ISSN:
1588-2837
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Abstract Константа скорости реакции O+CO+O2→CO2+O2 в температурном интервале 400–5000K на основании данных /9/ может бытъ выражена формулой к=6,5·10−36 exp(3700/RT) cm3молъ−1сек−1. Отрицателдъная энербия активации, предположителъно, обусловлена механизмом O+O2⇆O 3 * (+M)⇆O 3 ′ (+M)+CO=CO2+O2, бде O 3 ′ стабилизированная, возбужденная молекула озона, возмоЗно, находящаяся в триплетном состоянии.
Notes:
Abstract On the basis of the results reported in Ref. [9], the rate constant for the reaction O+CO+O2→CO2+O2 can be expressed as k=6.5×10−36 (3700/RT) cm3 mol−1s−1 in the temperature range of 400–500 K. It is suggested that the negative activation energy can be accounted for by the mechanism is a stabilized, excited ozone molecule, possibly in the triplet state.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02075114
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