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  • Inorganic Chemistry  (67)
  • Aluminium oxide; Archive of Ocean Data; ARCOD; Atlantic Ocean; Calcium oxide; Calculated; Components indeterminata; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Elevation of event; Event label; GC; Grab; GRAB; Gravity corer; Iron oxide, Fe2O3; Iron oxide, FeO; Latitude of event; Longitude of event; Magnesium oxide; Manganese oxide; Mikhail Lomonosov; ML1_70; ML5; ML5_348; ML5_363; NOAA and MMS Marine Minerals Geochemical Database; NOAA-MMS; Phosphorus pentoxide; Potassium oxide; Sample type; Silicon dioxide; Sodium oxide; Sulfur trioxide; Sum; Titanium dioxide; Water in rock; Wet chemistry
  • Archive of Ocean Data; ARCOD; Calculated; Cephalopoda; Cephalopoda, mass; Decapoda; Decapoda, mass; DEPTH, water; Euphausiacea; Euphausiacea, mass; Fish larvae; Fish larvae, mass; Hyperiidae, mass; Hyperiidea; Macroplankton; Macroplankton, mass; Macroplankton, wet weighted; Myctophidae; Myctophidae, mass; Mysidacea; Mysidacea, mass; Pteropoda; Pteropoda, mass; TRAWL; Trawl net; VITYAZ; Vityaz (ex-Mars); VITYAZ6493; Western Pacific
  • Archive of Ocean Data; ARCOD; Decapoda, biomass; DEPTH, water; Euphausiacea, biomass; Fishes, biomass; Invertebrata, biomass; Macroplankton, biomass; Myctophidae, biomass; TRAWL; Trawl net; VITYAZ; Vityaz (ex-Mars); VITYAZ6429; Western Pacific
  • 1970-1974  (70)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Übergangsmetallchalkogenverbindungen Über Diphenyldithiophosphinato-Komplexe von Vanadin(III), Vanadin(IV) und Molybdän(VI) (1971)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 104 (1971), S. 461-472 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transition Metal Chalcogen Compounds Diphenyldithiophosphinato Complexes of Vanadium(III), Vanadium(IV) and Molybdenum(VI)The preparation and properties of the compounds [(C6H5)2PS2]2MoO2 (3), [(C6H5)2PS2]2-VO (4) and [(C6H5)2PS2]3 V (5) are described. Their vibrational and electronic spectra are reported. The parameters 10 Dq = 13 200/cm and B = 395/cm were calculated from the electronic spectrum of the vanadium(III) compound.
    Notes: Die Darstellung und Eigenschaften der Verbindungen [(C6H5)2PS2]2MoO2 (3), [(C6H5)2PS2]2-VO (4) und [(C6H5)2PS2]3 V (5) werden beschrieben. Die Schwingungs- und Elektronenspektren werden mitgeteilt und letztere mit der Kristallfeldtheorie interpretiert. Für die Vanadin(III)-Verbindung lassen sich aus den Übergängen ν1(3T1g→3T2g) und ν2(3T1g(F) → 3T1g(P)) die Werte für 10 Dq 13200/cm und B 395/cm berechnen.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19711040215
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  • 2
    Electronic Resource
    Electronic Resource
    Übergangsmetallchalkogenverbindungen. Darstellung, Elektronen- und Schwingungsspektren von Diphenyldiselenophosphinato-Komplexen (1971)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 104 (1971), S. 1905-1914 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transition Metal Chalkogen Compounds. Preparation, Electronic and Vibrational Spectra of Diphenyldiselenophosphinato ComplexesThe anion of the diphenyldiselenophosphinic acid (dpspi) as a bidentate ligand forms complexes of the type [(C6H5)2PSe2]nM (M=metal). This ligand and its complexes with CoII, NiII, CuI, CdII, and ZnII are reported for the first time. The ligand field splitting parameters are calculated from the electronic spectra of Ni(dpspi)2 and Co(dpspi)2. The position of dpspi in the spectrochemical series is discussed. Its nephelauxetic effect is extremely high. The PSe stretching vibrations of the diphenyldiselenophosphinato complexes are assigned.
