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  • 1
    Electronic Resource
    Electronic Resource
    An algorithm for high order polynomial extrapolation (1979)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 14 (1979), S. 1428-1429 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620140914
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  • 2
    Electronic Resource
    Electronic Resource
    Normal gradient boundary condition in finite difference calculations (1973)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 7 (1973), S. 395-400 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: An outline is given of a method for dealing with curved boundaries in finite difference calculations (relaxation or other similar techniques) where the gradient normal to the boundary is specified. Fluid flow calculations using the velocity potential are typical of such problems and the flow round a circular cylinder is computed as an example. The method makes no approximation which is not made in the usual finite difference techniques, therefore accuracy at the boundary is as good as in the remainder of the field.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620070314
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  • 3
    Electronic Resource
    Electronic Resource
    Continuous-culture system for ecological studies of microorganisms (1966)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 8 (1966), S. 473-488 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An improved system is presented for measurement of interactions between a number of individual bacterial species. In the procedure, steady-state populations are fed into a common-mixed-culture vessel. Generation times of each species are determined under these conditions and contrasted with generation time in an identical situation in pure culture. Populations for generation time are determined with the aid of differential media. The mechanical system includes three types of peristaltic pumps for media feed and a unit for measurement, recording, and/or control of pH. A new type of anaerobic continuous-culture vessel which can be inoculated, sampled, and fed continuously is also described. A functional test of a three-part system including Streptococcus salivarius, Veilloncella alcalescens, and Staphylococcus aureus is presented. An unusual feature was the finding that, under certain conditions, the generation time of S. Salivarius was less than 10 min.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260080403
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  • 4
    Electronic Resource
    Electronic Resource
    The direct determination of oestrogen and progesterone in human ovarian tissue by quantitative high resolution mass spectrometry (1976)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 3 (1976), S. 295-298 
    Details
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The concentration of oestrone, oestradiol and progesterone in ovarian tissue have been determined directly by quant tative high resolution mass fragmentography without the necessity of extraction or purification. The changes in the levels of these steroids in the ovary throughout a 28 day period correlate well with those measured in plasma and also with those of the corresponding metabolites excreted in urine. Some benign ovarian tumours (cysts) have been shown to contain abnormally large amounts of progesterone.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bms.1200030608
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  • 5
    Electronic Resource
    Electronic Resource
    ELectron-impact studies in medicine and biochemistry - II: The mass spectra of the alkaloids from Cissampelos ovalifolia D.C. (1970)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 607-614 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of some new alkaloids extracted from Cissampelos ovalifolia are discussed. The compounds are shown to be tertiary bis-benzyl isoquinoline bases of an unusual type possessing a p-xylyl moiety. Some information about the relative positions of hydroxyl and methoxyl substituents in the macrocyclic ring system is also obtained.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210040161
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  • 6
    Electronic Resource
    Electronic Resource
    Electron impact studies in medicine and biochemistry - I: A mass spectrometric study of the impurities in yellow phenolphthalein (1970)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 4 (1970), S. 299-313 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A number of impurities have been extracted from yellow phenolphthalein by thin layer chromatography and characterized on the basis of their mass spectra. One of these by-products appears to be fluoran while the structure proposed for a second accounts for the properties ascribed to it by previous investigations. The bulk of the impurity appears to consist of condensation products of three molecules of phenol with two of phthalic anhydride.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210040133
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  • 7
    Electronic Resource
    Electronic Resource
    Single pass major element x-ray fluorescence analysis of silicate rock samples using a Philips 1212 spectrometer (1982)
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 11 (1982), S. 100-108 
    Details
