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  • 1970-1974  (9)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie in unserer Zeit 8 (1974), S. 72-77 
    ISSN: 0009-2851
    Keywords: Chemistry ; Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 46-49 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal Structure of l,2,3,4,4a,9a-hexahydro-4a,9-propanocarbazolium HydrobromideThe crystal structure of the title compound has been determined by X-ray structure analysis. From these results a twist angle of 64.5° of the orbital of the nitrogen is derived.
    Notes: Auf röntgenographischem Weg wurde die Kristallstruktur der Titel-Verbindung bestimmt. Aus den so erhaltenen Ergebnissen resultiert ein Verdrillungswinkel des Orbitals am Stickstoff von ϕpH = 64.5°.
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 107 (1974), S. 2326-2328 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 2-Propyl-cis-perhydroquinolin-5α-olReaction of 1,3-cyclohexanedione with 1-chloro-3-hexanone (2), followed by reductive amination yields 2-propyl-1,2,3,4,5,6,7,8-octahydro-5-quinolinon (4). On hydrogenation with Pt in acetic acid 2-propyl-cis-perhydroquinolin-5α-ol (5) is obtained.
    Notes: Ausgehend von 1,3-Cyclohexandion wurde durch Umsetzung mit 1-Chlor-3-hexanon (2) und nachfolgende reduktive Aminierung das 2-Propyl-1,2,3,4,5,6,7,8-octahydro-5-chinolinon (4) erhalten. Hieraus entsteht bei der Hydrierung mit Pt in Eisessig 2-Propyl-cis-perhydrochinolin-5α-ol (5).
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 104 (1971), S. 524-527 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal and Molecular Structure of a Dimer of N-MethylazepineAbove 0°C N-Methylazepine dimerizes very fast, yielding two isomers. The structure 5e of the higher melting of both is elucidated by X-ray crystal structure analysis.
    Notes: N-Methyl-azepin dimerisiert oberhalb 0° sehr rasch. Es entstehen zwei Isomere. Die Struktur des höherschmelzenden von beiden wird auf röntgenographischem Weg im Sinne von Formel 5e bewiesen.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 742 (1970), S. 145-151 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 3β-Hydroxy-4,4,14-trimethyl-Δ8-5α-pregnen-20-oneBy stepwise oxidative degradation of the side chain of lanosterol (1a), 3β-hydroxy-4,4,14-trimethyl-Δ8-5α-pregnen-20-one (15a) has been obtained (overall yield 10%).
    Notes: Durch stufenweisen oxydativen Abbau der Seitenkette von Lanosterin (1a) wird 3ß-Hydroxy-4.4.14-trimethyl-Δ8-5α-pregnen-20-on (15a) in einer Gesamtausbeute von rund 10% gewonnen.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 742 (1970), S. 138-144 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Thermic and Mass Spectroscopic Behaviour of Berberine and Other PseudobasesThe three possible types of pseudobases - immonium hydroxide, carbinolamine and aminoaldehyde - shows striking differences in their mass spectra. Carbinolamines undergo a thermal disproportionation into amide and amine, which gives rise to a “M - 14”-peak; aminoaldehydes form fragments characteristic for aldehydes, while with immonium hydroxides the favoured fragmentation reactions are the elimination of water and the splitting off of an OH-radical.
    Notes: Pseudobasen geben in Massenspektrum verschiedene Zerfallsschemata, je nachdem ob sie als Carbinolamin, als Aminoaldehyd oder als Immoniumhydroxid reagieren. Carbinolamine disproportionieren thermisch in Säureamid und Amin, wodurch eine “M - 14”-Spitze vorgetäuscht wird; bei Aminoaldehyden treten die charakteristischen Bruchstücke von Aldehyden auf, während bei den Immoniumhydroxiden die Eliminierung von Wasser und die Abspaltung eines OH-Radikals die Hauptfragmentierungsreaktionen sind.
    Additional Material: 3 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 731 (1970), S. 53-57 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Toxins of Mediterranean Holothuriae, II1). The Aglycones of the Toxins of Holothuria poliiSix aglycones have been isolated from the toxins of the skin of Holothuria polii (Delle Chiaje) and their structures elucidated by means of spectroscopic data. The 22-O substituted compounds 1-3 have already been detected in other Holothurioideae. The remaining, as yet unknown, compounds, are holothurinogenin (4), 25-methoxyholothurinogenin (5), and 17-deoxy-25-methoxyholothurinogenin (6).  -  The hitherto unknown configuration at C-20 could be deduced from NMR-data.
    Notes: Aus den in der Haut von Holothuria polii (Delle Chiaje) enthaltenen Toxinen werden sechs Aglyka isoliert und auf spektroskopischem Wege in ihrer Struktur aufgeklärt. Die 22-O-substituierten Komponenten 1-3 waren bereits von anderen Holothurioideen her bekannt. Bei den bislang unbekannten Substanzen handelt es sich um Holothurinogenin (4), 25-Methoxy-holothurinogenin (5) und 17-Desoxy-25-methoxy-holothurinogenin (6).  -  Aus NMR-Daten ist die bisher ungeklärte Konfiguration an C-20 abgeleitet worden.
    Additional Material: 1 Tab.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 750 (1971), S. 128-135 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Disproportionation of PseudobasesThe alkali-catalyzed disproportionation of pseudobases is, according to the experiments described, a heteroanalogous Cannizzaro reaction and is intermediate between the acid-catalyzed disproportionation of the benzhydrols and the alkali-catalyzed Cannizzaro reaction.
    Notes: Die durch Alkali katalysierte Disproportionierung der Pseudobasen stellt nach den vorliegenden Untersuchungen eine heteroanaloge Cannizzaro-Reaktion dar und nimmt eine Mittelstellung zwischen der sauer katalysierten Disproportionierung der Benzhydrole und der alkalisch katalysierten Cannizzaro-Reaktion ein.
    Additional Material: 1 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1974 (1974), S. 169-175 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Isolation and Structure of Larreagenin AFour glycosides have been isolated from leaves of the central american plant Larreu divaricata Cav.; the structure of one of the aglycons, larreagenin A, has been elucidated by means of 1H-NMR- and 13C-NMR-investigation together with other spectroscopic data as 3β-hydro-xy-29-nor-urs-13(18)-en-20β,28β-olide (4). Larreic acid, isolated from the same plant as glycoside, can be isomerized to larreagenin A.
    Notes: Aus Blättern der mittelamerikanischen Pflanze Lurrea divaricata Cav. wurden 4 Glykoside isoliert; die Struktur eines der Aglyka, das Larreagenin A wurde mit Hilfe von 1H-NMR- und 13C-NMR-Untersuchungen sowie anderer spektroskopischer Daten als 3β-Hydroxy-29-nor-urs-l3(18)-en-20β,28β-olid (4) aufgeklärt. Die aus der gleichen Pflanze als Glykosid isolierte Larreasäure läßt sich zu Larreagenin A isomerisieren.
    Additional Material: 1 Ill.
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