    Notes: Das Anion der Diphenyldiselenophosphinsäure („dpspi“) bildet als zweizähniger Ligand Komplexe des Typs [(C6H5)2PSe2]nM (M=Metall). Über diesen Liganden sowie die entsprechenden Komplexe mit CoII, NiII, CuI, CdII und ZnII wird in dieser Arbeit erstmalig berichtet. Aus den Elektronenspektren von Ni(dpspi)2 und Co(dpspi)2 werden die Ligandenfeldparameter berechnet. Die Einordnung von dpspi in die spektrochemische Reihe wird diskutiert. Der nephelauxetische Effekt ist außerordentlich groß. Die PSe-Valenzschwingungen der Diphenyldiselenophosphinato-Komplexe werden zugeordnet.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19711040630
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  • 3
    Electronic Resource
    Electronic Resource
    Übergangsmetallchalkogenverbindungen. Darstellung, Eigenschaften und röntgenographische Untersuchung von Tetrathioperrhenaten Schwingungs- und Elektronenspektrum sowie Normalkoordinatenanalyse des ReS-4 - Ions (1970)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 2961-2971 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transition Metall Chalkogen Compounds. Preparation, Properties and X-Ray Study of Tetrathioperrhenates. Vibrational and Electronic Spectra, Normal Coordinate Analysis of the ReS4--IonThe preparation and properties of tetrathioperrhenates MI ReS4 (MI = (C6H5)4As, (C6H5)4P, (CH3)4N) are described. The measured vibrational- and electronic spectra are discussed in terms of the bond properties. For the ReS4- ion a normal coordinate treatment is reported. From X-ray studies it could be derived that the tetraphenylarsonium salt (a = 13.14 Å, c = 7.11 Å) and the tetraphenylphosphonium salt (a = 12.94 Å, c = 7.20 Å) are crystallising tetragonal with Z = 2 probably in the space group S42-I 4.
    Notes: Darstellung und Eigenschaften von Tetrathioperrhenaten MIReS4 (MI = (C6H5)4As,(C6H5)4P, (CH3)4N) werden beschrieben. Die gemessenen Schwingungs- und Elektronen-spektren werden gedeutet und im Zusammenhang mit den Bindungsverhältnissen diskutiert. Für das ReS-4 -Ion wird eine Normalkoordinatenanalyse durchgeführt. Die röntgenographische Untersuchung ergab, daß das Tetraphenylarsoniumsalz (a = 13.14 Å, c = 7.11 Å) und das Tetraphenylphosphoniumsalz (a = 12.94 Å, c = 7.20 Å) tetragonal mit Z = 2 wahrscheinlich in der Raumgruppe S42-I 4 kristallisieren.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19701030932
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  • 4
    Electronic Resource
    Electronic Resource
    Übergangsmetallchalkogenverbindungen. Darstellung, Elektronen- und Schwingungsspektren von Diphenyl-dithiophosphinato-Komplexen (1971)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 104 (1971), S. 1892-1904 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transition Metal Chalkogen Compounds. Preparation, Electronic and Vibrational Spectra of Diphenyldithiophosphinate ComplexesThe preparation and properties of the chelate complexes of the diphenyldithiophosphinate ion Sn(dptpi)2, In(dtpi)3, As(dptpi)3, Sb(dptpi)3, Bi(dptpi)3, Co(dptpi)3, Rh(dptpi)3, Ir(dptpi)3, Pd(dptpi)2, Pt(dptpi)2 and Au(dptpi)3 are reported. From the electronic spectra of various compounds the diphenyldithiophosphinate ion can be placed in the spectrochemical series between the diethyldithiophosphate ion (dtp) and the chloride ion.  -  The nephelauxetic effect is greater than in dtp. Metal-sulfur stretching vibrations for all compounds are found between 270 and 329/cm.
