ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Organometalphosphine-substituted Transition Metal Complexes, VII. Organometalphosphinetricarbonylnickel(0) ComplexesThe reaction of tetracarbonyl nickel with tri(tert-butyl)phosphine, tris(trimethylsilyl)-, tris(trimethylgermyl)-, tris(trimethylstannyl)-, and tris(trimethylplumbyl)phosphine as well as with trimethylstannyldiphenylphosphine, bis(trimethylstannyl)phenylphosphine, and bis(diphenylphosphino)phenylarsine results in the elimination of one CO-ligand and the formation of corresponding organometalphosphinetricarbonylnickel(0) complexes. The i.r., 1H n.m.r., and 31P n.m.r. spectra are reported and discussed.
Notes:
Tetracarbonylnickel reagiert mit Tri(tert.-butyl)-phosphin, Tris(trimethylsilyl)-, Tris(trimethylgermyl)-, Tris(trimethylstannyl)- und Tris(trimethylplumbyl)-phosphin sowie mit Trimethylstannyl-diphenyl-phosphin, Bis(trimethylstannyl)-phenyl-phosphin und Bis(diphenylphosphino)-phenyl-arsin unter Abspaltung eines CO-Liganden und Bildung entsprechender Organometallphosphin-tricarbonyl-nickel(0)-Komplexe. Die Infrarot-, 1H-NMR-und 31P-NMR-Spektren werden mitgeteilt und diskutiert.
Additional Material:
5 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19701030510
Permalink
