ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
The compounds M(CO)5 · THF (M = Cr, Mo, W) react with sodium mercaptide, NaSR (R = C6F5, C6H5, C2H5), to give the mercapto-pentacarbonylmetallate anions [M(CO)5 · · SR]-. The preparation of some pentafluorophenylthio complexes, e. g. [(C6H5)3P]2MSC6F5(M = Cu, Ag, Au), [(C6H5)3P]2Hg(SC6F5)2, is reported.
Notes:
Die Mercapto-pentacarbonylmetallat-Anionen [M(CO)5SR]- (M = Cr, Mo, W; R = C6F5, C6H5, C2H5) entstehen durch Umsetzung von M(CO)5THF und Natriummercaptid. Darstellung und Eigenschaften einiger phosphinhaltiger Pentafluorphenyltio-Komplexe von Kupfer(I), Silber(I), Gold(I), Kobalt(II) und Quecksilber(II) werden beschrieben.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19703750304
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