ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. In the reactions of the ambident anions of 1,1-dinitroalkanes (dinitroethane and dinitropropane) with acetyl and benzoyl chlorides these anions are acylated only on a nitro oxygen atom with formation of the corresponding O-acyl derivatives. 2. These unstable O-acyl derivatives undergo a number of further transformations; in the case of the 1,1-dinitroethane anion 1,1-dinitroethyl acetonitrolate, acetic or benzoic acetonitrolic anhydride, and 1,1-dinitroethane are formed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00996517
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