carbidmorpholgie entscheidend ist, sondern die Kontinuität des Carbidnetzes. Außerdem wurde direkt nachgewiesen, daß die in Titan stabilisierten Stählen auftretenden Titancarbide die hauptursache für die Messerlinienkorrosion von Schweißverbindungen sind.
    Additional Material: 13 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 15 (1969), S. 483-489 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study concerns rates of evaporation and mass transfer of water vapor from a heated salt solution through a water repellent porous membrane to a cooled water condensate. This transfer is a result of temperature differences and corresponding vapor pressure differences across the membrane. Three groups of experiments were carried out which indicate that the major factor influencing the rates of transfer is diffusion through a stagnant gas in the membrane pores. However, an equation considering film heat transfer coefficients, membrane thermal conductivity, and an empiricial correction based on temperature driving force appears to be necessary for representing all the data. The empirical correction appears to be related to internal condensation and possibly diffusion along surfaces.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 78 (1966), S. 612-613 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 5 (1967), S. 465-472 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The rotatory dispersion of the β-form of polypeptides is considered. The parameter b0 of the Moffit-Yang equation is calculated quantum mechanically. The results obtained b0 = -30, agrees with experiment which gives b0 near zero for the β-form.
    Additional Material: 4 Ill.
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  • 10
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In this paper, the preferred conformations of the bases with respect to the sugar in various base-sugar units are worked out using criteria of potential energy. The van der Waals type of intercations between nonbonded atoms is represented by a 6-12 function and the electrostatic interactions have been calculated in the monopole approximation using Coulomb's law. The torsional contributions to the total energy have been neglected. It is found that in general the pyrimidines have preferred anti contributions (as described by Donohue and Trueblood) and purines have both syn and anti and conformations. Certain differences between differently puckered riboses in regard to the above general tendency are discussed. The conclusions, in general, conform with the results obtained by us earlier with the use of hard-sphere potential and are also supported by observations on conformations of nucleotides and nucleotides in crystal structure.
    Additional Material: 6 Ill.
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