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  • Chemistry  (3)
  • Inorganic Chemistry  (3)
  • 1970-1974  (3)
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  • Chemistry  (3)
  • Inorganic Chemistry  (3)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 380 (1971), S. 23-29 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Hydrazinium monochloride disproportionates on interaction with diphenyl-trichlorophosphorane, giving N2 and [(C6H5)2P(Cl)—N—PCl(C6H5)2]Cl. The phosphinazine dihydrochloride [(C6H5)2PCl—NH—NH—PCl(C6H5)2]Cl2 is obtained according to equation (4). The preparation of the P—N five-ring compound X, formulated in „Inhaltsübersicht“, is described.
    Notes: Beim Umsatz von Diphenyltrichlorphosphoran mit Hydraziniumhydrochlorid disproportioniert dieses, es wird [(C6H5)2PCl—N—PCl(C6H5)2]Cl (III) und N2 gebildet. Zum Phosphinazindihydrochlorid [(C6H5)2PCl—NH—NH—PCl(C6H5)2]Cl2 gelangt man auf dem durch (4) beschriebenen Weg. Die Darstellung des P und N enthaltenden Fünfrings X wird beschrieben.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 397 (1973), S. 269-278 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Thermolysis of Phosphorus(V) Sulfur(VI) Nitride HalidesThermolysis of compounds of the type R2PCl = N-SO2X (R = Cl, CH3, C6H5; X = F, Cl) results in the formation of the compounds R2P(O)Cl and [NS(O)X]n. Pyrolysis of the title compounds with longer chains yields, among others, the cyclic compounds III and IX. IX is also one of the decomposition products of a sulfamide derivative (XXI). Finally the thermal behaviour of carbon containing phosphorus(V) sulfur(VI) nitride chlorides has been investigated.
    Notes: Bei der Thermolyse von Verbindungen des Typs R2PCl = N-SO2X (R = Cl, CH3, C6H5; X = F, Cl) werden die Verbindungen R2P(O)Cl und [NS(O)X]n gebildet. Bei der Pyrolyse längerkettiger Titelverbindungen entstehen u. a. die cyclischen Verbindungen III und IX. IX ist auch eines der Zersetzungsprodukte eines Sulfamidderivates (XXI). Schließlich wurde das thermische Verhalten kohlenstoffhaltiger Phosphor(V)-Schwefel(VI)-nitrid-chloride untersucht.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 379 (1970), S. 48-55 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Aminoarsanes may be prepared by aminolysis of arsenic trichloride or methyl-dichloroarsine. However, better yields are obtained by transamination of tris-dimethyl-amino-arsane which also reacts with amino alcohols: On using bis-oxyalkyl- or bis-aminoalkyl-amine, bicyclic systems are obtained such as 1.6.7.8-dioxazarsa-pentalane, 1.7.8.9-dioxazarsa-hydrindane, 1.8.9.10-dioxazarsa-decaline, or the corresponding triazarsa-compounds.
    Notes: Aminoarsane werden durch Aminolyse von Arsentrichlorid oder Methyldichlorarsin dargestellt. Die Transaminierung von Trisdimethylamino-arsan führt jedoch zu besseren Ausbeuten. Auch Aminoalkohole setzen sich mit dem Aminoarsan um. Benutzt man Bis-oxyalkyl-amin oder Bis-aminoalkyl-amin, so erhält man bicyclische Systeme, wie das 1.6.7.8-Dioxazarsa-pentalan, das 1.7.8.9-Dioxazarsa-hydrindan, das 1.8.9.10-Dioxazarsa-dekalin oder entsprechende Triazarsa-Verbindungen.
    Type of Medium: Electronic Resource
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