ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
The polarographic behaviour of the anions nitrosodicyanmethanide and nitrodicyanmethanide is described. Contrary to the homologous oxoanions nitrite and nitrate the dicyanmethanidooxoanions are reduced, hydroxylamine being formed as an intermediate product, The results are discussed, assuming an influence of the asymmetric structure of the anions.
Notes:
Das polarographische Verhalten des als Nitritanalogon zu betrachtenden Nitrosodicyanmethanidions und des Nitratanalogons Nitrodicyanmethanid wird beschrieben. Infolge ihres asymmetrischen Baues werden die Dicyanmethanido-oxoanionen reduziert. Als Zwischenprodukt bildet sich Hydroxylamin.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19713800307
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