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  • Wiley-Blackwell  (90)
  • American Physical Society (APS)
  • Macmillian Magazines Ltd.
  • 1970-1974  (90)
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Keywords
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Year
  • 1
    Electronic Resource
    Electronic Resource
    An electron microscopic method for studying nucleic acid-protein complexes. Visualization of RNA polymerase bound to the DNA of bacteriophages T7 and T3Dedicated to the memory of Dr. Jean-Pierre Tranzer. (1974)
    New York : Wiley-Blackwell
    Biopolymers 13 (1974), S. 995-1009 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Double-stranded DNA can be readily adsorbed on mica or directly on carbon coated grids from the surface of solutions containing ethidium bromide, actinomine, or propidium diiodide. The DNA molecules are unfolded, well separated, and show a length distribution similar to molecules prepared by protein monolayer techniques.Since the intercalating dyes tested do not lead to an increased apparent diameter of the nucleic acid the method is useful for the study of nucleic acid-protein complexes. As a model, the binding of E. coli RNA polymerase to phage T7 and T3 DNA was examined under different conditions. The enzyme can easily be identified and its position along the DNA molecule can be mapped.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1974.360130514
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  • 2
    Electronic Resource
    Electronic Resource
    Zellphysiologie des Stoffwechsels. Von D. Pette. Bd. 13 der Konstanzer Universitätsreden. Herausgeg. von G. Hess. Konstanzer Universitätsverlag 1970. 50 S., brosch. DM 4,80 (1970)
    Weinheim : Wiley-Blackwell
    Chemie in unserer Zeit 4 (1970), S. 196-196 
    Details
    ISSN: 0009-2851
    Keywords: Chemistry ; Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ciuz.19700040613
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  • 3
    Electronic Resource
    Electronic Resource
    Physikalische Methoden in der Chemie: UV-Photoelektronenspektroskopie (1971)
    Weinheim : Wiley-Blackwell
    Chemie in unserer Zeit 5 (1971), S. 65-77 
    Details
    ISSN: 0009-2851
    Keywords: Chemistry ; Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ciuz.19710050302
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  • 4
    Electronic Resource
    Electronic Resource
    Padé approximants to physical properties via inner projections (1973)
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 7 (1973), S. 133-134 
    Details
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/qua.560070114
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  • 5
    Electronic Resource
    Electronic Resource
    Molecular-orbital calculations on transition metal complexes, charge-transfer spectra and the sequence of metal and ligand orbitals (1972)
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 6 (1972), S. 859-880 
    Details
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An outline is given of a semi-empirical scheme for molecular-orbital calculations on transition-metal complexes according to a revised INDO procedure. To judge the reliability of the results of the calculations, the charge-transfer transitions of a number of complexes have been calculated and compared with experimental data. Both for the excitation energies and for the oscillator strengths the agreement is very satisfactory. With respect to the sequence of occupied metal and ligand orbitals it was found that for closed-shell d6 and d8 systems the molecular orbitals which are mainly composed of metal d orbitals have a lower energy than the orbitals built up from ligand p orbitals. Calculations by the extended Hückel method and other similar schemes give the d orbitals as the highest occupied ones as a result of a bad approximation of the diagonal elements of the Fock matrix. The consequences for the interpretation of photo-electron spectra of transition-metal complexes are discussed.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/qua.560060506
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  • 6
    Electronic Resource
    Electronic Resource
    Molecular integrals over generalized gaussian basis sets (1974)
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 8 (1974), S. 179-191 
    Details
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method is given for obtaining the common molecular integrals over generalized gaussian functions: \documentclass{article}\pagestyle{empty}\begin{document}$$ \chi_i = x^{\lambda_i}_i \exp \big\{ - \big(\alpha_i x^2_i + \alpha^{\prime}_i x^{\prime 2}_i + \alpha^{\prime\prime}_i x^{\prime\prime 2}_i\big)\big\} $$\end{document}The present algorithms are expected to be more efficient than those given in earlier work by the same author.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/qua.560080205
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  • 7
    Electronic Resource
    Electronic Resource
    Notiz über ein einfaches Verfahren zur Darstellung von 3,4-Bismethylencyclobuten (1973)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 106 (1973), S. 3461-3462 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19731061031
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  • 8
    Electronic Resource
    Electronic Resource
    [2.2]Paracyclophane durch Addition von Acetylenderivaten an 1,2,4,5-Hexatetraen (1974)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 107 (1974), S. 1891-1902 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation of [2.2]Paracyclophanes by Addition of Acetylene Derivatives to 1,2,4,5-HexatetraeneThe tetrasubstituted [2.2]paracyclophanes 4a - e are formed by cycloaddition of the symmetrical acetylene derivatives 2a - e to 1,2,4,5-hexatetraene (1), and their constitution and configuration is established by spectroscopic methods, degradation and pyrolysis experiments. The tetramethyl ester 4a is reduced to the tetraalcohol 4g, and the tetracarboxylic acid 4c is converted to the bisanhydride 4f and [2.2] paracyclophanes (4h), respectively. All possible disubstituted [2.2] paracyclophanes 6 are obtained when methyl propiolate (5a) is added to. 1, whereas further symmetrical and unsymmetrical acetylene derivatives do not react with 1.