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A ‘single pass’ method of analysing silicate rocks for their major element composition has been developed using a Philips 1212 x-ray fluorescence spectrometer. Samples need only be submitted once to the spectrometer and all ten major elements (SiO2, TiO2, Al2O3, Fe2O3T, MnO, MgO, CaO, Na2O, K2O and P2O5) are determined using a Cr x-ray tube and three analysing crystals, i.e. TIAP, PET and LiF220. The method has been evaluated in terms of the quality of the calibration lines for each element, the precision of replicated analyses and by the analysis of rock standards as unknown samples. The single pass method is rapid, facilitates on-line data reduction and is capable of producing high quality analytical data.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/xrs.1300110303
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  • 8
    Electronic Resource
    Electronic Resource
    An iterative method for determining background intensities used in XRF calibration lines for flux-fusion silicate rock analysis (1978)
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 7 (1978), S. 38-43 
    Details
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: In major element rock analysis using XRF and fused samples and standards, the construction of standard calibration lines is facilitated by the accurate knowledge of the background intensities for the elements analyed. As an alternative to measuring the background ‘off peak’ or on blanks, an iterative technique is proposed. This technique is based on repeatedly incrementing the background value until the best calibration line has been found. The quality of the calibration line is evaluated in terms of the average relative and average absolute errors. Comparative data, presented for calibration lines constructed from (1) backgrounds measured from blanks and (2) backgrounds determined by iterationm, show that the iterative technique produces superior calibrations. The analytical techniques have been tested by analysing international rock standards as unknown samples.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/xrs.1300070112
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  • 9
    Electronic Resource
    Electronic Resource
    Sorption and flow of gases in polyethylene (1959)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 41 (1959), S. 53-71 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Solubilities and diffusivities of N2, O2, CO2, and He in a variety of polyethylenes were measured in the temperature range 0-50°C. Polyethylene films studied covered a range of crystallinities (43-82%) and branching indices, and were prepared under a variety of known thermal histories. Diffusivities were determined by the time-lag method; solubilities, by time-lag, and also by a newly developed and more accurate static method. Solubilities were found to obey Henry's Law; the solubility constants determined by both methods were found to agree within the limits of accuracy, confirming the applicability of the unsteady-state diffusion equation to essentially isotropic crystalline polymers. For a given gas at constant temperature, the solubility constant is directly proportional to the volume fraction of amorphous material in a polyethylene sample (as determined by density), irrespective of its origin or thermal history; the concept of the crystallites as an impermeable, dispersed phase thus appears justified. Diffusivities were found to vary widely (nearly fivefold) depending on polymer crystallinity and thermal history and were as much as tenfold lower than the values estimated for completely amorphous polyethylene. Application of principles of flow through porous media to this system leads to a conclusion that abnormally low diffusivities arise predominantly from the impedance to gas flow offered by the dispersed crystalline phase. Variations in diffusivity with branching index and thermal history correlate qualitatively with expected corresponding variations in crystallite growth kinetics and shape; the existence of highly anisometric, laminar crystallites in annealed linear polyethylene is indicated from these studies. The combined influence of crystallinity on solubility and diffusivity permits as much as a tenfold variation in gas permeability of polyethylene depending on polymerization method or fabrication process.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1959.1204113805
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  • 10
    Electronic Resource
    Electronic Resource
    Analysis of two-dimensional, finite amplitude wave propagation by time marching methods (1982)
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 2 (1982), S. 185-207 
    Details
    ISSN: 0271-2091
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Two-dimensional, finite-amplitude wave propagation in an inviscid, subsonic, perfect gas medium is analysed by explicit finite-difference methods. A two-step, Lax-Wendroff method and the single-step, Lax-Friedrichs method are used. A prescribed propagating velocity or pressure disturbance is applied along a single row of grid points normal to the stream direction and results in a 'forced' outflow boundary. The inflow boundary is placed far from outflow by utilizing a streamwise expanding grid and uniform inflow is imposed. Side boundaries are spatially periodic. The numerical solutions are compared with analytical small-perturbation solutions; higher-order effects arising from non-linearities are revealed by Fourier analysis. Solutions which closely approached a periodic state were obtained. The Lax-Wendroff method combined with the expanding grid is shown to be accurate and stable, the Lax-Friedrichs scheme produced highly damped solutions.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/fld.1650020206
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