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  • Articles  (542)
  • Chemical Engineering  (276)
  • General Chemistry  (266)
  • AERODYNAMICS
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  • 1965-1969  (425)
  • 1955-1959  (117)
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  • 11
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The separation of 4.5 g. of americium from approximately a kilogram of light rare earths (primarily lanthanum) was achieved on a pilot plant scale by chromatographic displacement of the mixture from Dowex-50 resin with 0.1% ammonium citrate at pH 8 into hydrogen-form Dowex-50. The americium collected into a narrow band and was eluted free from lanthanum but contained an equal weight of cerium. A 6- and a 2-in.-diam. column were used in tandem. Use of a final column with a much smaller diameter would have permitted a cleaner separation from cerium, but this was left for a laboratory-scale separation by a different process. Precipitation, which was observed in the columns during the first runs, was later avoided entriely by use of high flow rates both initially and during the transfer between columns. No adverse effects were noted from ∼15 curies of alpha activity.
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  • 12
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 397-402 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In connection with a study of the mechanism of gas absorption the problem arose of predicting absorption rates into laminar liquid jets. A solution to the problem is presented in this paper, which provides an example of the application of fluid dynamics to the analysis of mass transfer in a complex flow system.The water jets considered here issued from circular nozzles of about 1.5-mm diameter, flowed intact downward through an atmosphere of solute gas at average velocities of from 75 to 550 cm./sec. over distances of 1 to 15 cm., and were collected in a receiver slightly larger in diameter than the nozzles. Equations describing the liquid flow near the jet surface are deduced from measurements of jet diameter and analogy to related flow situations. When one uses these equations, absorption rates are predicted from unsteady state diffusion theory with the assumption of interfacial equilibrium. The predicted rates for carbon dioxide at 25°C are in close agreement with experimental determinations over the observed range of contact time of the liquid with gas, namely 0.003 to 0.04 sec.
    Additional Material: 6 Ill.
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  • 13
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 726-736 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Several methods that can be used to obtain solutions to the laminar boundary layer momentum, energy, and diffusion differential equations for moving continuous flat surfaces with suction and injection are presented. Results are obtained for a wide range of the injection parameter, f(0), at Prandtl and Schmidt numbers of 1, 10, and 100. Those methods which permit hand calculation of the properties of interest are compared using the numerical solutions of the boundary layer differential equations as the exact solutions. The new integral method of Hanson and Richardson which gives results for the momentum thickness that deviate less than 2.2% from the exact values is recommended for predicting values of the momentum boundary layer parameters. The Von Karman-Pohlhausen method, which was modified to account for suction and injection, is most generally valid. This method gives acceptable values of the transfer coefficients for heat, mass and momentum transfer for most of the values considered.
    Additional Material: 9 Ill.
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  • 14
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 797-800 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The captured vortex system produced by the flow of a fluid along a plate containing a transverse rectangular cavity was investigated by measuring the local mass transfer coefficient kg on the cavity walls. Both transverse and peripheral kg profiles are presented for cavity depth-to-length ratios of 0.5, 1.0, and 2.0 at free-stream velocities of 6.8, 13.5, and 27 ft./sec. for water evaporating into air. These profiles reflect the three-dimensional nature of the flow in the cavity.
    Additional Material: 12 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 236-241 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The decreasing solubility of hydrogen in hydrocarbons with decreasing temperature continues down to the freezing point of the hydrocarbons, around -300°F. This behavior is shown to be an enlargement of phenomena exhibited by normal hydrocarbon mixtures. Methods of predicting equilibrium-phase compositions are presented for hydrogen in ligh-hydrocarbon systems. The correlations are satisfactory for binary and certain ternary systems, but are not reliable for complex mixtures.
    Additional Material: 18 Ill.
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  • 16
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 382 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 290-294 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In a determination of the effect of solute concentration on gas-phase mass transfer rates carbon tetrachloride was vaporized at three different concentration levels in a short 4.0-in.-diameter column packed with 0.5-in. Raschig rings.The experimental data indicate that previous mass transfer correlations should be modified to include a term (PBM/PT)2/3 and that the Schmidt number should be evaluated at average film conditions.The correlation found is suitable for predicting gas-phase mass transfer coefficients which can be combined with effective interfacial areas reported previously to obtain volumetric mass transfer coefficients for any gas-liquid-solute system.
    Additional Material: 10 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 268-273 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The motion of individual air bubbles in a water stream flowing turbulently in a 4 in. × 4 in. vertical conduit is investigated by photographic means. The bulk water velocity ranges from 40.8 to 267 cm./sec., corresponding to a system Reynolds number range of 48,600 to 386,000. Both tap and demineralized water were used at or near room temperatures. Air bubbles range from 0.038 to 0.70 cm. in equivalent radius and the corresponding bubble Reynolds number based on relative velocity ranges from 58 to 4,500.The results indicated that the bubble relative velocity in a turbulent water stream is similar to the rise velocity of single bubbles through a quiescent liquid. It was found to be practically independent of the system Reynolds number for bubbles having an equivalent radius above 0.3 cm. Large fluctuations in the bubble velocities were noted in all cases. The drag coefficient is, in general, lower for the demineralized water tests than for tap water when the bubble Reynolds number is below 2,000. Above this value, a mergence of the drag coefficients for all tests occur with a peak of approximately 2.0 at a bubble Reynolds number of 3,000, which is lower than the nonflow value of 2.6.
    Additional Material: 9 Ill.
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  • 19
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 819-822 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 20
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 67 (1955), S. 178-178 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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