    Notes: Die tetrasubstituierten [2.2]Paracyclophane 4a - e werden durch Cycloaddition der symmetrischen Acetylenderivate 2a - e an 1,2,4,5-Hexatetraen (1) dargestellt und ihre Konstitution und Konfiguration durch spektroskopische Methoden. Abbau- und Pyrolyseversuche bewiesen. Der Tetramethylester 4a wird zum Tetraalkohol 4g reduziert und die Tetracarbonsäure 4c in das Bisanhydrid 4f bzw. [2.2] Paracyclophan (4h) übergeführt. Bei der Anlagerung von Propiolsäure-methylester (5a) an 1 werden alle isomeren disubstituierten [2.2]paracyclophanes 6 erhalten. Weitere symmetrische und unsymmetrische Acetylenderivate reagieren nicht mit 1.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19741070613
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  • 9
    Electronic Resource
    Electronic Resource
    Determination of thermodynamic parameters of polymer-solvent systems from sedimentation-diffusion equilibrium in the ultracentrifugePresented in part at the Microsymposium on Macromolecules, “Polymer Gels and Concentrated Solutions,” Prague, September 1967. (1970)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 841-868 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Sedimentation equilibrium in the ultracentrifuge means that there is such a distribution of molecular species throughout the cell, that the centrifugal forces are balanced by differences in the activities. This provides a method for determination of the activities and the chemical potentials in polymer solutions which, in principle, is very simple and reliable. A complication is caused by polydispersity of the dissolved polymer. If one assumes that the interaction parameter depends on concentration and temperature, but not on molecular weight, it is possible to determine the chemical potential of polymer and solvent from the ultracentrifugal data. Experiments have been carried out on the systems polystyrene-toluene and polystyrene-cyclohexane at different temperatures and in the concentration range 0-80 wt-%. The results are expressed in the data for the chemical potential of the solvent, the number average chemical potential of the polymer and the interaction parameter χ.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1970.160080603
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  • 10
    Electronic Resource
    Electronic Resource
    Wärmealterung und Grenztemperatur von organischen Isolierstoffen (1971)
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 2 (1971), S. 127-135 
    Details
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Thermal aging and endurance of organic insulating materials. The knowledge of the thermal endurance of organic insulating materials is very important for the application in electrical engineering. The change of the values of the properties by thermal aging is, theoretically, described under the assumption being a linear connection to the rules of the kinetic theory of chemical reactions. By this premise it is possible to indicate functions for aging and thermal endurance, being plotted as straight lines in suitable coordinates. In this way the test results can be evaluated better than by conventional means.
    Notes: Die Kenntnis der Grenztemperatur organischer Isolierstoffe ist für deren Anwendung in der Elektrotechnik von großer Wichtigkeit. Die Änderung von Eigenschaftswerten auf Grund einer Wärmebehandlung wird theoretisch beschrieben unter der Annahme, daß ein linearer Zusammenhang mit den Gesetzen der Reaktionskinetik besteht. Unter den getroffenen Voraussetzungen können. Alterungs- und Lebensdauerfunktionen angegeben werden, die sich bei geeigenten Koordinaten als Geradendarstellen lassen. Meßergebnisse können auf diese Weise besser ausgewertet werden als nach herkömmlichen Verfahren.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mawe.19710020304
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