    Notes: Darstellung und Eigenschaften der Chelatkomplexe des Diphenyldithiophosphinat-Ions Sn(dptpi)2, In(dptpi)3, As(dptpi)3, Sb(dptpi)3, Bi(dptpi)3, Co(dptpi)3, Rh(dptpi)3, Ir(dptpi)3, Pd(dptpi)2, Pt(dptpi)2 und Au(dptpi)3 werden beschrieben. Die ligandenfeld-theoretische Ausdeutung der Elektronenspektren verschiedener Komplexe ergibt, daß das Diphenyl-dithiophosphinat-Ion für die meisten Zentralatome (Ausnahme IrIII) in der spektrochemischen Reihe zwischen dem Diäthyldithiophosphat-Ion (dtp) und dem Chlorid-Ion steht.  -  Der nephelauxetische Effekt ist größer als im dtp. Die Metall-Schwefel-Valenzschwingung liegt in allen Verbindungen zwischen 270 und 329/cm.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19711040629
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  • 5
    Electronic Resource
    Electronic Resource
    Übergangsmetallchalkogenverbindungen Darstellung, Elektronen- und Schwingungsspektren von Diphenylselenothiophosphinato-Komplexen (1972)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 105 (1972), S. 1736-1748 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transition Metal Chalcogen Compounds. Preparation, Electronic and Vibrational Spectra of Diphenylselenothiophosphinato ComplexesThe preparation and properties of the chelate complexes of the diphenylselenothiophosphinate ion (C6H5)2P(Se)S- (= dpstpi) - Co(dpstpi)2 (2), Ni(dpstpi)2 (3), Zn(dpstpi)2 (4), Cd(dpstpi)2 (5), Pb(dpstpi)2 (6), Sb(dpstpi)3 (7) und Cr(dpstpi)3 (8) - are reported. On the basis of the electronic absorption spectra of 2, 3, and 8, the diphenylselenothiophosphinate ion can be placed in the spectrochemical and nephelauxetic series between (C6H5)2- and (C6H5)2PSe2-. The stretching vibrations of the fourmembered chelate ring MS(Se)P are assigned and compared with MS2P and MSe2P ring systems. The strongly coupled PS- and PSe-stretching vibrations of the complexes 2-8 are found between 576-548/cm and 525-510/cm respectively.
    Notes: Darstellung und Eigenschaften der Chelatkomplexe des Diphenylselenothiophosphinat-Ions (C6H5)2P(Se)S- (= dpstpi) - Co(dpstpi)2 (2), Ni(dpstpi)2 (3), Zn(dpstpi)2 (4), Cd(dpstpi)2 (5), Pb(dpstpi)2 (6), Sb(dpstpi)3 (7) und Cr(dpstpi)3 (8) - werden beschrieben. Die ligandenfeldtheoretische Ausdeutung der Elektronenspektren von 2, 3 und 8 ergibt, daß dpstpi in die spektrochemische und nephelauxetische Reihe zwischen (C6H5)2PS2- und (C6H5)2PSe2- einzuordnen ist. Die Valenzschwingungen der viergliedrigen Chelatringe MS(Se)P werden zugeordnet und mit denen der Ringsysteme MS2P und MSe2P verglichen. Die stark gekoppelten PS- und PSe-Valenzschwingungen der Komplexe 2-8 liegen zwischen 576 und 548/cm bzw. zwischen 525 und 510/cm.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19721050532
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  • 6
    Electronic Resource
    Electronic Resource
    Infrared and electronic Spectral Studies of Metal Maleato Complexes (1971)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 385 (1971), S. 329-336 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Es wurden die IR-Spektren von Maleinsäure, Na- und K-Maleat sowie der Maleatokomplexe M(mal) · xH2O und H2[M(mal)2] · 4H2O mit den zweiwertigen Metallen M = Co, Ni, Cu, Zn untersucht und vollständig gedeutet. Aus den Carbonyl-frequenzen folgt ein geringerer Kovalenzanteil der M-O-Bindung als bei analogen Oxalatound Malonatokomplexen. Um über die Struktur der Maleatokomplexe Auskunft zu erhalten, wurden auch die Elektronenspektren aufgenommen.
    Notes: Infrared spectra of maleic acid, its sodium and potassium salts, and its metal complexes of the formula M(mal) · xH2O and H2[M(mal)2] · 4 H2O, where M = divalent Co, Ni, Cu or Zn, have been studied. An assignment of all the infrared frequencies have been made by a comparison with related molecules. The carbonyl frequencies indicate less “covalent character” in metal-oxygen bond than in the related oxalate and malonate complexes. The electronic spectra have been recorded and used to obtain the structure of the complexes.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19713850316
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  • 7
    Electronic Resource
    Electronic Resource
    Selenocyanat-Komplexe der Seltenen Erden (1970)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 375 (1970), S. 302-307 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 70 rare earths selenocyanate complexes with Phen, Dipy, Urt and Diap as the ligands have been synthetized for the first time.From IR-spectral and X-ray data it has been established that in the compounds Ln(Phen)3 · · (NCSe)3, Ln(Dipy)3(NCSe)3, Ln(Dipy)2(NCSe)3 · 2CH3OH, Ln(Urt)2(NCSe)3 · 3C2H5OH, and Ln(Diatp)3(NCSe)3, where Ln-La, Ce, Pr and Nd, the selenocyanate groups are monodentate and coordinated to the rare earths metal through the nitrogen atom, whereas in Ln(Diatp)4 · · (NCSe)3 ionic NCSe- is present.
    Notes: Es wird über die Darstellung von Selenoxyanaten der SE unter Stabilisierung mit organischen Liganden (Phenanthiolin, Dipyridyl, Urotropin, Diantipyrilmethan) berichtet. Die insgesamt 70 Verbindungen werden infrarotspektroskopisch und röntgenographisch charakterisiert. Aus den Messungen wird auf N-gebundene Komplexe geschlossen mit Ausnahme bei den Verbindungen des Typs SE(Diantipyrilmethan)4(NCSe-)3, in denen die SeCN-Gruppe mit dem SE-Metall durch Ionenbindung gebunden ist.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19703750313
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  • 8
    Electronic Resource
    Electronic Resource
    Mixed Ligand Complexes of Oxovanadium (IV) Oxalate (1972)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 387 (1972), S. 373-376 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Es wurden die Oxovanadin(IV)-Komplexe VOC2O4 · 2 L (L = DMF, Formamid, Äthylenharnstoff, Harnstoff, Äthylendiamin) hergestellt und charakterisiert. In ihnen ist die Oxalatgruppe zweizähnig, ebenso das Äthylendiamin (über seinen Stickstoff), während die anderen Liganden L über den Carbonylsauerstoff einzähnig koordinieren. Das Vanadin befindet sich in all diesen Komplexen in einer verzerrten tetragonal-pyramidalen Fünferkoordinaten.Geschlossen wird dies aus magnetischen Messungen sowie Elektronen und IR-Spektren.
    Notes: The oxovanadium(IV) complexes VOC2O4 · 2DMF, VOC2O4 · 2 formamide, VOC2O4 · 2 ethylene urea, VOC2O4 · 2 urea and VOC2O4 · en have been prepared and characterized. The oxalato group functions as a bidentate ligand in all these complexes. Except ethylene diamine the remaining ligands - DMF. formamide, ethylene urea and urea - act as monodentate ligand coordinating through their carbonyl oxygen. Ethylene diamine is bound to the metal through nitrogen. In all the complexes vanadium is five coordinated in distorted tetragonal-pyramidal structures.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19723870311
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  • 9
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    (Table 2a) Biomass of the main groups of macroplanktonic animals in different depth layers at Station VITYAZ6429 (1973)
    PANGAEA
    In:  P.P. Shirshov Institute of Oceanology, Russian Academy of Sciences, Moscow
    Details
    Publication Date: 2023-07-10
    Keywords: Archive of Ocean Data; ARCOD; Decapoda, biomass; DEPTH, water; Euphausiacea, biomass; Fishes, biomass; Invertebrata, biomass; Macroplankton, biomass; Myctophidae, biomass; TRAWL; Trawl net; VITYAZ; Vityaz (ex-Mars); VITYAZ6429; Western Pacific
    Type: Dataset
    Format: text/tab-separated-values, 42 data points
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  • 10
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    (Table 1d) Distribution of macroplankton catches and percentage of groups (by weight) in different depth layers at Station VITYAZ6493 (1973)
    PANGAEA
    In:  P.P. Shirshov Institute of Oceanology, Russian Academy of Sciences, Moscow
    Details
    Publication Date: 2023-07-10
    Keywords: Archive of Ocean Data; ARCOD; Calculated; Cephalopoda; Cephalopoda, mass; Decapoda; Decapoda, mass; DEPTH, water; Euphausiacea; Euphausiacea, mass; Fish larvae; Fish larvae, mass; Hyperiidae, mass; Hyperiidea; Macroplankton; Macroplankton, mass; Macroplankton, wet weighted; Myctophidae; Myctophidae, mass; Mysidacea; Mysidacea, mass; Pteropoda; Pteropoda, mass; TRAWL; Trawl net; VITYAZ; Vityaz (ex-Mars); VITYAZ6493; Western Pacific
    Type: Dataset
    Format: text/tab-separated-values, 198 data points
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